Chromium(3+) trichloride → HCID 178519210、化合物

HRID 989566

反応式

HRID 989566 の反応式
[Cl-].[Cr+3:2].[Cl-].[Cl-].[O:5]=[C:6]1[O:12][C@H:11]([C@H:13]([CH2:15][OH:16])[OH:14])[C:9]([OH:10])=[C:7]1[OH:8]>O>[O:5]=[C:6]1[O:12][C@H:11]([C@H:13]([CH2:15][OH:16])[OH:14])[C:9]([O-:10])=[C:7]1[OH:8].[Cr+3:2].[O:5]=[C:6]1[O:12][C@H:11]([C@H:13]([CH2:15][OH:16])[OH:14])[C:9]([O-:10])=[C:7]1[OH:8].[O:5]=[C:6]1[O:12][C@H:11]([C@H:13]([CH2:15][OH:16])[OH:14])[C:9]([O-:10])=[C:7]1[OH:8]

参加物

4

反応物 2

HCID 6452300Chromium(3+) trichlorideHCID 54670067L-Ascorbic Acid2 回

生成物 1

HCID 178519210HCID 178519210、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

反応条件

温度
50 °C

実験手順

Half gram (1.85 mmole) of chromium chloride (CrCl3) was dissolved in 30 ml of deionized water to get a green solution. 1.0 g (5.5 mmole) of ascorbic acid (Asc) dissolved in 40 ml of deionized water, was added to the solution. The pH of the reaction mixture was adjusted to 4.5 (pK(Asc)4.2), and the reaction mixture was stirred for 3 hours at 50° C. to get a dark green solution. The solution was concentrated in vacuum and the large volume of ethanol 90% was added to get a green sediment. UV-VIS Spectrum for Cr-Asc showed two main absorbance peaks at 263 and 592 nm.

後処理

  1. customto get a green solution
  2. additionwas added to the solution
  3. customto get a dark green solution
  4. concentrationThe solution was concentrated in vacuum
  5. additionthe large volume of ethanol 90% was added
  6. customto get a green sediment

出典と根拠

ORDレコード
ord-41998616a7dd415388b9f444902f1e40
出典データセット
uspto-grants-2002_10
特許番号
US06458351B2

関連ノート

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