1-비닐사이클로헥센

Vinylcyclohexene

HCID 17497CAS 100-40-3

기본 정보

표준 SMILES
C=CC1=CCCCC1
InChIKey
SDRZFSPCVYEJTP-UHFFFAOYSA-N
분자식
C8H12
평균 분자량
108.18 g/mol
단동위원소 질량
108.09390038

개요

Vinylcyclohexene is a colorless liquid. Floats on water. (USCG, 1999)

이름 및 식별자

우선 이름
Vinylcyclohexene
IUPAC
1-ethenylcyclohexene
현지명
1-비닐사이클로헥센
영어명
1-vinylcyclohexene
분자식
C8H12
분자량
108.18

이름 및 동의어

VinylcyclohexeneRefChem:1100992DTXCID801518244DTXSID5010332091-VINYL-3-CYCLOHEXENE100-40-34-Vinyl cyclohexene4-Vinylcyclohexene-1Cyclohexene, 4-ethenyl-1-Vinylcyclohexene1-ETHENYLCYCLOHEXENECyclohexene, 1-ethenyl-
이름 더 보기
1-비닐사이클로헥센1-비닐시클로헥센1-vinylcyclohex-1-ene
1-Vinyl-1-cyclohexene2622-21-1Cyclohexene, ethenyl-Cyclohexene, 1-vinyl-25168-07-41-vinyl-cyclohexene2-Vinylcyclohexene1-ethenylcyclohex-1-ene

데이터베이스 식별자

CAS
100-40-3、25168-07-4、2622-21-1
PubChem CID
17497
DTXSID
DTXSID6051934
EC Number
220-070-8
Nikkaji
J192.129K

물성

구조 계산 물성

XLogP
2.8
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
1
무거운 원자 수
8

실험 및 물리화학적 성질

Chemical Classes · 2건

Other Classes -> Aliphatics, Unsaturated

Other Classes -> Other Organic Compounds

SpringerMaterials PropertiesOptical coefficient
Density · 3건

0.8303 at 68 °F (USCG, 1999) - Less dense than water; will float

0.8623 @ 15 °C/4 °C

0.83

Solubility · 2건

1 to 10 mg/mL at 67.1 °F (NTP, 1992)

INSOL IN WATER; SOL IN ETHER & BENZENE; VERY SOLUBLE IN METHYL ALCOHOL

Flash Point · 2건

60 °F (NTP, 1992)

60 °F

Boiling Point · 3건

259 to 261 °F at 760 mmHg (NTP, 1992)

145 °C @ 760 MM HG

259-261 °F

물리화학적 성질

끓는 점
137.85 °C · 137.85°C (rough estimate)
밀도
0.8623 · 0.8623
굴절률
1.4915 · 1.4915
Henry's Law Constant
7.7 · 7.7×10-4 mol/(m3Pa) at 25℃, Hilal et al. (2008)
EPA
1 · Cyclohexene, 1-ethenyl- (2622-21-1)

화학적 성질

Vinylcyclohex-1-ene is a flammable liquid.

안전 및 규제

유해성 정보

Regulatory Information · 4건

Chemical: Cyclohexene, 4-ethenyl-

Chemical: Cyclohexene, ethenyl-

Cyclohexene, 4-ethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexene, 4-ethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

4-Vinyl cyclohexene: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Cyclohexene, 4-ethenyl-: Human health tier II assessment
DOT LabelFlammable Liquid
Fire HazardsSpecial Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.
Health HazardsExposure can cause irritation of eyes, nose and throat. High concentrations have a narcotic effect. (USCG, 1999)
Hazards SummaryCauses male and female reproductive damage in high-dose animal studies; [ACGIH] Narcosis/anesthesia induced when inhaled at high concentrations; [HSDB]

안전 및 보호

Fire FightingFire Extinguishing Agents Not to Be Used: Water.
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Threshold Limit Values (TLV) · 2건

0.1 [ppm]

0.1 ppm [1994]

Personal Protective Equipment (PPE)Full impervious protective clothing, including boots and gloves. Where splashing is possible wear full face shield or chemical safety goggles. Use approved respirator to protect against vapors. (USCG, 1999)

독성 정보

Adverse EffectsNeurotoxin - Acute solvent syndrome
Toxicity Data · 2건

LCLo (rat) = 8,000 ppm/4H

LC50 (rat) = 10,500 mg/m3/4hr

안전 데이터

tsca
TSCA listed
기존화학 물질
KE-35355
유해 물질 데이터
2622-21-1(Hazardous Substances Data)

화학 및 산업

용도 및 제조

Uses · 3건

Used as an intermediate; [HSDB] In the past, highest concentrations were found in personal air samples of polymer production workers (styrene/butadiene and vinylnorborene production) at about 5 ppm and in Russian rubber workers at a mean of 270 to 540 ppm. [ACGIH]

Used as a research chemical; No known commercial production for sale in the US; [HSDB]

RESEARCH CHEMICAL; CHEM INT (POSSIBLE USE)

U.S. Exports · 2건

(1979) No Data

(1981) No Data

U.S. Imports · 2건

(1979) No Data

(1981) No Data

U.S. Production · 3건

2023: 5,000,000 - <10,000,000 lb

(1977) AT LEAST 4.5X10+8 G-MAY BE A BYPRODUCT

(1981) NO EVIDENCE OF COMMERCIAL PRODN IN U.S.

Consumer UsesIntermediate
Industry UsesAdhesion/cohesion promoter

응용 분야

용도Vinylcyclohex-1-ene is a common component of tobacco smoke thought to be formed by dimerization from butadiene (119). It serves as an important chemical intermediate.

상·하류 제품 정보

공급사1 곳

HONEST JOY HOLDINGS LIMITED[email protected]

관련 반응

15건

연결된 노트

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Vinylcyclohexene (HCID 17497)|Huagongshe