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황산 하이드록실아민

Hydroxylamine sulfate

HCID 24846
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
10039-54-0
표준 SMILES
O=S(=O)([O-])[O-].[NH3+]O.[NH3+]O
InChIKey
VGYYSIDKAKXZEE-UHFFFAOYSA-L
분자식
(NH2OH)2.H2SO4
평균 분자량
164.14 g/mol
단동위원소 질량
164.01030715

개요

Hydroxylamine sulfate is a colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

이름 및 식별자

우선 이름
Hydroxylamine sulfate
IUPAC
hydroxyazanium;sulfate
현지명
황산 하이드록실아민
영어명
Hydroxylamine sulfate
분자식
H2O4S.2H3NO
분자량
164.14

이름 및 동의어

Hydroxylammonium sulfateOxammonium sulfateHydroxylamine sulfate (2:1)Bis(hydroxylamine) sulfateHydroxylamine sulphateHydroxylamine, sulfateHydroxylamine neutral sulfateBis(hydroxylammonium) sulphateHydroxylammoniumsulfatLANASANE LABDTXSID202542449KP498D4O
이름 더 보기
비스(히드록실아민)황산염옥스암모늄황산염히드록실아민중화황산염히드록실아민황산염(2:1)(염)(HYDROXYLAMINESULFATE황산하이드록실아민황산히드록실아민히드록실암모늄황산염히드록실암모늄황산염,히드록실아민황산염,비스(히드록실아민)황산염황산하이드록실암모늄하이드록실아민설페이트옥스암모늄황산염하이드록황산하이드록실아민(HYDROXYLAMINESULFATE)황산 하이드록실아민(2:1)다이(하이드록실아민) 황산염비스(하이드록실암모늄) 설페이트비스(하이드록실암모늄)설페이트비스(하이드록실암모늄)설페이트 H3NO.1/2H2O4S옥시암모늄 설페이트하이드록실 암모늄 설페이트 ((HONH3)2SO4)HASHYDROXYLAMMONIUM SULPHATEHydroxyamine sulfateHydroxylammoniumHuHAS1amine suLHA synthase 1
hydroxyl ammonium sulfateBIS(HYDROXYLAMMONIUM) SULFATEEINECS 233-118-8UN2865UNII-49KP498D4ODTXCID505424HYDROXYLAMINE SULFATE [MI]EC 233-118-8

데이터베이스 식별자

CAS
10039-54-0
PubChem CID
24846
DTXSID
DTXSID2025424
UNII
49KP498D4O
EC Number
233-118-8

물성

구조 계산 물성

극성 표면적
184 Ų
수소 결합 공여자 수
4
수소 결합 수용자 수
6
회전 가능 결합 수
0
무거운 원자 수
9
형식 전하
0
복잡도
64.2

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Hydroxylamines

Corrosives

CosmeticsAntioxidant
LogP-3.6
Density · 2건

greater than 1 at 68 °F (USCG, 1999)

1.88 g/cm³

Solubility · 2건

greater than or equal to 100 mg/mL at 70 °F (NTP, 1992)

Solubility in water, g/100ml at 20 °C: 58.7

Decomposition120 °C
Melting Point · 2건

338 °F (decomposes) (NTP, 1992)

170 °C

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 4건

Hydroxylamine sulfate is a colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

Liquid; Other Solid; Liquid; Dry Powder; Liquid; Large Crystals; Dry Powder

Solid; [Merck Index] White odorless solid; [CHRIS] Colorless crystals; [Sigma-Aldrich MSDS]

WHITE CRYSTALS OR POWDER.

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Warning

H290: May be corrosive to metals [Warning Corrosive to Metals]

P203, P234, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P317, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Warning

H290 (97.9%): May be corrosive to metals [Warning Corrosive to Metals]

P203, P234, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P317, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 5건

Chemical: Hydroxylamine, sulfate (2:1) (salt)

Hydroxylamine, sulfate (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Hydroxylamine, sulfate (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Bis(hydroxylammonium) sulphate (EC: 233-118-8)

Hydroxylamine sulphate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hydroxylamine and its salts: Human health tier II assessment
DOT LabelCorrosive
Fire Hazards · 3건

Special Hazards of Combustion Products: Sulfuric acid fumes may form in fires. (USCG, 1999)

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

화학 및 산업

용도 및 제조

Uses · 2건

Used as a reducing agent in photography, an antioxidant for fatty acids and soaps, and a dehairing agent for hides; [Merck Index] Used mainly as an intermediate for cyclohexanone oxime or caprolactum; Also used as an intermediate (pharmaceuticals, insecticides, herbicides, and artificial sweeteners), photographic developer, vulcanizing accelerator, antioxidant for natural rubber, and inhibitor in plastic polymerizations; Other uses are surface treatment of steel, separation of uranium and plutonium, electroplating of metals and plastics, and fixing textile dyes; [EU Risk Assessment]

Steel Producing [Category: Industry]

U.S. Production2023: 500,000,000 - <1,000,000,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesChelating agent
Use ClassificationCosmetics -> Antioxidant
General Manufacturing Information · 2건

All Other Chemical Product and Preparation Manufacturing

Hydroxylamine, sulfate (2:1): ACTIVE

응용 분야

용도Hydroxylamine sulfate may be used to prepare highly sensitive cellulose tape, used for the detection of formaldehyde gas. It may be used in the quantitative determination of perchlorate in biological fluids by spectrophotometric methods .

일반 설명Colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

제조 방법

Hydroxylamine sulfate may be prepared by mixing stoichiometric amountsof hydroxylamine and sulfuric acid. It also may be prepared by electrolytical-ly reducing an aqueous solution of ammonium sulfate.

관련 반응

24건
반응 기록 만들기
HRID 53401 반응식
HRID 53401반응물로uspto-grants-1997_04
HRID 53402 반응식
HRID 53402반응물로uspto-grants-1997_04
HRID 53403 반응식
HRID 53403반응물로uspto-grants-1997_04
HRID 53404 반응식
HRID 53404반응물로uspto-grants-1997_04
HRID 53405 반응식
HRID 53405반응물로uspto-grants-1997_04
HRID 339296 반응식
HRID 339296생성물로uspto-grants-2014_11
HRID 429526 반응식
HRID 429526반응물로uspto-grants-2001_11
HRID 461618 반응식
HRID 461618반응물로uspto-grants-1977_12
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화합물 노트

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물리화학적 성질

녹는점
170 °C · 170 °C (dec.)(lit.)
끓는 점
56.5 ℃ · 56.5℃
밀도
1.86 · 1.86
증기압
0.001 Pa · 0.001Pa at 20℃
저장 조건
-20 °C · -20°C
용해도
물: 용해될 수 있음(lit.)
물리적 상태
크리스탈
색상
하얀색
수소이온지수(pH)
3.6 · 3.6 (10g/l, H2O, 20℃)
생물학적 소스
mouse
수용성
329 g/L · 329g/L(20℃)
Merck
14 · 14,4828
안정성
안정적이지만 폭발 위험이 있을 수 있습니다. 가열하지 마십시오. 알칼리 존재 시 폭발적으로 분해될 수 있습니다. 공기에 민감합니다. 흡습성. 구리, 구리 합금, 강산화제, 강염기, 아질산염과 호환되지 않습니다.
화장품 원료 기능
항산화제
InChI
1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)
InChIKey
VRXOQUOGDYKXFA-UHFFFAOYSA-N
SMILES
NO.NO.OS(O)(=O)=O
LogP
-1.031 · -1.031 (est)
EPA
Hydroxylamine sulfate (2:1) (10039-54-0)
화학적 성질 · 1건

Also hydroxylammonium sulfate, or HS, (NH2OH)2·H2S04 is colorless crystals that are soluble in water and slightly soluble in alcohol. The solution has a corrosive action on the skin. Used as a reducing agent, photographic developer, purification agent for aldehydes and ketones, chemical synthesis, textile chemical, oxidation inhibitor for fatty acids, catalyst, in biological and biochemical research, for making oximes for paints and varnishes, and rustproofing.

Combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health Hazards · 2건

Inhalation of dust or ingestion may cause systemic poisoning characterized by cyanosis, methemoglobinemia, convulsions, and coma. Contact with eyes or skin causes irritation. (USCG, 1999)

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

Hazards Summary · 1건

A skin irritant; May cause methemoglobinemia, cyanosis, convulsions, hypotension, and coma; [Merck Index] A strong reducing agent; A skin and eye irritant; May cause skin sensitization; May induce methemoglobinemia; Long term or repeated exposure may cause anemia; Can be absorbed through skin; [ICSC] May cause severe skin, eye, and mucous membrane irritation; [CAMEO] A skin and eye irritant; May cause cyanosis, methemoglobinemia, convulsions, and coma; [CHRIS] May explode by shock, friction, fire, or other source of ignition; Reports of occupational contact dermatitis; [ToxPlanet: EU Risk Assessment] Causes irritation or corrosive injuries to skin, eyes, and mucous membranes; [NTP] A skin and strong eye irritant; May cause skin sensitization; Harmful by ingestion; Targets the blood and CNS; [Sigma-Aldrich MSDS] See Hydroxylamine and Hydroxylamine hydrochloride.

DOT ID and Guide2865 154
Reactive GroupSalts, Acidic
EC ClassificationSymbol: Xn, N; R: 22-36/38-43-48/22-50; S: (2)-22-24-37-61
UN ClassificationUN Hazard Class: 8; UN Pack Group: III
Reactivity ProfileSulfuric acid fumes may form in fires (USCG, 1999). Solid hydroxylamine sulfate explodes when heated to 170 °C [Chem. Process 26:30(1963)]. Sodium ignites on contact with hydroxylamine. (Mellor, 1940, Vol. 8, 292.)
Chemical Dangers · 1건

Decomposes on contact with hot surfaces or flames. This produces corrosive fumes of sulfur oxides. The solution in water is a medium strong acid. The substance is a strong reducing agent. It reacts violently with oxidants, powdered metals, nitrates, nitrites and heavy metal salts.

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

First Aid Measures · 4건

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

General First Aid:

Safe StorageSeparated from oxidants, nitrates, nitrites and combustible substances.
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Spillage Disposal · 1건

Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment.

Isolation and Evacuation · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

Eye PreventionWear safety spectacles or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.

독성 정보

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.
Signs and Symptoms · 4건

See Ingestion.

MAY BE ABSORBED! Redness.

Redness. Pain.

Blue lips, fingernails and skin. Confusion. Convulsions. Dizziness. Headache. Nausea. Unconsciousness.

ICSC Environmental DataThe substance is toxic to aquatic organisms.

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
NC5425000
ridadr
UN 2865
독성
LD50 orally in Rabbit: 842 mg/kg LD50 dermal Rabbit 1500 - 2000 mg/kg
HS 번호
28251000
risk_code
22-36/38-43-48/22-50-40-21/22-2
hazard_code
Xn,N,E
safety_code
22-24-37-61-36/37
포장분류
III
위험 등급
8
기존화학 물질
KE-20599KE-03210
F 고인화성물질
21
Hazard Classifications
Acute Tox. 4 DermalAcute Tox. 4 OralAquatic Acute 1Carc. 2Eye Irrit. 2Met. Corr. 1Skin Irrit. 2Skin Sens. 1STOT RE 2 Oral
스토리지 클래스
4.1A - Other explosive hazardous materials
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 히드록실아민과 그 염류 및 그 중 하나를 1% 이상 함유한 혼합물
유해화학물질 필터링
97-1-411

상·하류 제품 정보

상류 원료

에틸알코올이아황산 암모늄, 고체2-부타논 옥심이산화 황메틸에틸케톤아세토시메황산암모늄황산

하류 제품

Ethoxyamine hydrochloride3-(4-니트로-페닐)-이속사졸-5-일라민3-TERT-부틸리속사졸-5-아민황산 산화 납4-히드록시프탈라진-1-카르복실산메토밀5-Amino-3-(4-methoxyphenyl)isoxazole3-이소프로필리속사졸-5-아민2-아자시클록타논3-(3-Nitrophenyl)propionic acid3-클로로-4,4-디메틸펜트-2-에니트릴리누론2-부타논 옥심아세트알독심Levofloxacin3,4-디클로로페닐하이드록시우레아시클로헵타논옥심Benzohydroxamic acid5-Methylisoxazole-3-carbonyl chlorideALDICARB-OXIME메틸3-아미노-5-(tert-부틸)티오펜-2-카르복실레이트4-피리딘알독심카프로락탐3-아미노-5-(TERT-부틸)티오펜-2-카르복스아미드