関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sodium Azide | HCID 33557 | — |
| 反応物 | 1-Ethyl-heptyl Methanesulphonate | HCID 17888751 | — |
| 溶媒 | Dimethyl Sulfoxide | HCID 679 | — |
| 生成物 | 3-Azidononane | HCID 18419356 | — |
反応手順
15.0 g (67.46 mmol) of 1-ethyl-heptyl methanesulphonate are dissolved in 300 ml of DMSO and, after addition of 17.54 g (269.8 mmol) of sodium azide, the mixture is stirred at 50° C. for 16 hours. The reaction mixture is poured into ice-water and extracted three times with ether. The extract is dried over sodium sulphate giving 11.4 g (96%) of a yellow liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06458796B1 |
|---|
| 出典データセット | uspto-grants-2002_10 |
|---|
| ORD ID | ord-5973f6b0206647cab6dccfdb93d60356 |
|---|
| 出典メモ | uspto-grants-2002_10 |
|---|
