Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Azoxybenzene
Fentoxan · Azoxybenzol · ZOXYBENZENE · Azoxybenzeen · Azoxybenzide · Azoxybenzole · Azoxybenzene · Azoxylbenzene
식별자 및 물리적 특성
| CAS No. | 20972-43-4 |
|---|---|
| 분자식 | C12H10N2O |
| 평균 분자량 | 198.22 g/mol |
| 단동위원소 질량 | 198.07931294 g/mol |
| SMILES | [O-][N+](=Nc1ccccc1)c1ccccc1 |
| InChIKey | GAUZCKBSTZFWCT-UHFFFAOYSA-N |
| PubChem CID | 10316 |
| ChEMBL | CHEMBL1442921 |
| ChEBI | CHEBI:51865 |
| EC No. | 207-802-1 |
| DTXSID | DTXSID0024555 |
화학 및 물리적 성질
| XLogP | 3.1 |
|---|---|
| 극성 표면적 | 41.1 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 2 |
| 무거운 원자 수 | 15 |
| 형식 전하 | 0 |
| 복잡도 | 216 |
| 물질 분류 | Nitrogen Compounds -> Other Aromatics (Nitrogen) |
| 밀도 | 1.159 at 79 °F (NTP, 1992) - Denser than waterwill sink1.1590 @ 26 °C/4 °C1.16 |
| Color/Form | PALE YELLOW ORTHORHOMBIC NEEDLES |
| 용해도 | less than 1 mg/mL at 68 °F (NTP, 1992)INSOL IN WATERSOL IN ALCOHOL & ETHER43.5 G DISSOLVE IN 100 G PETROLEUM ETHER @ 15 °C |
| 끓는 점 | Decomposes (NTP, 1992)130 °C / 0.9mmHg |
| Decomposition | ...ON DECOMPOSITION IT EMITS TOXIC FUMES... |
| 녹는점 | 97 °F (NTP, 1992)36 °C32-36 °C |
| Physical Description | Azoxybenzene appears as bright yellow crystals or yellowish-brown solid. (NTP, 1992)Yellow solidmp = 36 deg C[HSDB] Bright yellow or yellowish-brown solid[CAMEO] Orange solidmp = 33-36 deg C[Alfa Aesar MSDS] |
| Other Experimental Properties | 100 PARTS OF ABSOLUTE ALCOHOL SATURATED AT 16 °C CONTAIN 17.5 PARTS (WT/WT) AZOXYBENZENEEASILY VOLATILE IN SUPER-HEATED STEAM @ 140-150 °C |
| 굴절률 | 1.6330 (estimate) |
| 저장 조건 | 0-6°C |
| 색상 | 노란색, 마름모꼴 결정 |
| Merck | 14,923 |
| BRN | 743984 |
| 유전율 | 5.1(40℃) |
| 주요 응용 | 농업환경 |
| InChI | 1S/C12H10N2O/c15-14(12-9-5-2-6-10-12)13-11-7-3-1-4-8-11/h1-10H/b14-13- |
| InChIKey | GAUZCKBSTZFWCT-YPKPFQOOSA-N |
| SMILES | [O-]\[N+](=N/c1ccccc1)c2ccccc2 |
| EPA | Azoxybenzene (495-48-7) |
화학적 성질
ORANGE-YELLOW TO ORANGE CRYSTALS
안전 및 규제
| GHS 분류 | WarningH302: Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, and P501 (click each P-code to see the statement)H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral] |
|---|---|
| 규제 정보 | Azoxybenzene: Does not have an individual approval but may be used under an appropriate group standard |
| 화재 위험 | Flash point data for this chemical are not availablehowever, it is probably combustible. (NTP, 1992) |
| 화재 가능성 | SLIGHTLY DANGEROUS... |
| 건강 유해성 | SYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes. Other symptoms include jaundice, cyanosis, dermatitis and liver and kidney damage. |
| 유해성 요약 | External application to rabbit eyes scored 1 on a scale of 1-10 (10 being most severe) for degree of injury after 24 hoursCauses icteric skin, methemoglobinemia, swelling of liver and spleen, and atrophy of testis and epididymis in oral studies of rats and miceEmergency treatment: Methemoglobinemia[HSDB] Dust mixtures with air may be explosiveA skin and eye irritantMay cause liver and kidney injury[CAMEO] Causes decrease in cellular immune response in intraperitoneal toxic-dose studies of ratsCauses other GI and liver changes in oral lethal-dose studies of mice[RTECS] May cause irritation and methemoglobinemia[Alfa Aesar MSDS] |
| 반응성 그룹 | Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
| Reactivity Profile | AZOXYBENZENE is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. |
용도
용도
Intermediate in organic synthesis.
일반 설명
Bright yellow crystals or yellowish-brown solid.