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Ammonium bisulfate

HCID 24655
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
10043-02-4
표준 SMILES
O=S(=O)([O-])O.[NH4+]
InChIKey
BIGPRXCJEDHCLP-UHFFFAOYSA-N
분자식
H3N.H2O4S
평균 분자량
115.11 g/mol
단동위원소 질량
114.99392864

개요

Ammonium hydrogen sulfate is a colorless to white, powdered solid. It is toxic by ingestion. When heated to high temperatures, it may release toxic sulfur oxide and nitrogen oxide fumes. It is soluble in water. It is a chemical catalyst, used in hair preparations.

이름 및 식별자

우선 이름
Ammonium bisulfate
IUPAC
azanium hydrogen sulfate

이름 및 동의어

AMMONIUM BISULFATEAmmonium hydrogen sulfate7803-63-6Ammonium hydrogensulphateSulfuric acid, monoammonium saltAcid ammonium sulfateUN2506Monoammonium sulfate6218R7MBZBAmmonium acid sulfateAmmonium monohydrogen sulfateMonoammonium hydrogen sulfate
이름 더 보기
DTXSID9051244AMMONIUM SULFATE ((NH4)HSO4)UN-2506AMMONIUM HYDROGEN SULFATE (NH4HSO4)RefChem:112137DTXCID8029866232-265-5Ammonium hydrogensulfate

데이터베이스 식별자

CAS
10043-02-4、7783-20-2、7803-63-6
PubChem CID
24655
DTXSID
DTXSID9051244
UNII
6218R7MBZB
EC Number
232-265-5

물성

구조 계산 물성

극성 표면적
86.8 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
76

실험 및 물리화학적 성질

Chemical Classes · 2건

Other Classes -> Sulfur Compounds

Corrosives

Density1.78 @25 °C
Melting Point146.9 °C
Physical Description · 3건

Ammonium hydrogen sulfate is a colorless to white, powdered solid. It is toxic by ingestion. When heated to high temperatures, it may release toxic sulfur oxide and nitrogen oxide fumes. It is soluble in water. It is a chemical catalyst, used in hair preparations.

Liquid

Deliquescent solid; [Merck Index] Colorless to white deliquescent solid; [CAMEO] Colorless crystalline solid; Hygroscopic; [Aldrich MSDS]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 9.4% (8 of 85) of reports.

Danger

H314 (90.6%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 85 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 6건

Chemical: Sulfuric acid, monoammonium salt

Hazard Traits - Respiratory Toxicity

Sulfuric acid, ammonium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, ammonium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 03-03-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/33165

Ammonium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive
Fire Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

화학 및 산업

용도 및 제조

Uses · 2건

Used in hair-wave preparations and organic catalysts; [Merck Index]

Dressing Hair [Category: Other]

U.S. Production2023: 1,297,154 lb
Industry UsesCleaning agent
General Manufacturing Information · 2건

Transportation Equipment Manufacturing

Sulfuric acid, ammonium salt (1:1): ACTIVE

관련 반응

19건
반응 기록 만들기
HRID 261181 반응식
HRID 261181반응물로uspto-grants-1979_08
HRID 333191 반응식
HRID 333191반응물로uspto-grants-2014_11
HRID 333192 반응식
HRID 333192반응물로uspto-grants-2014_11
HRID 428644 반응식
HRID 428644반응물로uspto-grants-2001_11
HRID 437496 반응식
HRID 437496반응물로uspto-grants-1977_06
HRID 441400 반응식
HRID 441400생성물로uspto-grants-1977_08
HRID 441401 반응식
HRID 441401생성물로uspto-grants-1977_08
HRID 1026783 반응식
HRID 1026783반응물로uspto-grants-2014_05
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Hazards Summary · 1건

Hydrolyzed by water evolving small amounts of heat and sulfuric acid; Toxic by ingestion; [CAMEO] Causes ciliary function changes in 60-minute inhalation study of rabbits; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Aldrich MSDS]

DOT ID and Guide2506 154
Reactive GroupSalts, Acidic
Reactivity Profile · 1건

Acidic salts, such as AMMONIUM HYDROGEN SULFATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

DOT Hazard Classification · 4건

Ammonium hydrogen sulfate

UN2506

Class 8 Corrosive material (49 eCFR § 173.136)

PG II: the degree of danger presented by the material is medium

Air and Water ReactionsAmmonium hydrogen sulfate dissolves in water with the evolution of some heat and hydrolyzes to form some amounts of sulfuric acid. Deliquescent.
Hazard Classes and Categories · 2건

Skin Corr. 1B (90.6%)

Corrosives

안전 및 보호

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

Protective Action Criteria (PAC) · 3건

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire

독성 정보

Adverse EffectsDermatotoxin - Skin burns.