Diphenylphosphine → (3,3-Dimethylbutyl)(diphenyl)phosphane

反応式

[C:1]1([PH:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:14][C:15]([CH3:20])([CH3:19])[CH2:16][CH2:17]Cl>>[CH3:14][C:15]([CH3:20])([CH3:19])[CH2:16][CH2:17][P:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)[C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

参加物

反応物 2

HCID 70017Diphenylphosphine

HCID 761111-Chloro-3,3-dimethylbutane

生成物 1

HCID 14007798(3,3-Dimethylbutyl)(diphenyl)phosphane

実験手順

As a known compound, t-butylethyl, (i.e., 3,3-dimethylbutyl) diphenyl phosphine was also synthesized via the known displacement approach: the reaction of lithium diphenyl phosphide with 3,3-dimethylbutyl chloride provided the compound in good yield.

後処理

customprovided the compound in good yield

出典と根拠

ORDレコード: ord-d2632fa9443d414cb46e5caeb9b737f6
出典データセット: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04668809

反応ノート

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