Diisopropylphosphoramidous dichloride

HCID 5139911

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 921-26-6
표준 SMILES: CC(C)N(C(C)C)P(Cl)Cl
InChIKey: UPPVRFOGRCBSJP-UHFFFAOYSA-N
분자식: C6H14Cl2NP
평균 분자량: 202.06 g/mol
단동위원소 질량: 201.02409144

이름 및 식별자

우선 이름: Diisopropylphosphoramidous dichloride
IUPAC: N-dichlorophosphanyl-N-propan-2-ylpropan-2-amine
영어명: DIISOPROPYLPHOSPHORAMIDOUS DICHLORIDE
분자식: C6H14Cl2NP
분자량: 202.06

이름 및 동의어

921-26-6Diisopropylphosphoramidous dichlorideDTXSID30408696RefChem:587939DTXCID80359548633-001-5Dichloro N,N-DiisopropylphosphoramiditeN-dichlorophosphanyl-N-propan-2-ylpropan-2-amineN,N-Bis(1-methylethyl)phosphoramidous dichlorideMFCD00012236(dichlorophosphanyl)bis(propan-2-yl)aminePhosphoramidous dichloride, bis(1-methylethyl)-

이름 더 보기

1,1-dichloro-N,N-diisopropylphosphanamineDiisopropylaminodichlorophosphineDiisopropylaminodichlorphosphanDichlorophosphinodiisopropylamineDIISOPROPYLAMINOPHOSPHORDICHLORIDEDichloro(diisopropylamino)phosphineN-diisopropylaminodichlorophosphaneBis(isopropyl)aminodichlorophosphine

Phosphoramidousdichloride, N,N-bis(1-methylethyl)-iPr2NPCl2Dichloro-N,N-diisopropylamino-phosphaneC6H14Cl2NPSCHEMBL1146068SCHEMBL10716728diisopropylphosphoramidodichloriditeUPPVRFOGRCBSJP-UHFFFAOYSA-N

데이터베이스 식별자

CAS: 921-26-6
PubChem CID: 5139911
DTXSID: DTXSID30408696
EC Number: 633-001-5
Nikkaji: J429.871C

물성

구조 계산 물성

XLogP: 3.3
극성 표면적: 3.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 2
무거운 원자 수: 10
형식 전하: 0
복잡도: 87.7

실험 및 물리화학적 성질

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

물리화학적 성질

끓는 점: 56 · 56-58°C/15mmHg.
밀도: 1.096 g/mL · 1.096 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.485(lit.)
인화점: 66 °C · 66 °C
저장 조건: Hygroscopic, Refrigerator, Under Inert Atmosphere
용해도: Acetonitrile (Slightly), Chloroform (Soluble), Dichloromethane (Slightly), Ethyl
물리적 상태: 기름
산도 계수 (pKa): -1 · -1.00±0.70(Predicted)
색상: 무색~연황색
안정성: 수분에 민감한
InChI: InChI=1S/C6H14Cl2NP/c1-5(2)9(6(3)4)10(7)8/h5-6H,1-4H3
InChIKey: UPPVRFOGRCBSJP-UHFFFAOYSA-N
SMILES: P(N(C(C)C)C(C)C)(Cl)Cl

화학적 성질

Colourless Oil

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesPyr. Liq. 1 (100%)

안전 데이터

wgk: 3
ridadr: 2846
risk_code: 1-5-14-34
hazard_code: E,C
safety_code: 15-26-27-36/37/39-45
포장분류: I
위험 등급: 4.2

화학 및 산업

응용 분야

용도Diisopropylphosphoramidous dichloride is used as a versatile phosphitylating agent for the phosphorylation of hydroxy amino acids and the preparation of protected phosphopeptides.