Triphenylphosphine → Chlorodiphenylphosphine

반응식

[C:1]1([P:7](C2C=CC=CC=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:20]P(Cl)C1C=CC=CC=1>>[Cl:20][P:7]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

반응물 2

HCID 11776Triphenylphosphine

HCID 12573Phenyl phosphorus dichloride

생성물 1

HCID 66180Chlorodiphenylphosphine

실험 절차

At virtually the same temperature, triphenylphosphine also reacts with dichloro(phenyl)phosphine to give chloro(diphenyl)phosphine (German Pat. No. A-3,215,379):

출처 및 근거

ORD 기록: ord-07434c7949944785814f2384f13e7108
출처 데이터셋: uspto-grants-1987_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04708824

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