Triethoxysilane → 1,14-Bis(triethoxysilyl)tetradecane

HRID 983370

反応式

HRID 983370 の反応式
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=[CH2:14].[CH2:15]([O:17][SiH:18]([O:22][CH2:23][CH3:24])[O:19][CH2:20][CH3:21])[CH3:16]>C1(C)C(C)=CC=CC=1>[CH2:15]([O:17][Si:18]([O:22][CH2:23][CH3:24])([O:19][CH2:20][CH3:21])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][Si:18]([O:22][CH2:23][CH3:24])([O:19][CH2:20][CH3:21])[O:17][CH2:15][CH3:16])[CH3:16]

参加物

4

反応物 2

HCID 13830TriethoxysilaneHCID 30875Tetradeca-1,13-diene

生成物 1

HCID 225598111,14-Bis(triethoxysilyl)tetradecane

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

実験手順

A mixture of 25 g of 1,13-tetradecadiene (Aldrich), 44.4 g of triethoxysilane (Shin-Etsu Silicone) and 0.1 mL of 3% xylene solution of a platinum complex of bis((vinyl dimethyl)disiloxane) was stirred at room temperature in a nitrogen atmosphere for 3 days. The resultant reaction mixture was purified by distillation, to obtain 1,14-bis(triethoxysilyl)tetradecane. Its structure was confirmed by NMR.

後処理

  1. customThe resultant reaction mixture
  2. distillationwas purified by distillation

出典と根拠

ORDレコード
ord-6b9d9ed70234478894a9c99f754256de
出典データセット
uspto-grants-2005_03
特許番号
US06864006B2

関連ノート

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