Bis(norbornadiene)rhodium(I) tetrafluoroborate

HCID 10915722

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 36620-11-8
표준 SMILES: C1=CC2C=CC1C2.C1=CC2C=CC1C2.F[B-](F)(F)F.[Rh]
InChIKey: ZWPWNBFOFVFMPP-UHFFFAOYSA-N
분자식: C14H16BF4Rh-
평균 분자량: 373.99 g/mol
단동위원소 질량: 374.03417137

이름 및 식별자

우선 이름: Bis(norbornadiene)rhodium(I) tetrafluoroborate
IUPAC: bis(bicyclo[2.2.1]hepta-2,5-diene);rhodium;tetrafluoroborate
영어명: Bis(norbornadiene)rhodium (I) tetrafluoroborate
분자식: C14H8BF4Rh
분자량: 365.93

이름 및 동의어

36620-11-8Bis(norbornadiene)rhodium(I) tetrafluoroborateDTXSID30448239RefChem:329875DTXCID80399060625-230-4Bis(norbornadiene)rhodium (I) tetrafluoroborateMFCD00671775Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate[rh(nbd)2]bf4bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborateChiralyst P374

이름 더 보기

[Rh(ndb)2]BF4BIS(NORBORNADIENE)RH[Rh(norbornadiene)2]BF4Bis(norbornadiene)rhodium(I) tetBis(norbornadiene)rhodium(I) tetrafLbis(diene)tetrafluoroboronic acid(I)BIS(NORBORNADIENE)RHODIUM(I) TETRAFLUOR&Bis(Norbornadiene)Rh(I) TetrafluoroborateBis(norbornadiene)(tetrafluoroborato)rhodium

Rh(nbd)2BF4SC10120C14H16BF4RhC14H16BF4Rh-SCHEMBL695951SCHEMBL29364466Bis[|C-(2,5-norbornadiene)]rhodium(I) TetrafluoroborateAKOS025295231

데이터베이스 식별자

CAS: 36620-11-8
PubChem CID: 10915722
DTXSID: DTXSID30448239
EC Number: 625-230-4

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 5
회전 가능 결합 수: 0
무거운 원자 수: 20
형식 전하: -1
복잡도: 122

물리화학적 성질

녹는점: 209 · 209-211 °C
저장 조건: -20 °C · Inert atmosphere,Store in freezer, under -20°C
물리적 상태: 가루
색상: 빨간색
수용성: 디클로로메탄에 상당히 용해됩니다. 물에 불용성.
InChI: InChI=1S/2C7H4.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*6-7H,5H2;;/q;;-1;+1
InChIKey: NMZDXSXETNAOPO-UHFFFAOYSA-M
SMILES: [B+3]([F-])([F-])([F-])[F-].[Rh+]123456(C7C8CC(C1=C28)C3=7)C1C2CC(C4=C52)C6=1

화학적 성질

dark red

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H228 (33.8%): Flammable solid [Danger Flammable solids]

P210, P234, P235, P240, P241, P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P330, P332+P317, P337+P317, P362+P364, P363, P370+P378, P390, P403, P405, P406, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesFlam. Sol. 1 (33.8%)

안전 데이터

wgk: 3
tsca: No
ridadr: 1325
HS 번호: 28439000
risk_code: 11-34
hazard_code: F,C
safety_code: 16-45-36/37/39-26
포장분류: II
위험 등급: 8
Hazard Classifications: Eye Dam. 1Skin Corr. 1B
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

응용 분야 · 1건

용도Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.