디알킬디티오인산
O,O-dimethyl phosphorodithioate
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기본 정보
- CAS
756-80-9- 표준 SMILES
COP(=S)(S)OC- InChIKey
CZGGKXNYNPJFAX-UHFFFAOYSA-N- 분자식
- C2H7O2PS2
- 평균 분자량
- 158.18 g/mol
- 단동위원소 질량
- 157.96250809
개요
Dimethyldithiophosphate is an organic thiophosphate.
이름 및 식별자
- 우선 이름
- O,O-dimethyl phosphorodithioate
- IUPAC
- dimethoxy-sulfanyl-sulfanylidene-λ5-phosphane
- 현지명
- 디알킬디티오인산
- 영어명
- Dimethylphosphorodithioate
- 분자식
- C2H7O2PS2
- 분자량
- 158.18
이름 및 동의어
756-80-9O,O-DIMETHYL DITHIOPHOSPHATEO,O-DimethyldithiophosphateDimethyl phosphorodithioateDimethyldithiophosphoric acidDimethyl phosphodithionateO,O-Dimethyl phosphorodithioateO,O-Dimethyl dithiophosphoric acidO,O-Dimethyl phosphorodithioic acid4K09JRW4Z6DTXSID5027306Kyselina O,O-dimethyldithiofosforcna
이름 더 보기
디알킬디티오인산O,O-디메틸수소디씨오포스페이트O,O-Dimethyl S-hydrogen phosphorodithioateDMPTATHIOACIDMP-1MAPBPMAP2K1IP1U.N. 1760METHOTHIOACIDdimethyldithio
DMDTPRefChem:855038DTXCID707306212-053-9DimethylphosphorodithioateDimethyldithiophosphatePhosphorodithioic acid, O,O-dimethyl esterO,O-Dimethyl hydrogen dithiophosphate
데이터베이스 식별자
- CAS
756-80-9- PubChem CID
- 12959
- DTXSID
DTXSID5027306- ChEBI
CHEBI:166461- UNII
- 4K09JRW4Z6
- EC Number
- 212-053-9
- Nikkaji
- J2.109A
물성
구조 계산 물성보충 중
- XLogP
- 1.7
- 극성 표면적
- 51.6 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 4
- 회전 가능 결합 수
- 2
- 무거운 원자 수
- 7
- 형식 전하
- 0
- 복잡도
- 85.7
실험 및 물리화학적 성질
Chemical ClassesOther Classes -> Organophosphates, Other
PesticidesEnvironmental transformation -> Pesticide transformation products (metabolite, successor)
물리화학적 성질
- 끓는 점
- 65 ℃ · 65℃
- 밀도
- 1.29 · 1.29
- 증기압
- 1.33 hPa · 1.33hPa at 48.5℃
- 굴절률
- 1.535 · 1.535
- 저장 조건
- -20 °C · -20°C
- 용해도
- 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
- 물리적 상태
- 투명한 액체
- 산도 계수 (pKa)
- -0.1 · -0.10±0.30(Predicted)
- 색상
- Colorless to Light yellow to Red
- 수용성
- 226 g/L · 226g/L at 20℃
- LogP
- -0.7 at · -0.7 at 22℃
- EPA
- O,O-Dimethyl dithiophosphate (756-80-9)
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P203, P210, P233, P234, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P321, P330, P363, P370+P378, P390, P403+P235, P405, P406, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 30 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H227: Combustible liquid [Warning Flammable liquids]
유해성 정보
Regulatory Information
Hazard Traits - Developmental Toxicity; Neurotoxicity
Status: Active Update: 22-11-2010 https://echa.europa.eu/registration-dossier/-/registered-dossier/10137
Hazards Summary
A human metabolite of many organophosphate pesticides; Emergency treatment: Organophosphates; [HSDB] Dialkyl phosphate metabolites are considered non-toxic and do not inhibit cholinesterase activity like their parent pesticides; May also be found in the environment as a result of organophosphate pesticide degradation; [https://www.cdc.gov/biomonitoring/pdf/OP-DPM_FactSheet.pdf] A severe eye and moderate skin irritant; Causes effects to male fertility index in repeated inhalation studies of rats; [RTECS]
Hazard Classes and Categories
Flam. Liq. 3 (100%)
Flammable liquids - Category 4
안전 및 보호
Cleanup Methods
AN ORGANOPHOSPHATE CONTAINING WASTEWATER IS TREATED AT PH 5-7.5 WITH ACTIVATED SLUDGE. THUS, AN ACTIVATED SLUDGE WAS ACCLIMATIZED IN A CULTURE MEDIUM CONTAINING DIMETHYL DITHIOPHOSPHATE AMMONIUM SALT; THEN THE SLUDGE WAS USED TO TREAT A DIMETHYL DITHIOPHOSPHATE CONTAINING WASTEWATER. THE TOTAL ORG C OF 83-87 PPM WAS REDUCED TO 17-19 PPM AFTER 12 HR OF TREATMENT.
THE ACTIVATED SLUDGE WAS ACCLIMATED TO O,O-DIMETHYL PHOSPHORODITHIOATE BY THE FILL & DRAW METHOD. THE ACCLIMATED, ACTIVATED SLUDGE DEGRADE 500 MG/L IN 7 HR. THE PH OF THE MIXED LIQUOR WAS ADJUSTED TO DEGRADE O,O-DIMETHYL PHOSPHORODITHIOATE & THE OPTIMUM PH WAS 6.5-7.0.
독성 정보
Environmental FateO,O-DIMETHYL DITHIOPHOSPHATE IS PRODUCED AS METABOLITE FROM MANY ORGANOPHOSPHATE INSECTICIDES IN SOIL... EXAMPLES OF SUCH ORGANOPHOSPHATES ARE PHENTHOATE, MALATHION, DIMETHOATE, & SUPRACIDE.
Effluent ConcentrationsO,O-DIMETHYL PHOSPHORODITHIOATE IS A PRECURSOR IN THE PRODUCTION OF SUCH ORGANOPHOSPHORUS PESTICIDES AS MALATHION, DIMETHOATE, ETC, & IS ABUNDANT IN WASTE-WATER OF PESTICIDE MFR.
Probable Routes of Human ExposureDIMETHYL PHOSPHATE & ITS THIODERIVATIVES WERE EXCRETED IN URINE OF HUMANS AFTER OCCUPATIONAL EXPOSURE TO ORGANOPHOSPHORUS PESTICIDES.
Toxicity DataLC50 (rat) = 1,700 mg/m3/4h
안전 데이터
- tsca
- TSCA listed
- HS 번호
- 2920.19.5000
- 유해 물질 데이터
- 756-80-9(Hazardous Substances Data)
화학 및 산업
약리 정보
Metabolism/MetabolitesO,O-DIMETHYL DITHIOPHOSPHATE IS PRODUCED AS METABOLITE FROM MANY ORGANOPHOSPHATE INSECTICIDES IN...PLANTS /&/ ANIMALS... EXAMPLES OF SUCH ORGANOPHOSPHATES ARE PHENTHOATE, MALATHION, DIMETHOATE, & SUPRACIDE.
Absorption, Distribution and ExcretionIN THE UNITED STATES ON A NATIONAL BASIS FOR FISCAL YEAR 1970-74 ANALYSIS OF 267 URINE SAMPLES FROM GENERAL POPULATION REVEALED THE PRESENCE OF DIALKYL PHOSPHATE.
용도 및 제조
Uses
Used to make insecticides such as malathion, azinphos-methyl, phosmet, and methidathion; [HSDB]
CHEM INT FOR MALATHION (INSECTICIDE)
CHEM INT FOR AZINPHOS-METHYL (INSECTICIDE)
CHEM INT FOR PHOSMET (INSECTICIDE)
CHEM INT FOR METHIDATHION (INSECTICIDE)
U.S. Exports
(1979) No Data
(1981) No Data
U.S. Imports
(1979) No Data
(1981) No Data
U.S. Production
(1978) 7.0X10+9 G-EST PRODN FOR PESTICIDE USE
(1982) 7.0X10+9 G-EST PRODN FOR PESTICIDE USE
Consumption PatternsESSENTIALLY 100% AS A CHEM INT FOR INSECTICIDES
Methods of ManufacturingREACTION OF PHOSPHOROUS PENTASULFIDE WITH METHYL ALCOHOL
Use ClassificationEnvironmental transformation -> Pesticide transformation products (metabolite, successor)
General Manufacturing Information
Phosphorodithioic acid, O,O-dimethyl ester: INACTIVE
A SAMPLE OF TECHNICAL GRADE MALATHION CONTAINED O,O-DIMETHYL DITHIOPHOSPHATE.
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