기본 정보
- 표준 SMILES
[O-][Br+2]([O-])O- InChIKey
YTFCQDDTLVUOCN-UHFFFAOYSA-N- 분자식
- BrHO3
- 평균 분자량
- 128.91 g/mol
- 단동위원소 질량
- 127.91090599
개요
Bromic acid is a bromine oxoacid. It is a conjugate acid of a bromate.
이름 및 식별자
- 우선 이름
- Bromic acid
- IUPAC
- bromic acid
- 현지명
- 브롬산
- 영어명
- Bromic acid
- 분자식
- BrHO3
- 분자량
- 128.91
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
7789-31-3- PubChem CID
- 24445
- DTXSID
DTXSID7064861- ChEMBL
CHEMBL1161635- ChEBI
CHEBI:49382- UNII
- 908X3OZ87J
- EC Number
- 232-158-3
- Nikkaji
- J95.891C
물성
구조 계산 물성
- XLogP
- -0.1
- 극성 표면적
- 54.4 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 3
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 46.2
실험 및 물리화학적 성질
물리화학적 성질
- 녹는점
- 100 ℃ · decomposes at 100℃ [CRC10]
- 밀도
- 3.28 · 3.28 [HAW93]
- 용해도
- 2 O · soluble in H2O
- 물리적 상태
- 수용액에서만 안정함
- 색상
- stable only in aqueous solution
- 수용성
- 93 · aq미디어에서만 존재할 수 있다 [HAW93]
- EPA
- Bromic acid (7789-31-3)
화학적 성질
colorless or slightly yellowish liquid; stable only in very dilute aqueous solutions; oxidizing agent; used in dyes [HAW93]
안전 및 규제
유해성 정보
독성 정보
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
Health Effects
Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. Bromate is also a potential carcinogen. (L625, L626, L627, L638)
Toxicity Summary
Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)
Signs and Symptoms
Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)
안전 데이터
- tsca
- TSCA listed
- ridadr
- 3139
- 포장분류
- II
- 위험 등급
- 5.1
- 기존화학 물질
- KE-03599
화학 및 산업
약리 정보
Metabolism/Metabolites
Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)
용도 및 제조
응용 분야
용도Oxidizing agent.
제조 방법
Bromic acid is prepared by adding sulfuric acid to barium bromate.Ba(BrO3)2 + H2SO4 → 2HBrO3 + BaSO4The product is distilled and absorbed in water. A 50% solution may be obtained by slow evaporation of the dilute solution in vacuum at -12°C.
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