디이소프로필 수소 인산염

Diisopropyl phosphite

HCID 3072CAS 1809-20-7

기본 정보

표준 SMILES
CC(C)O[PH](=O)OC(C)C
InChIKey
BLKXLEPPVDUHBY-UHFFFAOYSA-N
분자식
C6H15O3P
평균 분자량
166.16 g/mol
단동위원소 질량
166.07588133

이름 및 식별자

우선 이름
Diisopropyl phosphite
IUPAC
2-propan-2-yloxyphosphonoyloxypropane
현지명
디이소프로필 수소 인산염
영어명
Diisopropyl phosphite
분자식
C6H15O3P
분자량
166.16

이름 및 동의어

RefChem:920277217-317-71809-20-7676G4RQ6NDbis(propan-2-yl) phosphonateDiisopropyl hydrogen phosphiteDiisopropyl hydrogen phosphonateDiisopropyl phosphiteDiisopropyl phosphonateDiisopropylphosphonateIsopropyl phosphonateNSC-82344
이름 더 보기
디아이소프로필수소인산염디이소프로필수소인산염디아이소프로필수소인산염(DIISOPROPYLHYDROGENPHOSPHITE)Diisopropylphosphine oxide3P-230(iPrO)2P(O)HO,O-DiisopropyLisopropylphosphonateDI-I-PROPYLPHOSPHITEDiisopropyl phosphit
O,O-diisopropyl phosphitePhosphonic acid, bis(1-methylethyl) esterPhosphonic acid, diisopropyl ester

데이터베이스 식별자

CAS
1809-20-7
PubChem CID
3072
DTXSID
DTXSID7061988
EC Number
217-317-7

물성

구조 계산 물성

XLogP
0.4
극성 표면적
35.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
3
회전 가능 결합 수
4
무거운 원자 수
10

실험 및 물리화학적 성질

Vapor Pressure0.54 [mmHg]
Physical DescriptionLiquid; [Alfa Aesar MSDS]

물리화학적 성질

끓는 점
71 °C · 71 °C (8 mmHg)
밀도
0.997 · 0.997
굴절률
1.4065 · 1.4065-1.4085
인화점
69 °C · 69°C
저장 조건
Inert atmosphere,Room Temperature
용해도
클로로포름(소량으로 용해), 메탄올(소량으로 용해)

화학적 성질

clear colourless liquid, corrosive, soluble in organic solvents such as ethanol.

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 78.2% (43 of 55) of all reports.

Warning

H302 (20%): Harmful if swallowed [Warning Acute toxicity, oral];H315 (18.2%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (20%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (16.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 55 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 43 of 55 reports by companies.;There are 9 notifications provided by 12 of 55 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 2건

Chemical: Phosphonic acid, bis(1-methylethyl) ester

Phosphonic acid, bis(1-methylethyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards Summary · 1건

Causes convulsions and lung changes in inhalation lethal-concentration studies of rats, mice, and guinea pigs; [RTECS] A skin and strong eye irritant; Harmful by inhalation; Toxic by ingestion; [Alfa Aesar MSDS] See Dimethyl hydrogen phosphite.

Hazard Classes and CategoriesAcute Tox. 4 (20%);Skin Irrit. 2 (18.2%);Eye Irrit. 2A (20%);STOT SE 3 (16.4%)

독성 정보

Adverse EffectsNeurotoxin - Other CNS neurotoxin
Toxicity DataLC50 (rat) = 9,600 mg/m3

규제 정보

Regulatory Information · 2건

Chemical: Phosphonic acid, bis(1-methylethyl) ester

Phosphonic acid, bis(1-methylethyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

안전 데이터

tsca
TSCA listed
rtecs
SZ7660000
ridadr
3265
독성
guinea pig,LC50,inhalation,9010mg/m3 (9010mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGESGASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDSBEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 29(11), Pg. 51, 1985.
HS 번호
29209085
risk_code
36/37/38-22

화학 및 산업

용도 및 제조

General Manufacturing InformationPhosphonic acid, bis(1-methylethyl) ester: ACTIVE
제조 방법 · 1건

Diisopropyl phosphite is prepared by directly reacting isopropanol with phosphorus trichloride.3(CH3)2CHOH+PCl3→[(CH3)2CHO]2POH+2HCl↑+(CH3)2CHClAt a ratio of 3:1 (mol), continuously feed 215kg/h of isopropanol and 150kg/h of phosphorus trichloride. When mixed, this results in a violent reaction that generates hydrogen chloride gas. This gas is quickly removed from the mixing pot using vacuum mercury. The crude ester produced is then heated in a falling film type spinner deacidification device and further deacidified. The resulting product is then cooled to below 40°C and obtained with a content of 92%-95% and a yield of 95%~98%.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
南京一化生物科技有限公司13429882898; 13429882898
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

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