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바나듐(V) 옥시클로라이드

Vanadium trichloride oxide

HCID 24410
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7727-18-6
표준 SMILES
Cl.Cl.Cl.[O]=[V]
InChIKey
JNKMSLLEOBTKQY-UHFFFAOYSA-N
분자식
Cl3H3OV
평균 분자량
176.32 g/mol

개요

Vanadium oxytrichloride is a vanadium coordination entity. It has a role as a NMR chemical shift reference compound, a catalyst and an oxidising agent.

이름 및 식별자

우선 이름
Vanadium trichloride oxide
IUPAC
oxovanadium;trihydrochloride
현지명
바나듐(V) 옥시클로라이드
영어명
Vanadium(V) trichloride oxide
분자식
Cl3OV
분자량
173.3

이름 및 동의어

Vanadium trichloride oxideRefChem:901659VANADIUM OXYTRICHLORIDE7727-18-6Vanadyl trichlorideVanadium(V) oxytrichlorideTrichlorooxovanadiumTrichlorooxovanadium oxideVanadium, trichlorooxo-, (T-4)-Vanadium oxide trichlorideTrichlorooxo vanadiumVanadium monoxide trichloride
이름 더 보기
바나듐옥시트리염화물바나듐(V)옥시클로라이드바나듐옥시트리염화물(VANADIUMOXYTRICHLORIDE)바나듐(V)삼염화물산화물Vanadium oxychlorideVANADYL CHLORIDEvanadylic chlorideVANADYL(V) CHLORIDEVanadyl(IV) chloridetrichlorooxo-vanadiuVanadium,trichlorooxo-
Vanadium trichloride monoxideVanadium trichloride monooxideVanadium(V) trichloride oxideVanadium, trichlorooxo-Vanadyl chloride (VOCl3)VOCl3HSDB 1023Vanadium chloride oxide (VOCl3)

데이터베이스 식별자

CAS
7727-18-6
PubChem CID
24410

물성

구조 계산 물성

극성 표면적
17.1 Ų
수소 결합 공여자 수
3
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
5
형식 전하
0
복잡도
6.9

물리화학적 성질

녹는점
76.5 °C · −76.5 °C (−105.7 °F; 196.7 K)
끓는 점
126.7 °C · 126.7 °C (260.1 °F; 399.8 K)
밀도
1.826 g · 1.826 g mL−1
증기압
13.8 mm · 13.8 mm Hg ( 20 °C)
굴절률
1.63 · 1.6300
인화점
Not applicable
용해도
벤젠, 디클로로메탄, 헥산과 혼합 가능.
물리적 상태
liquid
색상
yellow
Specific Gravity
1.84 · 1.84
수용성
2 O에서 · H2O에서 바나드산과 HCl로 분해됩니다. 가용성 메탄올, 에테르, 아세톤, 산 [KIR83] [MER06]
비열
0.52 J/ · Cp(gas): 0.52 J/(g·K), at 25℃
Merck
14 · 14,9927
Dielectric constant
3.6 · 3.6(26℃)
InChI
1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3
InChIKey
JBIQAPKSNFTACH-UHFFFAOYSA-K
SMILES
Cl[V](Cl)(Cl)=O
LogP
0 at · 0 at 20℃
EPA
Vanadium, trichlorooxo-, (T-4)- (7727-18-6)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 4.7% (5 of 107) of reports.

Danger

H301 (92.5%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P262, P264, P264+P265, P270, P273, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 107 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory InformationStatus: Active Update: 21-01-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/12388
Hazard Classes and Categories · 3건

Acute Tox. 3 (92.5%)

Acute toxicity (Oral) - Category 2

Acute toxicity (Oral) - Category 3

안전 및 보호

Minimum Risk LevelAcute Inhalation: 0.0002 mg/m3 (L134) Intermediate Oral: 0.003 mg/kg/day (L134)

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Vanadium is absorbed mainly via inhalation, though small amounts can be absorbed through the skin and gastrointestional tract. It is rapidly distributed in the plasma, mainly to the kidney, liver, lungs, heart, bone, where it tends to accumulate. With the help of cytochrome P-450 enzymes, it can interconvert between its two oxidation states, vanadyl (V+4) and vanadate (V+5). Both states of vanadium can reversibly bind to transferrin protein in the blood and then be taken up into erythrocytes. Vanadium is excreted mainly in the urine. (L837)

용도 및 제조

UsesVanadium oxytrichloride is used as a reagent in organic synthesis. (L841)
응용 분야 · 1건

용도Vanadium(V) trichloride oxide is used as a catalyst in olefin polymerization reaction, especially for the production of ethylene-propylene rubber. It is also used to synthesis organovanadium compounds and as a mordant in dyeing. It acts as a precursor to prepare vanadium pentoxide, vanadyl dichloride and dioxovanadium monochloride. Further, it serves as a reagent and a strong oxidizing agent in organic synthesis.

상·하류 제품 정보

상류 원료

Vanadium (IV) oxide염산염소(기체)염화티탄(Ⅳ)염화알루미늄일염화유황염화 티오닐

관련 반응

21건
반응 기록 만들기
HRID 26178 반응식
HRID 26178반응물로uspto-grants-1979_04
HRID 26179 반응식
HRID 26179반응물로uspto-grants-1979_04
HRID 26180 반응식
HRID 26180반응물로uspto-grants-1979_04
HRID 597602 반응식
HRID 597602반응물로uspto-grants-1977_03
HRID 1264191 반응식
HRID 1264191촉매로uspto-grants-2003_04
HRID 1462975 반응식
HRID 1462975촉매로uspto-grants-1984_07
HRID 1462976 반응식
HRID 1462976촉매로uspto-grants-1984_07
HRID 1462978 반응식
HRID 1462978촉매로uspto-grants-1984_07
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
DTXSID
DTXSID7064784
ChEBI
CHEBI:231500
EC Number
231-780-2

화학적 성질

Lemon-yellow liquid. Nonionizing solvent. Dissolves most nonmetals; dissolves and/or reacts with many organic compounds; hydrolyzes in moisture.

Health EffectsBreathing high levels of vanadium affects the lungs, throat, and eyes. Ingestion of vanadium may cause kidney and liver damage, birth defects, or death. (L837)
Exposure RoutesOral (L837) ; inhalation (L837) ; dermal (L837)
Toxicity Summary · 1건

Vanadium damages alveolar macrophages by decreasing the macrophage membrane integrity, thus impairing the cells' phagocytotic ability and viability. The pentavalent form of vanadium, vanadate, is a potent inhibitor of the Ca+-ATPase and Na+,K+-ATPase of plasma membranes, which decreases intracellular ATP concentration. Vanadium is also believed to induce the production of reactive oxygen species. This may damage DNA and also cause oxidative stress, which can damage the reproductive system. Vanadium also inhibits protein tyrosine phosphatases, producing insulin-like effects. (L837, A247, A248, A249, A250, A251)

Signs and SymptomsInhalation of vanadium causes lung irritation, coughing, wheezing, chest pain, runny nose, and a sore throat. (L837)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Toxicity DataLD50: 140 mg/kg (Oral, Rat) (T14)

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
YW2975000
ridadr
UN 2443
독성
LD50 orally in rats: 0.14 g/kg (Smyth)
risk_code
14-25-34
hazard_code
T
safety_code
26-27-28-36/37/39-45
포장분류
II
위험 등급
8
기존화학 물질
KE-35299
F 고인화성물질
10-21
Hazard Classifications
Acute Tox. 3 OralSkin Corr. 1B
스토리지 클래스
6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
유해 물질 데이터
7727-18-6(Hazardous Substances Data)
포스겐

하류 제품

티타늄바나듐 트리염화물이산화 황바나듐 테트라염화물바나듐(V) 옥시트리이소프로폭사이드Vanadium oxide

공급사46 곳

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