Lithium diisopropylamide mono(tetrahydrofuran)

HCID 10997623

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 123333-84-6
표준 SMILES: C1CCOC1.CC(C)[N-]C(C)C.[Li+]
InChIKey: YTJXGDYAEOTOCG-UHFFFAOYSA-N
분자식: C10H22LiNO
평균 분자량: 179.3 g/mol
단동위원소 질량: 179.18614387

이름 및 식별자

우선 이름: Lithium diisopropylamide mono(tetrahydrofuran)
IUPAC: lithium;di(propan-2-yl)azanide;oxolane
영어명: Lithium diisopropylamide mono(tetrahydrofuran)
분자식: C6H15N.C4H8O.Li
분자량: 180.24

이름 및 동의어

LITHIUM DIISOPROPYLAMIDE MONO(TETRAHYDROFURAN)116912-61-9lithium;di(propan-2-yl)azanide;oxolaneLDA THFLDA.THFlithiumdiisopropylamide THFlithium diisopropylamide THFSCHEMBL304794DTXSID30924467lithiumdiisopropylamide tetrahydrofuranAKOS015910965lithium diisopropylamide tetrahydorfuran

이름 더 보기

di(propan-2-yl)azanideLITHIUM DIISOPROPYLAMIDE MONO THFLITHIUM DIISOPROPYLAMIDE MONO-THF COMPLEXLithium diisopropylamide mono(tetrahydrofuran) solutionLITHIUM DIISOPROPYLAMIDE MONO(TETRAHYDRO -FURAN), 1.5M SOLN. IN CYCLOHEXANE2-Propanamine, N-(1-methylethyl)-, lithium salt, compd. with tetrahydrofuran (1:1)2-Propanamine, N-(1-methylethyl)-, lithium salt, compd. with tetrahydrofuran (1:1:1)LithiuM diisopropylaMide Mono(tetrahydrofuran), 1.5M solution in cyclohexane, AcroSeal

lithium diisopropylamide tetrahydrofuranlithium diisopropylamide monotetrahydrofuranDB-230583Lithium diisopropylamide mono tetrahydrofuranlithiumdiisopropylamide mono(tetrahydrofuran)lithium diisopropylamide mono (tetrahydrofuran)Lithium N-(propan-2-yl)propan-2-aminide--oxolane (1/1/1)Lithium, [N-(1-methylethyl)-2-propanaminato](tetrahydrofuran)-

데이터베이스 식별자

CAS: 123333-84-6
PubChem CID: 10997623
DTXSID: DTXSID30924467
EC Number: 629-624-7

물성

구조 계산 물성

극성 표면적: 10.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 2
무거운 원자 수: 13
형식 전하: 0
복잡도: 60.6

물리화학적 성질

밀도: 0.816 g/mL · 0.816 g/mL at 25 °C
증기 밀도: 1 · >1 (vs air)
인화점: 1 °F · −1 °F
저장 조건: 2 · 2-8°C
물리적 상태: 액체
색상: 오렌지 레드
InChI: 1S/C6H14N.C4H8O.Li/c1-5(2)7-6(3)4;1-2-4-5-3-1;/h5-6H,1-4H3;1-4H2;/q-1;;+1
InChIKey: YTJXGDYAEOTOCG-UHFFFAOYSA-N
SMILES: [Li+].C1CCOC1.CC(C)[N-]C(C)C

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory.

유해성 정보

Hazard Classes and CategoriesSkin Corr. 1B (100%)

안전 데이터

wgk: 2
ridadr: UN 2924 3/PG 2
risk_code: 45-46-11-34-67-65-50/53-48/20
hazard_code: F,T,N,C
safety_code: 53-16-26-27-36/37/39-45-62-61-60
F 고인화성물질: 1-10
Hazard Classifications: Aquatic Acute 1Aquatic Chronic 1Asp. Tox. 1Eye Dam. 1Flam. Liq. 2Skin Corr. 1BSTOT RE 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야 · 1건

용도Lithium diisopropylamide mono(tetrahydrofuran) can be used:As an initiator in the anionic polymerization ofD,L-lactide.In one of the key synthetic steps for the preparation of phenylacetic acid component of muscarinic M3receptor antagonist.In the synthesis of new sexithiophene derivatives, which are used as electron donor materials in bilayer photovoltaic devices.