기본 정보
- 표준 SMILES
CC(C)C1=CC2=CC[C@@H]3[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1- InChIKey
RSWGJHLUYNHPMX-ONCXSQPRSA-N- 분자식
- C20H30O2
- 평균 분자량
- 302.5 g/mol
- 단동위원소 질량
- 302.2245802
이름 및 식별자
- 우선 이름
- Abietic Acid
- IUPAC
- (1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid
- 현지명
- 로진
- 영어명
- Rosin
- 분자식
- C19H29COOH
- 분자량
- 0
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
15522-12-0、514-10-3、8050-09-7- PubChem CID
- 10569
- DTXSID
DTXSID7022047- ChEMBL
CHEMBL71893- ChEBI
CHEBI:28987- UNII
- V3DHX33184
- EC Number
- 208-178-3
- Nikkaji
- J10.135D
물성
구조 계산 물성
- XLogP
- 4.8
- 극성 표면적
- 37.3 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 2
- 무거운 원자 수
- 22
- 형식 전하
- 0
- 복잡도
- 542
실험 및 물리화학적 성질
Physical Description
Yellowish resinous powder. (NTP, 1992)
Yellow solid; [Hawley] Colorless crystalline solid; [MSDSonline]
물리화학적 성질
- 녹는점
- 70 · 70-72°C
- 밀도
- 1 · 1,07 g/cm3
- 인화점
- 180 °C · 180°C
- 저장 조건
- Room Temperature
- 용해도
- 0.1 g/mL, · 에 용해됨 클로로포름: 0.1 g/mL, 투명하고 강한 노란색
- 물리적 상태
- 분말/고체
- 색상
- 진한 노란색
- Specific Gravity
- 1.07 · 1.07~1.08
- 냄새
- 100 · 100.00?%. 마일드한 발사믹 우디
- 수용성
- 알코올, 벤젠, 에테르에 용해됩니다. 물에 불용성
- Merck
- 14 · 14,8266
- Dielectric constant
- 2.5 · 2.5(Ambient)
- 안정성
- 안정적인. 타기 쉬운. 산화제와 호환되지 않습니다.
- 화장품 원료 기능
- 제모제필름 형성제결합제점도 조절
- InChI
- 1S/C20H30O2/c1-13(2)14-6-8-16-15(12-14)7-9-17-19(16,3)10-5-11-20(17,4)18(21)22/h7,12-13,16-17H,5-6,8-11H2,1-4H3,(H,21,22)/t16-,17+,19+,20+/m0/s1
- InChIKey
- RSWGJHLUYNHPMX-ONCXSQPRSA-N
- SMILES
- OC(=O)[C@]1([C@H]2[C@@]([C@H]3CCC(=CC3=CC2)C(C)C)(CCC1)C)C
- LogP
- 13.11 · 13.110 (est)
- EPA
- Rosin (8050-09-7)
화학적 성질
solid with a slight odour of turpentine
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 60.6% (134 of 221) of all reports.
Warning
H315 (38.9%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (38.9%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (38.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (25.3%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 221 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 134 of 221 reports by companies.;There are 9 notifications provided by 87 of 221 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
유해성 정보
Regulatory Information
Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-
1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Reactivity Profile
ABIETIC ACID reacts exothermically with bases, both organic (for example, the amines) and inorganic. Can react with active metals to form gaseous hydrogen and a metal salt. Such reactions are slow if the solid acid remains dry. Can react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slow for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
안전 및 보호
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.;RECOMMENDED GLOVE MATERIALS: Permeation data indicate that butyl rubber gloves may provide protection to contact with this compound. Butyl rubber over latex gloves is recommended. However, if this chemical makes direct contact with your gloves, or if a tear, hole or puncture develops, remove them at once. (NTP, 1992)
독성 정보
규제 정보
Regulatory Information
Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-
1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- rtecs
- VL0480000
- HS 번호
- 38061010
- risk_code
- 43
- hazard_code
- Xi
- safety_code
- 24-37
- 기존화학 물질
- KE-18168
- F 고인화성물질
- 10-21
- Hazard Classifications
- Skin Sens. 1
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
약리 정보
MeSH Pharmacological Classification
Fibrinolysin or agents that convert plasminogen to FIBRINOLYSIN.
Substances that eliminate free radicals. Among other effects, they protect PANCREATIC ISLETS against damage by CYTOKINES and prevent myocardial and pulmonary REPERFUSION INJURY.
용도 및 제조
Uses
Used to make ester gums in lacquers, varnishes, and soaps; Also used in metal resinates, plastics, and paper sizes; [Merck Index]
Pulp and Paper Processing [Category: Industry]
응용 분야
용도Rosin is a yellow resin in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers, adhesives, surface coatings, polish, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, shoes, violin bow rosin, day, athletic grip aid, pine-oil cleansers; component in dental impression materials and periodontal packings.
일반 설명Gum rosin is an exudate gum, which is extracted from pine trees.
상·하류 제품 정보
상류 원료
하류 제품
공급사50 곳
추가 설명
순도시험(1) 산가 : 이 품목 약 1g을 정밀히 달아 미리 0.1N 수산화칼륨용액을 페놀프탈레인시액에 대하여 중성으로 한 에탄올․에테르의 혼액(1 : 1) 약 50mL에 녹인 액을 시험용액으로 하여 유지류시험법 중 산가의 방법에 따라 시험하였을 때, 그 값은 170~190이어야 한다. (2) 비소 : 이 품목을 비소시험법에 따라 시험할 때, 그 양은 4.0ppm 이하이어야 한다. (3) 납 : 이 품목 5.0g을 취하여 원자흡광광도법 또는 유도결합플라즈마발광광도법에 따라 시험할 때, 그 양은 2.0ppm 이하이어야 한다.
확인시험(1) 이 품목 0.1g을 무수초산 10mL에 넣고 수욕 중에서 가열하여 녹인 다음 식혀 황산을 가할 때, 적자색을 나타낸다.
정의이 품목은 소나무과 소나무(Pinus sp.)의 수피에서 분비물을 채취하여 여과, 정제하여 얻어지는 것이다.
정의A brittle yellow or brown resin that remains after the distillation of turpentine. It is used as a flux in soldering and in making paints and varnishes. Powdered rosin gives a ‘grip’ to violin bows and boxers’ shoes.
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