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데실 아크릴산

Decyl acrylate

HCID 16541
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
2156-96-9
표준 SMILES
C=CC(=O)OCCCCCCCCCC
InChIKey
FWLDHHJLVGRRHD-UHFFFAOYSA-N
분자식
C13H24O2
평균 분자량
212.33 g/mol
단동위원소 질량
212.17763

개요

N-decyl acrylate is a liquid. Less dense than water and insoluble in water. Hence floats on water. (USCG, 1999)

이름 및 식별자

우선 이름
Decyl acrylate
IUPAC
decyl prop-2-enoate
현지명
데실 아크릴산
영어명
DECYL ACRYLATE
분자식
C13H24O2
분자량
212.33

이름 및 동의어

DECYL ACRYLATEdecyl prop-2-enoaten-Decyl acrylate2-Propenoic acid, decyl esterDTXSID90448730LTY47V4RDHSDB 5130NSC 5929NSC-5929EINECS 218-462-9UNII-0LTY47V4RDBRN 1772028
이름 더 보기
데실아크릴레이트데실아크릴산데실아크릴산데실 아크릴레이트Acrylic acid decylacrylicacid,decylesterpropyleneacidecyl estern-Decyl acrylate, M-2232-propenoicacid,decylesterDecylacrylate(mixedisomers)Decyl acrylate,95%(stabilized with MEHQ)
AI3-03197DTXCID70248734-02-00-01467 (Beilstein Handbook Reference)nDecyl acrylateRefChem:1313522Propenoic acid, decyl esterDECYL ACRYLATE, STABILIZEDFWLDHHJLVGRRHD-UHFFFAOYSA-N

데이터베이스 식별자

CAS
2156-96-9
PubChem CID
16541
DTXSID
DTXSID9044873
ChEMBL
CHEMBL3187720
ChEBI
CHEBI:229422
UNII
0LTY47V4RD
EC Number
218-462-9
Nikkaji
J55.130I

물성

구조 계산 물성

XLogP
5.1
극성 표면적
26.3 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
11
무거운 원자 수
15
형식 전하
0
복잡도
164

실험 및 물리화학적 성질

Chemical ClassesReactive agents - 2nd degree
PolymersPlastics & Rubber -> (Meth)acrylates
SpringerMaterials PropertiesBoiling point
LogP5.46
Density · 3건

0.8781 at 68 °F (USCG, 1999) - Less dense than water; will float

0.8781 at 20 °C/4 °C

Relative density (water = 1): 0.88

Solubility · 2건

VERY SLIGHTLY SOL IN WATER

Solubility in water: poor

Flash Point · 4건

260 °F (USCG, 1999)

227 °C

227 °C (OPEN CUP)

227 °C o.c.

Boiling Point · 2건

473 °F at 760 mmHg (est.) (USCG, 1999)

158 °C @ 50 MM HG

Melting Point · 2건

less than 32 °F (USCG, 1999)

not available

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 13.7% (32 of 233) of reports.

Warning

H315 (86.3%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 233 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

유해성 정보

Regulatory Information · 4건

Chemical: 2-Propenoic acid, decyl ester

2-Propenoic acid, decyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, decyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

2-Propenoic acid, decyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelClass 9
Fire Hazards · 2건

Special Hazards of Combustion Products: May contain acrid smoke and fumes including toxic acrylic acid, one of the most serious eye injury chemcials and a severe skin irritant.

Combustible.

Health HazardsINHALATION: Higher concentrations may cause pronounced pulmonary irritation or edema. Prolonged contact may cause severe damage to tissues. May be fatal if swallowed or absorbed through skin. (USCG, 1999)

화학 및 산업

용도 및 제조

Uses · 2건

Research chemical; [HSDB]

RESEARCH CHEMICAL

U.S. Imports(1983) 1.36x10+9 g /Acrylates & Acrylic Acid/
U.S. Production · 3건

2023: 75,000 - <500,000 lb

(1977) NOT PRODUCED COMMERCIALLY IN US

(1979) NOT PRODUCED COMMERCIALLY IN US

Consumption PatternsESSENTIALLY 100% AS A RESEARCH CHEMICAL
Consumer UsesMonomers
Industry UsesMonomers
Methods of Manufacturing · 2건

ACRYLATES CAN BE PREPARED BY ... DEHYDRATION OF THE CORRESPONDING HYDROXYALKANOIC ACID, SAPONIFICATION OF THE ALKENE NITRILE, CATALYTIC HYDRATION OF ACETYLENE AND CARBON MONOXIDE, OR THE REACTION OF ACETONE WITH HYDROCYANIC ACID. /ACRYLATES/

In ... propylene oxidation process acrolein is first formed by the catalytic oxidation of propylene vapor at high temp in the presence of steam. The acrolein is then oxidized to acrylic acid. ... The acrylic acid is esterified with alcohol to the ... acrylic ester in a separate process. /Acrylic ester monomers/

Formulations/Preparations... Hydroquinone or monomethyl ether hydroquinone are added to acrylic monomers to stabilize them ... . /Acrylic ester monomers/
General Manufacturing Information · 2건

Adhesive Manufacturing

2-Propenoic acid, decyl ester: ACTIVE

응용 분야

일반 설명Liquid. Less dense than water and insoluble in water. Hence floats on water.

관련 반응

26건
반응 기록 만들기
HRID 104839 반응식
HRID 104839생성물로반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 260246 반응식
HRID 260246반응물로uspto-grants-1996_06
HRID 613195 반응식
HRID 613195반응물로uspto-grants-1999_12
HRID 649721 반응식
HRID 649721반응물로uspto-grants-2001_08
HRID 649723 반응식
HRID 649723반응물로uspto-grants-2001_08
HRID 1018399 반응식
HRID 1018399반응물로uspto-grants-2002_11
HRID 1058493 반응식
HRID 1058493반응물로uspto-grants-2003_02
HRID 1058495 반응식
HRID 1058495반응물로uspto-grants-2003_02
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Refractive IndexIndex of refraction: 1.4400 at 20 °C/D
Physical Description · 4건

N-decyl acrylate is a liquid. Less dense than water and insoluble in water. Hence floats on water. (USCG, 1999)

Liquid

Liquid; [ICSC]

LIQUID.

물리화학적 성질

녹는점
-69 °C · -69°C (estimate)
끓는 점
158 °C · 158°C 50mm
밀도
0 · 0,878 g/cm3
굴절률
1.4363 · 1.4363 (estimate)
저장 조건
Keep in dark place,Inert atmosphere,Room temperature
물리적 상태
액체
색상
Clear, colourless
EPA
Decyl acrylate (2156-96-9)
Hazards SummaryA severe skin, eye, and respiratory tract irritant; Acrylates cause skin sensitization, but no data on this substance; [ICSC] A skin irritant and sensitizer; Harmful if inhaled; [MSDSonline]
Reactive GroupAcrylates and Acrylic Acids
EC ClassificationSymbol: Xi, N; R: 36/37/38-51/53; S: (2)-26-28-61; Note: A
TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.
FIFRA Requirements · 1건

/Polymers of acrylic acid esters/ are exempted from the requirements of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops only.

Reactivity AlertsHighly Flammable
Reactivity Profile · 1건

N-DECYL ACRYLATE reacts exothermically with acids to give n-decyl alcohol and acrylic acid. May react vigorous with strong oxidizing acids and generate enough heat to ignite the reaction products. Interaction with caustic solutions also generates heat. Incompatible with alkali metals and hydrides. Polymerizes readily in the presence of heat and light generating much heat. [Handling Chemicals Safely, 1980. p. 250]. Burns to give acrid smoke and fumes that contain toxic acrylic acid, one of the most serious eye injury chemcials and a severe skin irritant.

DOT Hazard Classification · 2건

Decyl acrylate

Marine pollutant

안전 및 보호

Fire Fighting · 2건

Fire Extinguishing Agents: Small fires: dry chemical, CO2, water spray or foam; large fires: water spray, fog or foam. (USCG, 1999)

Use water spray, powder, alcohol-resistant foam, carbon dioxide.

First Aid Measures · 4건

Fresh air, rest.

Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

First AidINHALATION: Move victim to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.
Fire Fighting ProceduresWater or foam may cause frothing ... .
Storage Conditions · 1건

The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. ... The acrylic esters may be stored in mild or stainless steel, or aluminum. /Acrylic acid & derivatives/

Nonfire Spill ResponseNeutralizing Agents for Acids and Caustics: Not appl (USCG, 1999)
Disposal Methods · 1건

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Spillage DisposalPersonal protection: protective clothing. Collect leaking and spilled liquid in covered containers as far as possible.
Preventive Measures · 3건

Awareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Isolation and EvacuationExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Eye PreventionWear safety goggles or eye protection in combination with breathing protection.
Fire PreventionNO open flames.

독성 정보

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
Signs and Symptoms · 4건

Cough. Sore throat.

Redness. Pain.

Redness. Pain.

Abdominal cramps. Burning sensation. Diarrhoea.

Human Toxicity Excerpts · 1건

THE TOXICITY OF THE ACRYLATES DECREASES WITH INCREASING MOLECULAR WEIGHT. ... HUMAN SIGNS & SYMPTOMS FOLLOWING INGESTION OF ACRYLIC MONOMERS INCL COLLAPSE, SEVERE RESPIRATORY DIFFICULTIES, & CNS STIMULATION. INHALATION OF HIGHER CONCN MAY CAUSE MARKED IRRITATION, SALIVATION, CONJUNCTIVAL IRRITATION, & PRONOUNCED PULMONARY IRRITATION OR EDEMA. PROLONGED SKIN OR EYE CONTACT MAY RESULT IN SEVERE TISSUE DAMAGE. THE PATHOLOGY FROM SINGLE EXPOSURE IS CONTRARY TO REPEATED EXPOSURE EFFECTS, WHICH INCL PULMONARY CONGESTION OR HEMORRHAGE & CLOUDY SWELLING OF LIVER & KIDNEY. /ACRYLATES/

Non-Human Toxicity Excerpts · 2건

Acrylic acid decyl ester (mixed isomers) has been tested externally on the eyes of rabbits & ... rated 1 on scale of 1 to 10 according to the degree of injury observed after 24 hr. The most severely injurious substances have been rated 10. /Mixed isomers/

Contact sensitivity was produced in Guinea pigs with mono-, di-, and tri- acrylate compounds. /Mono-, di-, and tri- acrylate compounds/

규제 정보

TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.
FIFRA Requirements · 1건

/Polymers of acrylic acid esters/ are exempted from the requirements of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops only.

안전 데이터

tsca
TSCA listed
ridadr
3082
HS 번호
2916120090
risk_code
36/37/38-51/53
hazard_code
Xi,N
safety_code
26-28-61
기존화학 물질
KE-09537
유해 물질 데이터
2156-96-9(Hazardous Substances Data)

상·하류 제품 정보

상류 원료

1-(알릴옥시)데칸1-옥사시클로테트라데칸-2-온1,15-Dioxacyclooctacosane-14,28-dione데실산나트륨1,10-데칸디올10-요오도-1-데칸올10-Bromodecanol아세틸렌아크릴산acrylic acid methyl ester데실 알코올