1,2-비스(다이메틸포스피노)에탄

1,2-Bis(dimethylphosphino)ethane

HCID 141059CAS 23936-60-9

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: CP(C)CCP(C)C
InChIKey: ZKWQSBFSGZJNFP-UHFFFAOYSA-N
분자식: C6H16P2
평균 분자량: 150.14 g/mol
단동위원소 질량: 150.07272377

이름 및 식별자

우선 이름: 1,2-Bis(dimethylphosphino)ethane
IUPAC: 2-dimethylphosphanylethyl(dimethyl)phosphane
현지명: 1,2-비스(다이메틸포스피노)에탄
영어명: 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE
분자식: C6H16P2
분자량: 150.14

이름 및 동의어

1,2-Bis(dimethylphosphino)ethane23936-60-99P3522CZ8T1,2-DMPEDTXSID70178649PHOSPHINE, 1,1'-(1,2-ETHANEDIYL)BIS(1,1-DIMETHYL-RefChem:411395DTXCID80101140627-450-62-dimethylphosphanylethyl(dimethyl)phosphaneMFCD00008511Ethylenebis(dimethylphosphine)

이름 더 보기

1,2-비스(다이메틸포스피노)에탄1,2-비스(디메틸포스피노)에탄1,2-비스(다이메틸포스피노)에탄(1,2-BIS(DIMETHYLPHOSPHINO)ETHANE)DMPE98% DMPEMyr2-PGro1,2-Bis(dimethyLBis(dimethylphosphino)ethane1,2-Bis(dimethylphosphino)ethane,97%1,2-Ethanediylbis[dimethylphosphine]

Phosphine, 1,2-ethanediylbis[dimethyl-1,2-Di(dimethylphosphino)ethaneC6H16P2Me2P(CH2)2PMe2ghl.PD_Mitscher_leg0.173SCHEMBL168779UNII-9P3522CZ8TZKWQSBFSGZJNFP-UHFFFAOYSA-

데이터베이스 식별자

CAS: 23936-60-9
PubChem CID: 141059
DTXSID: DTXSID70178649
UNII: 9P3522CZ8T
EC Number: 627-450-6
Nikkaji: J208.108C

물성

구조 계산 물성

XLogP: -0.4
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 3
무거운 원자 수: 8
형식 전하: 0
복잡도: 42.5

물리화학적 성질

녹는점: 0 ℃ · 0℃
끓는 점: 180 °C · 180 °C(lit.)
밀도: 0.9 g/mL · 0.9 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.507(lit.)
인화점: -16 °C · -16 °C
저장 조건: Flammables area
물리적 상태: 액체
Specific Gravity: 0.9 · 0.90.900
색상: 무색의
BRN: 1732994 · 1732994
InChI: 1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3
InChIKey: ZKWQSBFSGZJNFP-UHFFFAOYSA-N
SMILES: CP(C)CCP(C)C

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (97.8%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P222, P231, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P335+P334, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesFlam. Liq. 2 (97.8%)

안전 데이터

wgk: 3
tsca: No
ridadr: UN 1993 3/PG 2
HS 번호: 29310099
risk_code: 11-36/37/38
hazard_code: F,Xi
safety_code: 16-26-36-36/37/39
포장분류: II
위험 등급: 3
기존화학 물질: KE-03097
F 고인화성물질: 10-13-23
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야

용도1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.

일반 설명1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.