Azetidine (HCID 10422)

개요

Azetidine is a saturated organic heteromonocyclic parent, an azacycloalkane and a member of azetidines.

이름 및 식별자

우선 이름: Azetidine
IUPAC: azetidine
영어명: Azetidine
분자식: C3H7N
분자량: 57.09

이름 및 동의어

AZETIDINE503-29-7AzacyclobutaneTrimethylenimine1,3-Propylenimine37S883XDWRDTXSID8060117CHEBI:30968RefChem:560501DTXCID7040813207-963-8Trimethylene imine

이름 더 보기

AztidineAZETIDINE 99%Azetidine,98%Azetidine ,95%tetrahydroazete

MFCD00005165Azetidine, L-AcetidineTrimethyleneimineAzete, tetrahydro-Azetidine, 98%AI3-61395AKOS000121515

데이터베이스 식별자

CAS: 503-29-7
PubChem CID: 10422
DTXSID: DTXSID8060117
ChEMBL: CHEMBL2171713
ChEBI: CHEBI:30968
UNII: 37S883XDWR
EC Number: 207-963-8
Nikkaji: J79.636K

물성

구조 계산 물성

XLogP: -0.1
극성 표면적: 12 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 4
형식 전하: 0
복잡도: 17.2

실험 및 물리화학적 성질

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

Dissociation Constants11.3

물리화학적 성질

녹는점: -70 °C · -70°C
끓는 점: 61 · 61-62 °C(lit.)
밀도: 0.847 g/mL · 0.847 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.432(lit.)
인화점: 5 °F · −5 °F
저장 조건: 30 °C · Store below +30°C.
산도 계수 (pKa): 11.29 · 11.29(at 25℃)
물리적 상태: 액체
색상: 무색의
수용성: 혼용 가능
BRN: 102384 · 102384
Henry's Law Constant: 4.8 · 4.8×100 mol/(m3Pa) at 25℃, Ebert et al. (2023)
InChI: 1S/C3H7N/c1-2-4-3-1/h4H,1-3H2
InChIKey: HONIICLYMWZJFZ-UHFFFAOYSA-N
SMILES: C1CNC1
NIST: Azetidine(503-29-7)
EPA: Azetidine (503-29-7)

화학적 성질

clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationAzetidine: HSNO Approval: HSR004353 Approved with controls

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 2733 3/PG 2
HS 번호: 29339990
risk_code: 11-34
hazard_code: F,C
safety_code: 16-26-36/37/39-45
포장분류: I
위험 등급: 3.1
F 고인화성물질: 2-10
Hazard Classifications: Eye Dam. 1Flam. Liq. 2Skin Corr. 1B
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationAzetidine: ACTIVE

응용 분야 · 2건

용도Azetidine is involved in a high yielding palladium-catalyzed cross-coupling reaction with aryl bromides. Further, it is used in Ullmann type coupling reaction with iodonitroflourenes. In addition to this, it reacts with bis-(3-amino-propyl)-amine to prepare N,N'-bis-(3-amino-propyl)-propanediyldiamine using palladium as a catalyst.

일반 설명Phototransformations of azetidine radical cations in freonic matrices under the action of light with λ = 436nm has been investigated. The IR spectrum of azetidine in solid argon matrices has been measured.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

科瑞迪化学400-821-5857 021-64326257 · [email protected]

上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

北京华威锐科化工有限公司0757-86329057 18934348241 · [email protected]

연결된 노트

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Azetidine

기본 정보

개요