2-Methyl-3-nitroaniline

HCID 11783

기본 정보

CAS
603-83-8
표준 SMILES
Cc1c(N)cccc1[N+](=O)[O-]
InChIKey
HFCFJYRLBAANKN-UHFFFAOYSA-N
분자식
C7H8N2O2
평균 분자량
152.15 g/mol
단동위원소 질량
152.0585775

개요

2-methyl-3-nitroaniline appears as yellow rhombic needles (from water) or bright yellow powder. (NTP, 1992)

이름 및 식별자

우선 이름
2-Methyl-3-nitroaniline
IUPAC
2-methyl-3-nitroaniline
영어명
2-Methyl-3-nitroaniline
분자식
C7H8N2O2
분자량
152.15

이름 및 동의어

2-Methyl-3-nitroaniline603-83-82-Amino-6-nitrotoluene3-NITRO-O-TOLUIDINEBenzenamine, 2-methyl-3-nitro-o-Toluidine, 3-nitro-2-methyl-3-nitrobenzenamine1-Amino-2-methyl-3-nitrobenzeneDTXSID8025628D3JC433CEB6-nitro-2-aminotoluene6-Amino-2-nitrotoluene
이름 더 보기
-3-nitroaniL3-nitro-o-toluidinMethyl-3-nitroanilLABOTEST-BB LTBB0006222-Methy-3-nitroaniline2-NITRO-6-AMINOTOLUENE
NSC-227939DTXCID505628NSC-25011RefChem:475379210-059-62-methyl-3-nitro-anilineMFCD000077312-methyl-3-nitro-phenylamine

데이터베이스 식별자

CAS
603-83-8
PubChem CID
11783
DTXSID
DTXSID8025628
ChEMBL
CHEMBL1882292
UNII
D3JC433CEB
EC Number
210-059-6
Nikkaji
J85.099C

물성

구조 계산 물성

XLogP
1.8
극성 표면적
71.8 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
3
회전 가능 결합 수
0
무거운 원자 수
11

실험 및 물리화학적 성질

Solubilityless than 1 mg/mL at 73 °F (NTP, 1992)
Boiling Point581 °F at 760 mmHg (decomposes) (NTP, 1992)
Melting Point198 °F (NTP, 1992)
Physical Description2-methyl-3-nitroaniline appears as yellow rhombic needles (from water) or bright yellow powder. (NTP, 1992)

물리화학적 성질

녹는점
88 · 88-90 °C (lit.)
끓는 점
305 °C · 305 °C (lit.)
밀도
1.378 · 1.378
굴절률
1.6394 · 1.6394 (estimate)
인화점
305 °C · 305°C
저장 조건
30 °C · Store below +30°C.

화학적 성질

YELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Chemical: Benzenamine, 2-methyl-3-nitro-

2-Methyl-3-nitroaniline: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelPoison
Fire HazardsFlash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound include skin and eye irritation.
Reactive GroupNitro, Nitroso, Nitrate, and Nitrite Compounds, Organic
Reactivity Profile2-METHYL-3-NITROANILINE is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers. (NTP, 1992)

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

안전 데이터

wgk
3
rtecs
XU8200000
ridadr
UN 2660 6.1/PG 3
HS 번호
29214300
risk_code
23/24/25-33-51/53
hazard_code
T,N

화학 및 산업

응용 분야

용도2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms.

일반 설명Yellow rhombic needles (from water) or bright yellow powder.

제조 방법

생산 방법6-Nitro-o-toluidine is produced by sulfide reduction of 2,6-dinitrotoluene in a process similar to that for 3-nitroaniline or by controlled hydrogenation of 2,6-dinitrotoluene with palladium on a carbon catalyst.

공급사100 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]

관련 반응

112건

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