1,2-Epoxydodecane (HCID 17858)

개요

1,2-epoxydodecane is a clear colorless liquid. (NTP, 1992)

이름 및 식별자

우선 이름: 1,2-Epoxydodecane
IUPAC: 2-decyloxirane
현지명: 도데센(1,2-)옥사이드
영어명: 1,2-Epoxydodecane
분자식: C12H24O
분자량: 184.32

이름 및 동의어

1,2-EPOXYDODECANE2855-19-81-Dodecene oxideOxirane, decyl-Decyloxirane1,2-Dodecene oxideDecyl oxiraneDodecene epoxideDodecane, 1,2-epoxy-Nedox 12001,2-Dodecane oxide1,2-Epoxy-n-dodecene

이름 더 보기

도데센(1,2-)옥사이드도데켄-1-산화물도데켄-1-산화물(DODECENE-1-OXIDE)1,2-에폭시도데케인2-DecyloxiraneEDD1-DODECENE EPOXIDEDD5EDD1hHYDnedox1200Vikolox-12

1,2-Epoxy-N-dodecane1,2-Epoxydodekanalpha-Dodecene oxideNSC 6785CCRIS 2616DTXSID9025243HSDB 5538EINECS 220-667-3

데이터베이스 식별자

CAS: 2855-19-8
PubChem CID: 17858
DTXSID: DTXSID9025243
ChEMBL: CHEMBL3183029
UNII: 736974CF3U
EC Number: 220-667-3
Nikkaji: J13.742A

물성

구조 계산 물성

XLogP: 5.2
극성 표면적: 12.5 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 9
무거운 원자 수: 13
형식 전하: 0
복잡도: 112

실험 및 물리화학적 성질

PolymersPlastics & Rubber -> Epoxides

SpringerMaterials PropertiesOptical coefficient

Density0.844 (NTP, 1992) - Less dense than water; will float

Solubilityless than 1 mg/mL at 73 °F (NTP, 1992)

Flash Point · 2건

112 °F (NTP, 1992)

44 °C

Boiling Point255 to 257 °F at 15 mmHg (NTP, 1992)

물리화학적 성질

끓는 점: 124 · 124-125 °C/15 mmHg (lit.)
밀도: 0.844 g/mL · 0.844 g/mL at 25 °C (lit.)
증기압: 2 mmHg · 2 mmHg ( 100 °C)
굴절률: 1.435 · 1.435-1.437
인화점: 105 °C · 105 °C
저장 조건: 2 · 2-8°C
물리적 상태: 투명한 액체
Specific Gravity: 0.844 · 0.844
색상: 무색 내지 거의 무색
생물학적 소스: goat
수용성: 물과 섞이지 않습니다.
BRN: 105569 · 105569
InChI: 1S/C12H24O/c1-2-3-4-5-6-7-8-9-10-12-11-13-12/h12H,2-11H2,1H3
InChIKey: MPGABYXKKCLIRW-UHFFFAOYSA-N
SMILES: CCCCCCCCCCC1CO1
LogP: 5.9 at · 5.9 at 20℃
NIST: Oxirane, decyl-(2855-19-8)
EPA: 1 · 1,2-Epoxydodecane (2855-19-8)

화학적 성질

clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 174 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H315: Causes skin irritation [Warning Skin corrosion/irritation]

유해성 정보

Regulatory Information · 4건

Chemical: Oxirane, decyl-

Oxirane, 2-decyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-decyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-03-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/12323

1,2-Epoxydodecane: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Long-chain alkyl oxiranes: Human health tier II assessment

DOT LabelFlammable Liquid

Fire HazardsThis chemical is combustible. (NTP, 1992)

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin, eyes, mucous membranes and upper respiratory tract.

Hazards SummaryA tumorigen; [RTECS] A skin, eye, mucous membrane, and upper respiratory tract irritant; [CAMEO] An irritant; [MSDSonline]

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

독성 정보

Non-Human Toxicity ExcerptsCARCINOGENIC POTENTIAL OF 1,2-EPOXYDODECANE RESULTED IN 0/30 MICE AFTER DERMAL APPLICATION TO MICE. /FROM TABLE/

안전 데이터

wgk: 1
tsca: TSCA listed
rtecs: JR2450000
HS 번호: 29109000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36-37/39
기존화학 물질: KE-09561
F 고인화성물질: 10-23
Hazard Classifications: Aquatic Acute 1Aquatic Chronic 1Skin Irrit. 2
스토리지 클래스: 10 - Combustible liquids
유해 물질 데이터: 2855-19-8(Hazardous Substances Data)

화학 및 산업

용도 및 제조

Uses · 2건

Used as a secondary heat stabilizer for polymers; No known commercial production in the US; [HSDB]

SECONDARY HEAT STABILIZER FOR POLYMERS

U.S. Exports · 2건

(1979) No Data

(1981) No Data

U.S. Imports · 2건

(1979) No Data

(1981) No Data

U.S. Production · 3건

2023: 34,534 lb

(1979) NO EVIDENCE OF COMMERCIAL PRODN IN U.S.

(1981) NO EVIDENCE OF COMMERCIAL PRODN IN U.S.

Consumer UsesHeat transferring agent

Industry UsesHeat transferring agent

응용 분야 · 2건

용도In the production of epoxy resins, 1,2-Epoxydodecane is used as a reactive diluent and cross-linking agent which can help to improve the performance and versatility of these industrial materials. In the production of emulsions, foams, and dispersants, 1,2-Epoxydodecane can be used as a surfactant. In pharmaceutical industry, 1,2-Epoxydodecane can be used as a solvent in the production of certain pharmaceuticals, like pyrazolones. In the synthesis of hydroxyurea, 1,2-epoxydodecane is used as an intermediate in the production of a key starting material.

일반 설명Clear colorless liquid.