2,3-Dihydro-1-methyl-1H-phosphole 1-oxide → 1-Methyl-1-oxophospholanyl dimethyl phosphine oxide

HRID 972306

反応式

HRID 972306 の反応式
[CH3:1][P:2]1(=[O:7])[CH2:6][CH2:5][CH:4]=[CH:3]1.[CH3:8][PH:9](=[O:11])[CH3:10]>C(OCCCC)(=O)C1C(=CC=CC=1)C(OCCCC)=O>[CH3:1][P:2]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH:3]1[P:9](=[O:11])([CH3:10])[CH3:8]

参加物

4

反応物 2

HCID 701042,3-Dihydro-1-methyl-1H-phosphole 1-oxideHCID 178503022methylphosphonoylmethane

生成物 1

HCID 214066461-Methyl-1-oxophospholanyl dimethyl phosphine oxide

試薬・触媒・溶媒 1

HCID 3026Dibutyl Phthalate溶媒

実験手順

116 g of 1-methyl-1-oxophospholine and 6 g of tert.-butyl perpivalate in dibutyl phthalate are added dropwise with stirring under an oxygen-free atmosphere to 234 g of dimethyl phosphine oxide. The reaction temperature is 75° to 80° C. The starting materials are then distilled off. The residue consists of 185 g of 1-methyl-1-oxophospholanyl dimethyl phosphine oxide.

後処理

  1. customis 75° to 80° C
  2. distillationThe starting materials are then distilled off

出典と根拠

ORDレコード
ord-baa22e997a8a460bb171ee0725220b3f
出典データセット
uspto-grants-1977_10
特許番号
US04052484

関連ノート

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