Butyl nitrite (HCID 10996)

개요

Butyl nitrite appears as a yellow oily liquid with a pleasant odor. A mixture of isomers (n-butyl, sec-butyl and tert-butyl). Slightly soluble in water. Slightly less dense than water. Vapors are much heavier than air. Toxic by ingestion, mildly toxic by inhalation. Used to make fuel for jet airplanes.

이름 및 식별자

우선 이름: Butyl nitrite
IUPAC: butyl nitrite
영어명: 1-Butyl nitrite
분자식: C4H9NO2
분자량: 103.12

이름 및 동의어

Butyl nitrite544-16-1N-BUTYL NITRITENitrous acid, butyl ester44P8QG0F3TNSC-8426RefChem:829371208-862-11-Butyl nitriteNitrous Acid Butyl EsterNitrous acid, n-butyl esterN-Butylnitrite

이름 더 보기

P95AT-V1AT-V2NCL-C-56553N-Butynitrite

ButylnitriteNCI-C56553NSC 8426DTXSID8049418n-C4H9ONOMFCD00002058Butyl ester of nitrous acidNBN

데이터베이스 식별자

CAS: 544-16-1
PubChem CID: 10996
DTXSID: DTXSID8049418
ChEMBL: CHEMBL3181968
ChEBI: CHEBI:173360
UNII: 44P8QG0F3T
EC Number: 208-862-1
Nikkaji: J4.511J

물성

구조 계산 물성

XLogP: 1.3
극성 표면적: 38.7 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 3
무거운 원자 수: 7
형식 전하: 0
복잡도: 47

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Nitrates and Nitrites

Flammable agents - 3rd degree

Vapor Pressure81.3 [mmHg]

Physical Description · 2건

Butyl nitrite appears as a yellow oily liquid with a pleasant odor. A mixture of isomers (n-butyl, sec-butyl and tert-butyl). Slightly soluble in water. Slightly less dense than water. Vapors are much heavier than air. Toxic by ingestion, mildly toxic by inhalation. Used to make fuel for jet airplanes.

Oily liquid; [Merck Index]

물리화학적 성질

끓는 점: 78 °C · 78 °C (lit.)
밀도: 0.882 g/mL · 0.882 g/mL at 25 °C (lit.)
증기압: 760 mm · 760 mm Hg ( 78 °C)
굴절률: 20 · n20/D 1.376(lit.)
인화점: 8 °F · 8 °F
저장 조건: 2 · 2-8°C
용해도: 알코올: 혼화성(lit.)
물리적 상태: 투명한 액체
색상: 밝은 노란색에서 노란색까지
수용성: 약간 용해됨
Merck: 14 · 14,1582
BRN: 1701036 · 1701036
안정성: 감광성, 휘발성
InChI: 1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3
InChIKey: NALZTFARIYUCBY-UHFFFAOYSA-N
SMILES: CCCCON=O
LogP: 2.35 · 2.35
NIST: n-Butyl nitrite(544-16-1)
EPA: Butyl nitrite (544-16-1)

화학적 성질

CLEAR YELLOW LIQUID

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H225: Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P316, P303+P361+P353, P304+P340, P316, P321, P330, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P316, P303+P361+P353, P304+P340, P316, P321, P330, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 3건

Status: Active Update: 29-11-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/24419

Butyl nitrite: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Nitrous acid, butyl ester: Environment tier I assessment

DOT LabelFlammable Liquid

Fire HazardsExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Health HazardsExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Hazards SummaryVasodilator effects similar to amyl nitrate; [Merck Index] An irritant; May cause lacrimation; Can induce methemoglobinemia; [MSDSonline]

안전 및 보호

Fire FightingExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

First AidExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Nonfire Spill ResponseExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Isolation and EvacuationExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

독성 정보

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect

Toxicity DataLC50 (rat) = 420 ppm/4h

안전 데이터

wgk: 1
tsca: TSCA listed
rtecs: RA0780000
ridadr: UN 2351 3/PG II/III (BUTYL NITRITES)
독성: LD50 orally in Rabbit: 83 mg/kg
HS 번호: 29209090
risk_code: 11-23/25
hazard_code: F,T
safety_code: 16-24-45
포장분류: II
위험 등급: 3.1
F 고인화성물질: 8-10-23
Hazard Classifications: Acute Tox. 2 InhalationAcute Tox. 3 OralFlam. Liq. 2
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

약리 정보

MeSH Pharmacological ClassificationDrugs used to cause dilation of the blood vessels.

Cellular LocationsCytoplasm

용도 및 제조

UsesUsed to make rare earth azides; [Merck Index]

General Manufacturing InformationNitrous acid, butyl ester: ACTIVE

응용 분야 · 1건

일반 설명A yellow oily liquid with a pleasant odor. A mixture of isomers (n-butyl, sec-butyl and tert-butyl). Slightly soluble in water. Slightly less dense than water. Vapors are much heavier than air. Flash point about 15°F. Toxic by ingestion, mildly toxic by inhalation. Used to make fuel for jet airplanes.

상·하류 제품 정보

상류 원료

하류 제품

Chlorphoxim 2-Amino-5-hydroxypyridine DESACETYLVINBLASTINEAMIDE 쿠페론 네오쿠페론 4-N-Boc-2-메틸-피페라진 4-아미노살리실 산

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

江西益众化工有限公司15307925109 15350027073 · [email protected]

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

연결된 노트

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Butyl nitrite

기본 정보

개요