기본 정보
- 표준 SMILES
O.O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[Ca+2].[Ca+2]- InChIKey
ZOMBKNNSYQHRCA-UHFFFAOYSA-J- 분자식
- (CaSO4)2.H2O
- 평균 분자량
- 290.3 g/mol
- 단동위원소 질량
- 289.8392056
개요
Plaster of paris appears as white or yellowish, finely divided, odorless powder consisting mostly or entirely of calcium sulfate hemihydrate, CaSO4*1/2H2O. Forms a paste when it is mixed with water that soon hardens into a solid. Used in making casts, molds, and sculpture. Generally non-toxic.
이름 및 식별자
- 우선 이름
- Calcium Sulfate, Hemihydrate
- IUPAC
- dicalcium;disulfate;hydrate
- 현지명
- 파리의석고(Ca(SO4).1/2H2O)
- 영어명
- Plaster of Paris (Ca(SO4).1/2H2O)
- 분자식
- Ca2H2O9S2
- 분자량
- 0
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
10034-76-1、26499-65-0- PubChem CID
- 3033839
- DTXSID
DTXSID90894798- ChEBI
CHEBI:32584- UNII
- 3RW091J48V
- EC Number
- 600-067-1、607-950-0
물성
구조 계산 물성
- 극성 표면적
- 178 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 9
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 13
- 형식 전하
- 0
- 복잡도
- 62.2
실험 및 물리화학적 성질
Density
2.5 (NIOSH, 2024) - Denser than water; will sink
Density (for the alpha hemihydrate): 2.76 g/cm³
2.5
2.5
Solubility
0.3 % at 77 °F (NIOSH, 2024)
Solubility in water, g/100ml at 25 °C: 0.30
(77 °F): 0.3%
Melting Point
325 °F (Loses H2O) (NIOSH, 2024)
163 °C
325 °F (loses H₂O)
325 °F (Loses H2O)
Vapor Pressure
0 mmHg (approx) (NIOSH, 2024)
0 mmHg (approx)
0 mmHg (approx)
Physical Description
Plaster of paris appears as white or yellowish, finely divided, odorless powder consisting mostly or entirely of calcium sulfate hemihydrate, CaSO4*1/2H2O. Forms a paste when it is mixed with water that soon hardens into a solid. Used in making casts, molds, and sculpture. Generally non-toxic.
Large Crystals
Dry Powder
White or yellowish, finely divided, odorless powder; [NIOSH]
FINE HYGROSCOPIC WHITE POWDER.
White or yellowish, finely divided, odorless powder.
물리화학적 성질
- 녹는점
- 163 °C · 163 °C
- 밀도
- 1.55 g/cm3 · 1.55 g/cm3
- 저장 조건
- -20 °C · -20°C
- EPA
- Plaster of Paris (Ca(SO4).1/2H2O) (26499-65-0)
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 100% (75 of 75) of all reports.
Not Classified
Aggregated GHS information provided per 75 reports by companies from 2 notifications to the ECHA C&L Inventory.
This chemical does not meet GHS hazard criteria for 100% (39 of 39) of all reports.
Not Classified
Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory.
유해성 정보
Regulatory Information
Chemical: Sulfuric acid, calcium salt (1:1), hemihydrate
Sulfuric acid, calcium salt, hydrate (2:2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, calcium salt, hydrate (2:2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Plaster of Paris (Ca(SO4).1/2H2O) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Plaster of Paris (Ca(SO4).1/2H2O) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Calcium sulfate hemihydrate: Does not have an individual approval but may be used under an appropriate group standard
Plaster of Paris (Ca(SO4).1/2H2O): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Reactivity Profile
PLASTER OF PARIS is non-flammable and non-combustible. Has generally low chemical reactivity but can act as an oxidizing agent under extreme conditions. Decomposes at high temperature to generate toxic oxides of sulfur. Reacts exothermically but slowly with moisture in the air or water to form gypsum CaSO4.2H2O.
Hazard Classes and Categories
Not Classified
Not Classified
Specific target organ toxicity - Single exposure - Category 3 (Respiratory tract irritation)
안전 및 보호
First Aid Measures
Fresh air, rest.
Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth.
First Aid
Excerpt from NIOSH Pocket Guide for Plaster of Paris:
(General first aid procedures)
독성 정보
Signs and Symptoms
Cough.
Redness. Pain.
irritation eyes, skin, mucous membrane, respiratory system; cough
안전 데이터
- OEB
- B
- OEL
- TWA: 10 mg/m3 (total)
화학 및 산업
약리 정보
용도 및 제조
U.S. Production
2023: 58,972,905 lb
2023: 34,600 lb
Industry Uses
Other
Filler
Household Products
Information on 15 consumer products that contain Calcium sulfate hemihydrate in the following categories is provided:
Information on 31 consumer products that contain Plaster of paris in the following categories is provided:
General Manufacturing Information
Primary Metal Manufacturing
Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)
응용 분야
일반 설명White or yellowish, finely divided, odorless powder consisting mostly or entirely of calcium sulfate hemihydrate, CaSO4·1/2H2O. Forms a paste when Plaster of Paris (Ca(SO4).1/2H2O) is mixed with water that soon hardens into a solid. Used in making casts, molds, and sculpture. Generally non-toxic.
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