2-Buten-1-amine, 3-methyl- → HCID 178446447、化合物

HRID 982293

反応式

HRID 982293 の反応式
[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][NH2:5].C[N:8](N=O)[C:9]([NH:11][N+:12]([O-:14])=[O:13])=N>CCO.O>[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][NH:5][C:9]([NH:11][N+:12]([O-:14])=[O:13])=[NH:8]

参加物

4

反応物 2

HCID 1669212-Buten-1-amine, 3-methyl-HCID 135436526N-Methyl-N'-nitro-N-nitrosoguanidine

生成物 1

HCID 178446447HCID 178446447、化合物

試薬・触媒・溶媒 1

HCID 19096565Water ethanol溶媒

実験手順

3-methyl-2-butenylamine (3.0 g) is added dropwise at room temperature to a slurry of 1-methyl-3-nitro-1 -nitrosoguanidine (4.3 g) in 50 ml of EtOH/H2O (1/1). After stirring the mixture at room temperature for 18 hours, the precipitate which forms is removed by filtration. The solid is then slurred with dilute hydrochloric acid, collected by filtration and washed with ethanol/water (30/70). Recrystallization from ethanol gives a white solid with mp 134°-136° C.

後処理

  1. customthe precipitate which forms is removed by filtration
  2. filtrationcollected by filtration
  3. washwashed with ethanol/water (30/70)
  4. customRecrystallization from ethanol
  5. customgives a white solid with mp 134°-136° C.

出典と根拠

ORDレコード
ord-fc1345d0539b41a2bec5e144a8d474e9
出典データセット
uspto-grants-1991_02
特許番号
US04995903

関連ノート

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