Vanadium trichloride oxide → HCID 178478237, 화합물

반응식

[O:1]=[V:2].[ClH:3].[ClH:4].[ClH:5].[Cl:6][C:7]1[CH:12]=[CH:11][C:10]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[OH:14])=[CH:9][CH:8]=1>>[O-2:14].[Cl:21][C:18]1[CH:19]=[CH:20][C:15]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Cl:6])=[CH:8][CH:9]=2)[O:14][V+2:2]([O:14][Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Cl:6])=[CH:8][CH:9]=2)[C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[O:1][Si:13]([C:15]2[CH:16]=[CH:17][C:18]([Cl:5])=[CH:19][CH:20]=2)([C:22]2[CH:27]=[CH:26][C:25]([Cl:4])=[CH:24][CH:23]=2)[C:10]2[CH:9]=[CH:8][C:7]([Cl:3])=[CH:12][CH:11]=2)=[CH:16][CH:17]=1

참가 물질

반응물 2

HCID 24410Vanadium trichloride oxide

HCID 21324931Tris(4-chlorophenyl)silanol

생성물 1

HCID 178478237HCID 178478237, 화합물

실험 절차

vanadium oxytrichloride was reacted with tri (p-chlorophenyl)-silanol (m.p.= 127°-128° C.) to produce tris [tri-(p-chlorophenyl)-siloxy] vanadium oxide (m.p.== 181° C.);

출처 및 근거

ORD 기록: ord-92084b1c8cd9491197c779b6cc45e269
출처 데이터셋: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04148829

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