로진

Abietic Acid

HCID 10569CAS 15522-12-0

기본 정보

표준 SMILES
CC(C)C1=CC2=CC[C@@H]3[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1
InChIKey
RSWGJHLUYNHPMX-ONCXSQPRSA-N
분자식
C20H30O2
평균 분자량
302.5 g/mol
단동위원소 질량
302.2245802

이름 및 식별자

우선 이름
Abietic Acid
IUPAC
(1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid
현지명
로진
영어명
Rosin
분자식
C19H29COOH
분자량
0

이름 및 동의어

ABIETIC ACID514-10-3Sylvic acidl-Abietic acid7,13-Abietadien-18-oic acid13-Isopropylpodocarpa-7,13-dien-15-oic acidKyselina abietovaV3DHX33184NSC-251491-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-(1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acidDTXSID7022047
이름 더 보기
로진GUM ROSINHYDROGENATED ROSINdisproportionated rosinCOLOPHONYCOLOPHONIUMPOLYMERIZED ROSINRosin Estersrosin-colophonySTAYBELITE RESINBRAZILIAN GUM ROSIN
CHEBI:28987Podocarpa-7,13-dien-15-oic acid, 13-isopropyl-RefChem:5505DTXCID202047208-178-3AbietateRosin AcidMFCD03423567

데이터베이스 식별자

CAS
15522-12-0、514-10-3、8050-09-7
PubChem CID
10569
DTXSID
DTXSID7022047
ChEMBL
CHEMBL71893
ChEBI
CHEBI:28987
UNII
V3DHX33184
EC Number
208-178-3
Nikkaji
J10.135D

물성

구조 계산 물성

XLogP
4.8
극성 표면적
37.3 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
2
회전 가능 결합 수
2
무거운 원자 수
22

실험 및 물리화학적 성질

Boiling Point482 °F at 9 mmHg (NTP, 1992)
Melting Point343 to 345 °F (NTP, 1992)
Physical Description · 2건

Yellowish resinous powder. (NTP, 1992)

Yellow solid; [Hawley] Colorless crystalline solid; [MSDSonline]

Collision Cross Section182.0 Ų [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID8042399]

물리화학적 성질

녹는점
70 · 70-72°C
밀도
1 · 1,07 g/cm3
인화점
180 °C · 180°C
저장 조건
Room Temperature
용해도
0.1 g/mL, · 에 용해됨 클로로포름: 0.1 g/mL, 투명하고 강한 노란색
물리적 상태
분말/고체

화학적 성질

solid with a slight odour of turpentine

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 60.6% (134 of 221) of all reports.

Warning

H315 (38.9%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (38.9%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (38.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (25.3%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 221 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 134 of 221 reports by companies.;There are 9 notifications provided by 87 of 221 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 2건

Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-

1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationPEC / SN / Other assessments - Common skin sensitisers—hazard classification: Health
Fire HazardsCombustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: Slight fire hazard, slight explosive hazard as dust. Low toxicity. (NTP, 1992)
Hazards SummaryA skin and respiratory sensitizer; [CHEMINFO] An irritant; [MSDSonline] Danger of skin sensitization; [MAK] Abietic acid is the active allergen present in colophony. [Marks, p. 80] See Colophony.
Reactive GroupAcids, Carboxylic;Conjugated Dienes

안전 및 보호

Fire FightingA fire in your laboratory involving this chemical should be extinguished with a dry chemical, carbon dioxide or halon extinguisher. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.;RECOMMENDED GLOVE MATERIALS: Permeation data indicate that butyl rubber gloves may provide protection to contact with this compound. Butyl rubber over latex gloves is recommended. However, if this chemical makes direct contact with your gloves, or if a tear, hole or puncture develops, remove them at once. (NTP, 1992)

독성 정보

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.;Asthma - Reversible bronchoconstriction (narrowing of bronchioles) initiated by the inhalation of irritating or allergenic agents.

규제 정보

Regulatory Information · 2건

Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-

1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
VL0480000
HS 번호
38061010
risk_code
43
hazard_code
Xi

화학 및 산업

약리 정보

MeSH Pharmacological Classification · 2건

Fibrinolysin or agents that convert plasminogen to FIBRINOLYSIN.

Substances that eliminate free radicals. Among other effects, they protect PANCREATIC ISLETS against damage by CYTOKINES and prevent myocardial and pulmonary REPERFUSION INJURY.

용도 및 제조

Uses · 2건

Used to make ester gums in lacquers, varnishes, and soaps; Also used in metal resinates, plastics, and paper sizes; [Merck Index]

Pulp and Paper Processing [Category: Industry]

Use ClassificationCosmetics -> Emulsion stabilizing
General Manufacturing Information1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: ACTIVE
응용 분야 · 2건

용도Rosin is a yellow resin in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers, adhesives, surface coatings, polish, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, shoes, violin bow rosin, day, athletic grip aid, pine-oil cleansers; component in dental impression materials and periodontal packings.

일반 설명Gum rosin is an exudate gum, which is extracted from pine trees.

공급사50 곳

北京华美互利生物化工010-56205725 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
成都超九八生物科技有限公司13348960310 13348960310 · [email protected]
추가 설명 · 4건

순도시험(1) 산가 : 이 품목 약 1g을 정밀히 달아 미리 0.1N 수산화칼륨용액을 페놀프탈레인시액에 대하여 중성으로 한 에탄올․에테르의 혼액(1 : 1) 약 50mL에 녹인 액을 시험용액으로 하여 유지류시험법 중 산가의 방법에 따라 시험하였을 때, 그 값은 170~190이어야 한다. (2) 비소 : 이 품목을 비소시험법에 따라 시험할 때, 그 양은 4.0ppm 이하이어야 한다. (3) 납 : 이 품목 5.0g을 취하여 원자흡광광도법 또는 유도결합플라즈마발광광도법에 따라 시험할 때, 그 양은 2.0ppm 이하이어야 한다.

확인시험(1) 이 품목 0.1g을 무수초산 10mL에 넣고 수욕 중에서 가열하여 녹인 다음 식혀 황산을 가할 때, 적자색을 나타낸다.

정의이 품목은 소나무과 소나무(Pinus sp.)의 수피에서 분비물을 채취하여 여과, 정제하여 얻어지는 것이다.

정의A brittle yellow or brown resin that remains after the distillation of turpentine. It is used as a flux in soldering and in making paints and varnishes. Powdered rosin gives a ‘grip’ to violin bows and boxers’ shoes.

관련 반응

14건

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