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벤젠포스포너스디클로라이드

Phenyl phosphorus dichloride

HCID 12573
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
644-97-3
표준 SMILES
ClP(Cl)c1ccccc1
InChIKey
IMDXZWRLUZPMDH-UHFFFAOYSA-N
분자식
C6H5Cl2P
평균 분자량
178.98 g/mol
단동위원소 질량
177.95059215

개요

Benzene phosphorus dichloride appears as a colorless, fuming liquid. Density 1.32 g / cm3. Flash point 102 °C. Corrosive to metals and tissue.

이름 및 식별자

우선 이름
Phenyl phosphorus dichloride
IUPAC
dichloro(phenyl)phosphane
현지명
벤젠포스포너스디클로라이드
영어명
Dichlorophenylphosphine
분자식
C6H5Cl2P
분자량
178.98

이름 및 동의어

Dichlorophenylphosphine644-97-3PhenyldichlorophosphinePhenylphosphonous dichlorideDichloro(phenyl)phosphineBenzenephosphonous dichloridePhenylphosphine dichloridePhosphonous dichloride, phenyl-PHENYL PHOSPHORUS DICHLORIDEBenzene phosphorus dichloridePhenylphosphorus dichloridePhosphine, dichlorophenyl-
이름 더 보기
디클로로(페닐)포스핀벤젠포스포너스디클로라이드페닐 포스포러스 다이클로라이드BPDPhPCl2Dichlorophenylphosphine,97%AURORA KA-1275Phenylphosphonous diDichiorophenylphosphine
Phenylphosphonous acid dichlorideBenzenephosphorus dichloridePhosphonous dichloride, P-phenyl-NSC 66478DTXSID4027282HSDB 2729Benzene phosphorus dichloride (DOT)EINECS 211-425-8

데이터베이스 식별자

CAS
644-97-3
PubChem CID
12573
DTXSID
DTXSID4027282
ChEMBL
CHEMBL1899635
UNII
WRU258L1EW
EC Number
211-425-8
Nikkaji
J34.568G

물성

구조 계산 물성보충 중

XLogP
3.1
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
9
형식 전하
0
복잡도
79.1

실험 및 물리화학적 성질

Chemical Classes · 2건

Other Classes -> Phosphorus Compounds

Corrosives

SpringerMaterials PropertiesSchoenflies notation
Odoracrid, pungent
Density · 2건

1.14 at 77 °F (USCG, 1999) - Denser than water; will sink

1.356 @ 20 °C/4 °C

Color/FormCOLORLESS LIQUID
Solubility · 2건

SOL IN COMMON INERT ORGANIC SOLVENTS

MISCIBLE WITH BENZENE, CARBON DISULFIDE

CorrosivityCorrodes metal, except 316 stainless steel, nickel, or Hastelloy
Flash Point · 2건

215 °F (USCG, 1999)

215 °F OC May be lower because of presence of dissolved phosphorus

Boiling Point · 2건

430 °F at 760 mmHg (USCG, 1999)

224.6 °C @ 760 MM HG; 99-101 °C @ 11 MM HG

Melting Point · 2건

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 1.2% (2 of 171) of reports.

Danger

H290 (63.2%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P390, P403+P233, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 171 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 4건

Chemical: Phosphonous dichloride, phenyl-

Status: Active Update: 27-11-2017 https://echa.europa.eu/registration-dossier/-/registered-dossier/5488

Dichlorophenylphosphine: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive
Fire Hazards · 3건

Special Hazards of Combustion Products: Toxic fumes include oxides of phosphorus and hydrogen chloride.

· EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily.

· EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily.

Fire PotentialFLAMMABLE.
Health Hazards · 3건

Inhalation causes irritation of nose and throat; pulmonary edema may develop following severe exposures. Contact with skin or eyes causes severe burns. Ingestion causes severe burns of mouth and stomach. (USCG, 1999)

화학 및 산업

용도 및 제조

Uses · 3건

Used in oil additives and in the production of plasticizers, polymers, and antioxidants; [HSDB]

ORGANIC SYNTHESIS; FOR DERIVATION OF PLASTICIZERS, POLYMERS, ANTIOXIDANTS; OIL ADDITIVES

CHEM INT, EG, FOR DICHLOROPHENYLPHOSPHINE OXIDE

U.S. Exports · 2건

(1977) No Data

(1979) No Data

U.S. Imports · 2건

(1977) No Data

(1979) No Data

U.S. Production · 2건

(1977) PROBABLY GREATER THAN 2.27X10+6 GRAMS

(1979) PROBABLY GREATER THAN 2.27X10+6 GRAMS

Methods of ManufacturingPROBABLY BY REACTION OF A GRIGNARD REAGENT WITH PHOSPHOROUS TRICHLORIDE
General Manufacturing InformationPhosphonous dichloride, P-phenyl-: ACTIVE

응용 분야

용도Dichlorophenylphosphine and its derivatives are used as an intermediate to make plasticizers, antioxidants, stabilizers, catalysts and high pressure lubricant additives and in lacquer formulatings.

일반 설명A colorless, fuming liquid. Density 1.32 g / cm3. Flash point 102°C. Corrosive to metals and tissue.

상·하류 제품 정보

하류 제품

(R, R) - (-) - 1,2- 비스 [(2- 메 톡시 페닐) (페닐) 포스 피노] 에탄1 1'-Bis(diphenylphosphino)ferrocene

관련 반응

78건
반응 기록 만들기
HRID 94839 반응식
HRID 94839반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 121499 반응식
HRID 121499반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 170559 반응식
HRID 170559반응물로Training data from https://doi.org/10.1039/C8SC04228D (9/10)
HRID 212699 반응식
HRID 212699반응물로Training data from https://doi.org/10.1039/C8SC04228D (6/10)
HRID 224542 반응식
HRID 224542반응물로uspto-grants-1980_11
HRID 247535 반응식
HRID 247535반응물로uspto-grants-1987_11
HRID 247536 반응식
HRID 247536반응물로uspto-grants-1987_11
HRID 267858 반응식
HRID 267858반응물로uspto-grants-1976_03
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-60 °F (USCG, 1999)

-51 °C

Surface Tensionest 25 dynes/cm= 0.025 N/m @ 20 °C
Refractive Index · 2건

INDEX OF REFRACTION: 1.5958 @ 25 °C/D

INDEX OF REFRACTION: 1.6030 @ 20 °C/D

물리화학적 성질

녹는점
51 °C · −51 °C(lit.)
끓는 점
222 °C759 · 222 °C759 mm Hg(lit.)
밀도
1.319 g/mL · 1.319 g/mL at 25 °C(lit.)
굴절률
20 · n20/D 1.597(lit.)
인화점
230 °F · >230 °F
저장 조건
30 °C · Store below +30°C.
물리적 상태
액체
Specific Gravity
1.319 · 1.319 (20℃)
색상
무색투명~미황색
수용성
물과 반응
BRN
508189 · 508189
Henry's Law Constant
6.5 · 6.5×10-1 mol/(m3Pa) at 25℃, Zhang et al. (2010)
NIST
Phosphonous dichloride, phenyl-(644-97-3)
EPA
Phosphonous dichloride, P-phenyl- (644-97-3)

화학적 성질

Colorless to light yellow liqui

· CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

· CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1건

Corrosive to skin and tissue; Emergency treatment: Acids; [HSDB] Reacts with moisture producing hydrogen chloride and heat; May cause severe burns to skin and eyes; Inhalation of high concentrations may cause pulmonary edema; [CAMEO] Causes convulsions in mice after lethal doses; [RTECS] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline]

DOT ID and Guide · 2건

2798 137

2798 137

Reactive GroupAcyl Halides, Sulfonyl Halides, and Chloroformates
Reactivity AlertsWater-Reactive
Reactivity Profile · 1건

BENZENE PHOSPHORUS DICHLORIDE is incompatible with water, with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

DOT Emergency Guidelines · 5건

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Fire or Explosion: EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Health: CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Public Safety: CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas.

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.

For more DOT Emergency Guidelines (Complete) data for PHENYL PHOSPHORUS DICHLORIDE (8 total), please visit the HSDB record page.

DOT Hazard Classification · 4건

Phenyl phosphorus dichloride

UN2798

Class 8 Corrosive material (49 eCFR § 173.136)

PG II: the degree of danger presented by the material is medium

안전 및 보호

Fire FightingExcerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:
Accidental Release Measures · 4건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 3건

Get medical attention following all exposures to this compound.

General First Aid:

General First Aid:

Firefighting HazardsContainers may rupture. Hot liquid is spontaneously flammable because of presence of dissolved phosphorus.
Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting ProceduresLarge amounts of water.
Nonfire Spill ResponseExcerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:
Isolation and Evacuation · 3건

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

Immediate precautionary measure

Immediate precautionary measure

Personal Protective Equipment (PPE) · 2건

Self-contained breathing apparatus; acid-type canister mask; goggles and face shield; rubber gloves; protective clothing. (USCG, 1999)

Self-contained breathing apparatus; acid-type canister mask; goggles & face shield; rubber gloves; protective clothing.

Emergency Response Planning Guidelines · 2건

· When material is not involved in fire, do not use water on material itself.

· When material is not involved in fire, do not use water on material itself.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Human Toxicity ExcerptsHIGH IRRITANT TO SKIN, EYES & MUCOUS MEMBRANES & VIA ORAL & INHALATION ROUTES. HIGH= CAPABLE OF CAUSING DEATH OR PERMANENT INJURY DUE TO EXPOSURES OF NORMAL USE; INCAPACITATING & POISONOUS...
Non-Human Toxicity Excerpts · 2건

SYMPTOMATOLOGY (...INGESTION OR SKIN CONTACT): 1. CORROSION OF MUCOUS MEMBRANES OF MOUTH, THROAT AND ESOPHAGUS, WITH IMMEDIATE PAIN AND DYSPHAGIA. NECROTIC AREAS...GRAYISH WHITE BUT SOON ACQUIRE A BLACKISH DISCOLORATION (YELLOW IN CASE OF NITRIC ACID) & SOMETIMES SHRUNKEN OR WRINKLED TEXTURE... 2. EPIGASTRIC PAIN...MAY BE ASSOC WITH NAUSEA & VOMITING... AT TIMES, GASTRIC HEMORRHAGE MAY BE INTENSE, AND VOMITUS THEN CONTAINS FRESH BLOOD. PROFOUND THIRST. 3. ULCERATION OF ALL MEMBRANES AND TISSUES WITH WHICH THE ACID COMES IN CONTACT. AFTER THE INGESTION OF CONCN MINERAL ACID, THIS CORROSION MAY LEAD WITHIN A FEW HR OR A FEW DAYS TO GASTRIC PERFORATION AND PERITONITIS. 4. CIRCULATORY COLLAPSE WITH CLAMMY SKIN, WEAK & RAPID PULSE, SHALLOW RESP, AND SCANTY URINE. CIRCULATORY EDEMA. /ACIDS/

SYMPTOMATOLOGY.../INGESTION/: 6. LATE ESOPHAGEAL, GASTRIC & PYLORIC STRICTURES & STENOSES, WHICH MAY REQUIRE MAJOR SURGICAL REPAIR, SHOULD BE ANTICIPATED. SIGNS OF OBSTRUCTION COMMONLY APPEAR WITHIN A FEW WK BUT MAY BE DELAYED FOR MONTHS AND EVEN YEARS. PERMANENT SCARS MAY ALSO APPEAR IN THE CORNEA, SKIN AND OROPHARYNX. 7. UNCORRECTED CIRCULATORY COLLAPSE OF SEVERAL HR...MAY LEAD TO RENAL FAILURE & ISCHEMIC LESIONS IN LIVER & HEART. /ACIDS/

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
TB2478000
ridadr
UN 2798
HS 번호
29310095
risk_code
17-25-34-29-37-35-14
hazard_code
F,T
safety_code
26-28-36/37/39-43-45-28A
포장분류
II
위험 등급
8
기존화학 물질
KE-05-0452
F 고인화성물질
10-21
유해 물질 데이터
644-97-3(Hazardous Substances Data)
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 디클로로(페닐)포스핀 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링
98-1-475
디시클로헥실페닐포스핀
Isopropyldiphenylphosphine
페닐포스핀
디에칠페닐포스핀
철 펜타카보닐
3-(하이드록시페닐포스피닐)프로판산
2,5-디클로로-2,5-디메틸헥산
3-Methyl-1-phenyl-2-phospholene 1-oxide
디-tert-butylphenylphosphine
사염화 게르마늄