Methacrylic Acid → Triphenyl bismuth (V) methacrylate

HRID 1493115

반응식

HRID 1493115 반응식
[C:1]1([Bi:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]([OH:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].C(OO)(C)(C)C>C(OCC)C>[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].[C:14]1([Bi+2:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22]

참가 물질

5

반응물 3

HCID 4093Methacrylic AcidHCID 6410tert-Butyl hydroperoxideHCID 11774Triphenylbismuth

생성물 1

HCID 19830615Triphenyl bismuth (V) methacrylate

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

The general method as outlined by V. A. Dodonov, A. V. Gustichin and T. G. Brilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound. The details of a typical preparation are: Triphenyl bismuthine (4.4 g, 0.01 mol.), methacrylic acid (1.97 g) (0.02 mol), tert-butyl hydroperoxide (1.39 g) were mixed with 20 ml of diethyl ether in a round bottom flask. The contents were stirred overnight (20 hr) at ambient temperature. The volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr to obtain a solid which was analyzed for its metal content.

후처리

  1. customBrilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound
  2. customThe details of a typical preparation
  3. customThe volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr
  4. customto obtain a solid which

출처 및 근거

ORD 기록
ord-32d84826fcbb49c1928fcb3e2ecb49a8
출처 데이터셋
uspto-grants-1991_06
특허 번호
US05021398

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