트라이페닐 비스무트
Triphenylbismuth
기본 정보
- CAS
603-33-8- 표준 SMILES
c1cc[c]([Bi]([c]2ccccc2)[c]2ccccc2)cc1- InChIKey
ZHXAZZQXWJJBHA-UHFFFAOYSA-N- 분자식
- C18H15Bi
- 평균 분자량
- 440.3 g/mol
- 단동위원소 질량
- 440.09777
개요
structure given in first source
이름 및 식별자
- 우선 이름
- Triphenylbismuth
- IUPAC
- triphenylbismuthane
- 현지명
- 트라이페닐 비스무트
- 영어명
- Triphenylbismuth
- 분자식
- C18H15Bi
- 분자량
- 440.29
이름 및 동의어
Triphenylbismuth603-33-8TriphenylbismuthineTriphenyl bismuthBISMUTHINE, TRIPHENYL-AerotexTrifenylbismutinDTXSID6042498Triphenyl bismuthinePh3BiNSC-465R18732F41W
이름 더 보기
트라이페닐비스무트트라이페닐비스무트트라이페닐비스무TPB(C6H5)3Bitriphenyl-bismuthinTriphenylbismuth,99%Triphenylbismuth,98%
DTXCID4022498RefChem:191900210-033-4triphenylbismuthaneBismuth triphenylBismuth, triphenyl-Caswell No. 896triphenylbismuthin
데이터베이스 식별자
- CAS
603-33-8- PubChem CID
- 11774
- DTXSID
DTXSID6042498- UNII
- R18732F41W
- EC Number
- 210-033-4
- Nikkaji
- J42.067K
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 3
- 무거운 원자 수
- 19
- 형식 전하
- 0
- 복잡도
- 202
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure0.000034 [mmHg]
Physical Description
CBI
Solid; [Merck Index] White to off-white powder; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 78 · 78-80 °C
- 끓는 점
- 310 °C · 310°C
- 밀도
- 1 · 1,585 g/cm3
- 굴절률
- 1.704 · 1.7040
- 인화점
- 242 °C/14mm · 242°C/14mm
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 클로로포름(약간 용해됨), DMSO(약간 용해됨), 메탄올(약간 용해됨)
- 물리적 상태
- 수정 같은
- 색상
- 하얀색
- Specific Gravity
- 1.585 · 1.585
- 수용성
- 불용성
- NIST
- Bismuthine, triphenyl-(603-33-8)
- EPA
- Triphenylbismuth (603-33-8)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.
Warning
H302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Hazard Traits - Bioaccumulation; Environmental Persistence
Bismuthine, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Bismuthine, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Bismuthine, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryMay cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Triphenylantimony.
Hazard Classes and CategoriesAcute Tox. 4 (95.7%)
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- EB2980000
- HS 번호
- 2931900090
- risk_code
- 20/21/22
- hazard_code
- Xn
- safety_code
- 24/25-36/37
- 기존화학 물질
- KE-34734
화학 및 산업
용도 및 제조
UsesUsed as a radiopacifying agent in dental resins and medical devices, polymerization catalyst, and in organic synthesis; [Merck Index]
U.S. Production2023: <50,000 lb
Industry UsesOther
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Bismuthine, triphenyl-: ACTIVE
응용 분야
용도Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.
제조 방법
Triphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.
상·하류 제품 정보
상류 원료
하류 제품
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