CAS 56183-63-2 Bis(diisopropylamino)chlorophosphine (HCID 2733425)

이름 및 식별자

우선 이름: Bis(diisopropylamino)chlorophosphine
IUPAC: N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-amine
영어명: BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
분자식: C12H28ClN2P
분자량: 266.79

이름 및 동의어

Bis(diisopropylamino)chlorophosphine56183-63-2DTXSID00369907RefChem:569062DTXCID10320943628-718-5MFCD00061482N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-aminePhosphorodiamidous chloride, tetrakis(1-methylethyl)-C12H28ClN2PSCHEMBL1117784bisdiisopropylaminochlorophosphine

이름 더 보기

Bis(diisopropyamino)chlorophosphineChlorobis(N,N-diisopropylamino)phosphineSKL629Bis(diisopropylaminodiisopropylaMino)phosphineChlorbis(diisopropylamino)phosphanChloro-di-N-(diisopropyl)-phosphiteBIS(DI-I-PROPYLAMINO)CHLOROPHOSPHINE

FEHUTHGOLLQBNW-UHFFFAOYSA-NGCA18363Bis(di-isopropylamino)chlorophosphineChloro(bis(diisopropylamino))phosphaneAKOS015910528bis(N,N-diisopropylamino)chlorophosphinebis-(N,N-diisopropylamino)chlorophosphineBP-14118

데이터베이스 식별자

CAS: 56183-63-2
PubChem CID: 2733425
DTXSID: DTXSID00369907
EC Number: 628-718-5
Nikkaji: J1.175.515A

물성

구조 계산 물성

XLogP: 4.4
극성 표면적: 6.5 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 6
무거운 원자 수: 16
형식 전하: 0
복잡도: 159

물리화학적 성질

녹는점: 100 · 100-104 °C(lit.)
끓는 점: 291 ℃ · 291℃
인화점: 130 ℃ · 130℃
저장 조건: Store under inert gas
물리적 상태: 가루
산도 계수 (pKa): 4.5 · 4.50±0.70(Predicted)
색상: 흰색에서 황백색까지
InChI: InChI=1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
InChIKey: FEHUTHGOLLQBNW-UHFFFAOYSA-N
SMILES: P(N(C(C)C)C(C)C)(N(C(C)C)C(C)C)Cl

화학적 성질

white to light yellow crystal powde

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (97.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesSkin Corr. 1B (100%)；Eye Dam. 1 (97.6%)

안전 데이터

wgk: 3
ridadr: UN 3261 8/PG 1
HS 번호: 29310099
risk_code: 14-34
hazard_code: C
safety_code: 26-27-28-36/37/39-45
포장분류: II
위험 등급: 8
Hazard Classifications: Eye Dam. 1Skin Corr. 1B
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

응용 분야 · 2건

개요Bis(diisopropylamino)chlorophosphine is a white to off-white powder to crystalline organophosphorus compound, mainly used as an organic synthetic raw material or reaction reagent. It can be used in the synthesis of mixed phosphorothioate and methylenephosphine derivatives, etc. It is commonly used in chemical production and laboratory research.

용도Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.It is also can be used to synthesize:acyclic N-phosphonio imine catalyst for selective epoxidationsboryl-substituted methylenephosphonium derivatives