N-에틸 사이클로헥실아민

N-Ethyl cyclohexylamine

HCID 21609CAS 5459-93-8

기본 정보

표준 SMILES
CCNC1CCCCC1
InChIKey
AGVKXDPPPSLISR-UHFFFAOYSA-N
분자식
C8H17N
평균 분자량
127.23 g/mol
단동위원소 질량
127.13609954

개요

Ethyl-n-cyclohexylamine appears as a clear colorless liquid with an ammonia-like odor. Floats on water and slightly soluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion.

이름 및 식별자

우선 이름
N-Ethyl cyclohexylamine
IUPAC
N-ethylcyclohexanamine
현지명
N-에틸 사이클로헥실아민
영어명
N-Ethylcyclohexylamine
분자식
C8H17N
분자량
127.23

이름 및 동의어

N-Ethylcyclohexylamine5459-93-8N-EthylcyclohexanamineCyclohexanamine, N-ethyl-N-CyclohexylethylamineVulkacit HXAccelerator HXCyclohexylamine, N-ethyl-(Ethylamino)cyclohexaneN-ETHYL CYCLOHEXYLAMINECyclohexane, (ethylamino)-YJK13P0H3E
이름 더 보기
N-에틸사이클로헥실아민N-에틸 사이클로헥실아민NECHANsc6272vulkacithxWln: L6tj am2acceleratorhx
NSC-6272DTXSID8063913RefChem:1091728DTXCID7041754226-733-8Cyclohexyl(ethyl)amineN-Ethyl(cyclohexyl)amineEthylcyclohexylamine

데이터베이스 식별자

CAS
5459-93-8
PubChem CID
21609
DTXSID
DTXSID8063913
UNII
YJK13P0H3E
EC Number
226-733-8
Nikkaji
J23.471K

물성

구조 계산 물성

XLogP
2
극성 표면적
12 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
1
회전 가능 결합 수
2
무거운 원자 수
9

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Amines, Aliphatic

Corrosives

Density · 2건

0.8527 at 77 °F (USCG, 1999) - Less dense than water; will float

0.868 @ 0 °C/0 °C

SolubilitySLIGHTLY SOL IN WATER; SOL IN ALL PROP IN ALCOHOL, ETHER
Flash Point · 2건

85 °F ; 115 °F (cc) (USCG, 1999)

86 °F OC

Boiling Point · 2건

329 °F at 760 mmHg (USCG, 1999)

164 °C @ 760 MM HG

Melting Point-49 °F (USCG, 1999)

물리화학적 성질

녹는점
-15 °C · -15°C (estimate)
끓는 점
165 °C · 165 °C (lit.)
밀도
0.844 g/mL · 0.844 g/mL at 25 °C (lit.)
증기 밀도
4.4 · 4.4 (vs air)
증기압
2 mm · 2 mm Hg ( 20 °C)
굴절률
20 · n20/D 1.452(lit.)

화학적 성질

Clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 212 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: Cyclohexanamine, N-ethyl-

Status: Active Update: 20-05-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/11208

Cyclohexanamine, N-ethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire HazardsBehavior in Fire: Dangerous when exposed to heat or flame. Can react vigorously with oxidizing materials. (USCG, 1999)
Fire PotentialDANGEROUS, WHEN EXPOSED TO HEAT, FLAME, OR OXIDIZERS
Health HazardsInhalation of high concentration of vapor will produce irritation of the respiratory tract and lungs. Inhalation of large quantities of vapor may be fatal. (USCG, 1999)
Hazards Summary · 1건

Corrosive and toxic; [Hawley] External application to rabbit eyes scored 9 on a scale of 1-10 (10 being most severe) for degree of injury after 24 hours; Emergency treatment: Irritants; [HSDB] Lung and respiratory tract irritant; [CAMEO] Vapor is irritating to eyes, nose, and throat; Liquid can burn skin and eyes; [CHRIS] A severe skin and eye irritant; [RTECS] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may result in chemical pneumonitis; [Alfa Aesar MSDS]

안전 및 보호

Fire FightingExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
First AidINHALATION: Remove from exposure area. Prompt medical attention required.
Fire Fighting ProceduresALCOHOL FOAM, MIST, SPRAY, DRY CHEMICAL
Nonfire Spill ResponseExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Personal Protective Equipment (PPE)Gas mask suitable for ammonia; face shield or splash proof goggles; rubber gloves. If entering spill area, wear self-contained breathing apparatus and full protective clothing, including boots. (USCG, 1999)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Non-Human Toxicity Excerpts...RATED 9 ON RABBIT EYES. /SUBSTANCE HAS BEEN TESTED EXTERNALLY & RATED ON A SCALE OF 1-10 ACCORDING TO DEG OF INJURY OBSERVED AFTER 24 HR. MOST SEVERE INJURIES HAVE BEEN RATED 10./
Toxicity DataLCLo (rat) = 500 ppm/4h

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
GX1225000
ridadr
UN 2734 8/PG 2
HS 번호
29213000
risk_code
10-20/21/22-35

화학 및 산업

용도 및 제조

UsesUsed as intermediate in the production of herbicides and pharmaceuticals; [Hawley]
General Manufacturing InformationCyclohexanamine, N-ethyl-: ACTIVE

응용 분야

용도N-Ethylcyclohexylamine can be used in the synthesis of a series of isatin-N-Mannich bases.

일반 설명A clear colorless liquid with an ammonia-like odor. Floats on water and slightly soluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion.

제조 방법 · 1건

생산 방법N-Ethylcyclohexylamine is produced by hydrogenation of ethylaniline at 180 ℃ and 6 MPa or by amination of cyclohexanone under hydrogenation conditions in the presence of ethylamine. The amine is a starting material for the preplant sugar beet, grass, and spinach herbicide cycloate (Zeneca's Ro-Neet), which is obtained by converting N-ethylcyclohexylamine into S-ethyl-N-ethyl-N-cyclohexylthiocarbamate. A minor use of N-ethylcyclohexylamine is for vulcanization accelerators.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海沛灵生物科技有限公司13127581762 13127581762 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]

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