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수산화리튬1수화물

Lithium hydroxide, monohydrate

HCID 168937
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
1310-66-3
표준 SMILES
O.[Li+].[OH-]
InChIKey
GLXDVVHUTZTUQK-UHFFFAOYSA-M
분자식
H2O.HLiO
평균 분자량
42 g/mol
단동위원소 질량
42.02930777

개요

Small colorless crystals. Denser than water. Contact may cause severe irritation to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make electric storage batteries, soaps, and lubricants.

이름 및 식별자

우선 이름
Lithium hydroxide, monohydrate
IUPAC
lithium;hydroxide;hydrate
현지명
수산화리튬1수화물
영어명
Lithium hydroxide monohydrate
분자식
Li.HO.H2O
분자량
41.96

이름 및 동의어

Lithium hydroxide monohydrate1310-66-3Lithium hydroxide, monohydrateLithium hydroxide (Li(OH)), monohydrateLithium hydroxide (USP)Lithium hydroxide [USP]RefChem:799552603-454-3lithium hydroxide hydrateLithium hydroxidoHydroxyde de lithiumLiOH-hydrate
이름 더 보기
수산화리튬하이드록시리튬모노수화물하이드록시리튬,모노수화물하이드록시리튬모노수화물수산화리튬일수화물LiOH.H2OLiOHH2OLi.HO.H2OLithium hydrateithium hydroxide monohydrateLithium(1+) hydrate hydroxideLithine hydrateMonohydrate Lithium HydroxideLithium hydroxide mo
LiOH waterlithium;hydroxide;hydratewater LiOHMFCD00149772lithiumhydroxid-hydrateLithium hydroxide H2Olithium hydroxide water76576-67-5

데이터베이스 식별자

CAS
1310-66-3、55622-30-5
PubChem CID
168937
DTXSID
DTXSID8051382
UNII
G51XLP968G
EC Number
603-454-3

물성

구조 계산 물성

극성 표면적
2 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
3
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical Classes · 2건

Metals -> Metals, Inorganic Compounds

Corrosives

Density · 2건

1.51 g/cm³

1.51 @25 °C

SolubilitySolubility in water, g/100ml at 20 °C: 19.1 (good)
Decomposition924 °C
Melting Point450-471 °C
Physical Description · 4건

Small colorless crystals. Denser than water. Contact may cause severe irritation to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make electric storage batteries, soaps, and lubricants.

Dry Powder

Colorless hygroscopic solid; [ICSC] White odorless crystalline powder; [Alfa Aesar MSDS]

COLOURLESS-TO-WHITE HYGROSCOPIC CRYSTALS.

물리화학적 성질

녹는점
462 °C · 462 °C
끓는 점
920 °C · 920 °C
밀도
1.51 · 1.51
저장 조건
Store at room temperature.
용해도
2 O: · H2O: 1 M at 20 °C, 투명, 무색
물리적 상태
고체

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301+H311 (17.8%): Toxic if swallowed or in contact with skin [Danger Acute toxicity, oral; acute toxicity, dermal]

P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 584 reports by companies from 26 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

유해성 정보

Regulatory Information · 4건

Chemical: Lithium hydroxide, monohydrate

Lithium hydroxide (Li(OH)), monohydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Lithium hydroxide (Li(OH)), monohydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Lithium hydroxide, monohydrate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Lithium hydroxide: Human health tier II assessment
DOT LabelCorrosive
Fire Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Not combustible.

Health HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

화학 및 산업

용도 및 제조

Uses · 2건

Used in photographic developers and alkaline storage batteries; Also used as a catalyst and in esterifications; [Merck Index]

Battery Manufacturing [Category: Industry]

U.S. Production2023: 33,000 lb
Industry UsesNot Known or Reasonably Ascertainable
General Manufacturing InformationNot Known or Reasonably Ascertainable
응용 분야 · 2건

용도Lithium hydroxide monohydrate is used for the production of lithium greases, lithium soaps, lithium stearate and lithium salts. It finds application as a carbon dioxide adsorbent in breathing gas purification systems for spacecrafts, submarines and rebreathers; as a storage-battery electrolyte; as a heat transfer medium and as a catalyst for polymerization reaction. It is also used in ceramics and some portland cement formulations.

일반 설명Small colorless crystals. Denser than water. Contact may cause severe irritation to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make electric storage batteries, soaps, and lubricants. An aqueous solution of a lithium salt below its boiling point has been considered for both a tritium breeding blanket and as a coolant in several fusion reactor designs. In order to breed sufficient tritium to fuel the reactor, a high concentration of lithium is desirable and lithium hydroxide is sufficiently soluble for this purpose. The solution would be contained in pipes and heat exchangers, most probably made from carbon steel.

제조 방법 · 1건

Lithium hydroxide monohydrate may also be made by the evaporation of a solution prepared by the reaction of calcium hydroxide and lithium carbonate.Anhydrous lithium hydroxide may be prepared by heating the monohydrate in air or in a vacuum.

관련 반응

7,504건
반응 기록 만들기
HRID 1672 반응식
HRID 1672반응물로uspto-grants-1998_03
HRID 1675 반응식
HRID 1675반응물로uspto-grants-1998_03
HRID 1676 반응식
HRID 1676반응물로uspto-grants-1998_03
HRID 1678 반응식
HRID 1678반응물로uspto-grants-1998_03
HRID 1683 반응식
HRID 1683반응물로uspto-grants-1998_03
HRID 1695 반응식
HRID 1695반응물로uspto-grants-1998_03
HRID 1698 반응식
HRID 1698반응물로uspto-grants-1998_03
HRID 1699 반응식
HRID 1699반응물로uspto-grants-1998_03
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화합물 노트

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새 노트새 반응견적 요청하기
색상
흰색에서 크림색 또는 노란색
Specific Gravity
1.51 · 1.51
냄새
냄새 없는
수소이온지수(pH)
12 · ~12 (25℃, 1M in H2O)
수용성
109 g/L · 109g/L(20℃)
Merck
14 · 14,5534
안정성
안정적인. 습기와 호환되지 않습니다. 강산, 이산화탄소. 공기 중 이산화탄소를 흡수합니다.
주요 응용
배터리 전구체촉매재료 합성 전구체
InChI
1S/Li.2H2O/h;2*1H2/q+1;;/p-1
InChIKey
WMFOQBRAJBCJND-UHFFFAOYSA-M
SMILES
[Li+].O.[OH-]
NIST
LiOH(1310-66-3)
EPA
Lithium hydroxide (Li(OH)), monohydrate (1310-66-3)
Hazards Summary · 1건

Highly alkaline and caustic; A strong skin irritant; [Merck Index] Causes burns; Inhalation may cause pulmonary edema; [ICSC] May cause severe irritation; Toxic by ingestion, inhalation, and skin absorption; [CAMEO] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion and inhalation; [Alfa Aesar MSDS] See Lithium hydroxide.

Reactive GroupBases, Strong
Reactivity AlertsKnown Catalytic Activity
Reactivity Profile · 1건

LITHIUM HYDROXIDE, MONOHYDRATE neutralizes acids exothermically to form salts plus water. Reacts with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. May serve as a catalyst. Reacts when heated above about 84 °C with aqueous solutions of reducing sugars other than sucrose to evolve toxic levels of carbon monoxide [Bretherick, 5th Ed., 1995].

Chemical Dangers · 1건

Decomposes on heating above 924 °C . This produces toxic fumes. The solution in water is a strong base. It reacts violently with acid and is corrosive to aluminium, tin and zinc. This produces flammable/explosive gas (hydrogen - see ICSC 0001). Reacts with strong oxidants.

Packaging and LabellingDo not transport with food and feedstuffs.
Air and Water ReactionsSoluble in water; heat of dissolution may generate steam and cause spattering.

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4건

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower for at least 15 minutes. Refer immediately for medical attention.

Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.

Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention.

First AidExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Safe StorageSeparated from food and feedstuffs, strong oxidants and strong acids. Store only in original container. Dry. Well closed. Store in an area without drain or sewer access.
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Spillage Disposal · 1건

Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Eye PreventionWear face shield or eye protection in combination with breathing protection.
Inhalation RiskEvaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionPREVENT DISPERSION OF DUST! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Ingestion PreventionDo not eat, drink, or smoke during work.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion. Serious local effects by all routes of exposure.
Signs and Symptoms · 4건

Cough. Sore throat. Burning sensation. Shortness of breath. Laboured breathing.

Redness. Pain. Serious skin burns. Blisters.

Redness. Pain. Blurred vision. Severe deep burns.

Abdominal pain. Burning sensation in the throat and chest. Nausea. Vomiting. Shock or collapse.

ICSC Environmental DataThis substance may be hazardous to the environment. Special attention should be given to aquatic organisms.

안전 데이터

wgk
2
tsca
Yes
rtecs
OJ6307080
ridadr
UN 2680 8/PG 2
HS 번호
28252000
risk_code
22-35-20/22-34-52
hazard_code
C
safety_code
26-36/37/39-45-22-27
포장분류
II
위험 등급
8
F 고인화성물질
3-9-34
Hazard Classifications
Acute Tox. 4 OralEye Dam. 1Skin Corr. 1B
스토리지 클래스
8A - Combustible corrosive hazardous materials

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