2,2'-Bis(bromomethyl)-1,1'-biphenyl

HCID 251962

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 38274-14-5
표준 SMILES: BrCc1ccccc1-c1ccccc1CBr
InChIKey: VDXGURZGBXUKES-UHFFFAOYSA-N
분자식: C14H12Br2
평균 분자량: 340.05 g/mol
단동위원소 질량: 337.93057458

이름 및 식별자

우선 이름: 2,2'-Bis(bromomethyl)-1,1'-biphenyl
IUPAC: 1-(bromomethyl)-2-[2-(bromomethyl)phenyl]benzene
영어명: 2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL
분자식: C14H12Br2
분자량: 340.05

이름 및 동의어

2,2'-Bis(bromomethyl)-1,1'-biphenylRefChem:440239628-317-538274-14-52,2'-Bis(bromomethyl)biphenyl1-(bromomethyl)-2-[2-(bromomethyl)phenyl]benzene2,2'-Bis-bromomethyl-biphenyl2,2'-dibromomethyl-1,1'-biphenylMFCD000749102,2'-dibromomethylbiphenylo,o'-Bitolyl, a,a'-dibromo-DTXSID90291081

이름 더 보기

-Bis(bromomethyl)-1,1′2,2'-Bisbromomethyl-biphenyl2,2'-bis(bromethyl)-1,1'-biphenyl2,2'-Bis(broMoMethyl)-1,1'-biphenyl 99%2,2′-Bis(bromomethyl)-1,1′-biphenyl, CAS 38274-14-5

2,2 inverted exclamation marka-Bis(bromomethyl)-1,1 inverted exclamation marka-biphenyl1,1'-Biphenyl, 2,2'-bis(bromomethyl)-2,2'-Bis(bromomethyl)-1,1'-biphenyl, 99%NSC73047FT-0746744NCIOpen2_008806o,o'-Bis(bromomethyl)biphenyl2,2'-di(brommethyl)-diphenyl

데이터베이스 식별자

CAS: 38274-14-5
PubChem CID: 251962
DTXSID: DTXSID90291081
EC Number: 628-317-5
Nikkaji: J725.711B

물성

구조 계산 물성

XLogP: 4.7
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 3
무거운 원자 수: 16
형식 전하: 0
복잡도: 183

실험 및 물리화학적 성질

SpringerMaterials PropertiesChemical shift

물리화학적 성질

녹는점: 90 · 90-92 °C(lit.)
끓는 점: 148 · 148-150 °C(Press: 0.002 Torr)
밀도: 1.591 · 1.591±0.06 g/cm3(Predicted)
저장 조건: 2 · Storage temp. 2-8°C
물리적 상태: 가루
색상: 하얀색
InChI: 1S/C14H12Br2/c15-9-11-5-1-3-7-13(11)14-8-4-2-6-12(14)10-16/h1-8H,9-10H2
InChIKey: VDXGURZGBXUKES-UHFFFAOYSA-N
SMILES: BrCc1ccccc1-c2ccccc2CBr

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P337+P317, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesSkin Corr. 1B (100%)

안전 데이터

wgk: 3
ridadr: UN 3261 8/PG 2
HS 번호: 2902900000
risk_code: 34-36/37
hazard_code: C
safety_code: 26-27-28-36/37/39-45
포장분류: III
위험 등급: 8
Hazard Classifications: Eye Irrit. 2Skin Corr. 1BSTOT SE 3
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

응용 분야 · 1건

용도2,2′-Bis(bromomethyl)-1,1′-biphenyl was used in the preparation of mononuclear rhodium(III) complex with a nine-membered S, S-chelate ring. It was also used in the preparation of 1,1′-binaphthyl-substituted α-aminoisobutyric acid, a new chiral atropoisomeric α,α-disubstituted glycine.