O-(Trimethylsilyl)hydroxylamine

HCID 2734666

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기본 정보

CAS: 22737-36-6
표준 SMILES: C[Si](C)(C)ON
InChIKey: AEKHNNJSMVVESS-UHFFFAOYSA-N
분자식: C3H11NOSi
평균 분자량: 105.21 g/mol
단동위원소 질량: 105.0609905

이름 및 식별자

우선 이름: O-(Trimethylsilyl)hydroxylamine
IUPAC: O-trimethylsilylhydroxylamine
영어명: O-(TRIMETHYLSILYL)HYDROXYLAMINE
분자식: C3H11NOSi
분자량: 105.21

이름 및 동의어

O-(Trimethylsilyl)hydroxylamine22737-36-6DTXSID40370436RefChem:167113DTXCID70321471626-309-6O-trimethylsilylhydroxylamineMFCD00010872AminoxytrimethylsilaneTMSONH2O-trimethylsilyl-hydroxylamineO-(Trimethylsilylhydroxyl)amine

이름 더 보기

97% Min.AKOS MSC-0140(Aminooxy)trimethylsilane0-TrimethylsilylhydroxylamineO-(Trimethylsilyl)hydroxylamine,97%O-(TRIMETHYLSILYL)HYDROXYLAMINE,PRACTO-TriMethylsilyl hydroxylaMine Min 97%

Hydroxylamine, O-(trimethylsilyl)-C3H11NOSiO-TMS-hydroxylamineMe3SiONH2SCHEMBL5769O-trimethylsilyl hydroxylamineO-Trimethylsilyl)hydroxylamineSCHEMBL2765497

데이터베이스 식별자

CAS: 22737-36-6
PubChem CID: 2734666
DTXSID: DTXSID40370436
EC Number: 626-309-6
Nikkaji: J1.838.385C

물성

구조 계산 물성

극성 표면적: 35.3 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 2
회전 가능 결합 수: 1
무거운 원자 수: 6
형식 전하: 0
복잡도: 40.5

실험 및 물리화학적 성질

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

물리화학적 성질

끓는 점: 98 · 98-100 °C(lit.)
밀도: 0.86 g/mL · 0.86 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.405(lit.)
인화점: 48 °F · 48 °F
저장 조건: 2 · 2-8°C
물리적 상태: 액체
산도 계수 (pKa): 3.28 · 3.28±0.70(Predicted)
Specific Gravity: 0.86 · 0.860
색상: 무색의
BRN: 2035893 · 2035893
InChI: 1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3
InChIKey: AEKHNNJSMVVESS-UHFFFAOYSA-N
SMILES: C[Si](C)(C)ON

화학적 성질

clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

안전 데이터

wgk: 3
tsca: No
ridadr: UN 2733 3/PG 2
HS 번호: 29310099
risk_code: 11-34
hazard_code: F,C
safety_code: 16-26-36/37/39-45
포장분류: II
위험 등급: 3.1
F 고인화성물질: 10-21
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야

용도O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.

일반 설명O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.