싸이오사이안산 칼륨

Potassium thiocyanate

HCID 516872CAS 333-20-0

기본 정보

표준 SMILES
N#C[S-].[K+]
InChIKey
ZNNZYHKDIALBAK-UHFFFAOYSA-M
분자식
CKNS
평균 분자량
97.18 g/mol
단동위원소 질량
96.93885166

이름 및 식별자

우선 이름
Potassium thiocyanate
IUPAC
potassium thiocyanate
현지명
싸이오사이안산 칼륨
영어명
Potassium thiocyanate
분자식
CKNS
분자량
98.19

이름 및 동의어

POTASSIUM THIOCYANATE333-20-0Potassium rhodanatePotassium sulfocyanateRodancaPotassium thiocyanideArterocynRhocyaPotassium isothiocyanatepotassium rhodanideAterocynKyonate
이름 더 보기
로단카로단화칼륨로신유시안화칼륨칼륨로단산염키오나테티오카라로단칼리싸이오사이안산칼륨아데로-신아르테로신칼륨로단화물칼륨술포시안산칼륨이소티오시안산티오시안산칼륨포다-니드로당카리싸이오사이안산칼륨포타슘티오시아네이트Product Description
Thiocyanic acid, potassium saltKSCNDTXSID7029619TM7213864ADTXCID009619CHEBI:30951RefChem:6160206-370-1

데이터베이스 식별자

CAS
333-20-0
PubChem CID
516872
DTXSID
DTXSID7029619
ChEMBL
CHEMBL2106973
ChEBI
CHEBI:30951
UNII
TM7213864A
EC Number
206-370-1
Nikkaji
J3.633A

물성

구조 계산 물성

극성 표면적
24.8 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
4

실험 및 물리화학적 성질

Density · 2건

1.9 g/cm³

1.89 @25 °C

SolubilitySolubility in water: very good
Decomposition500 °C
Melting Point · 2건

173 °C

173 °C

Physical Description · 2건

Colorless deliquescent solid; [Merck Index]

COLOURLESS-TO-WHITE HYGROSCOPIC CRYSTALS.

물리화학적 성질

녹는점
173 °C · 173 °C (lit.)
끓는 점
500 °C · 500°C
밀도
1.886 · 1.886
증기압
0.001 hPa · <0.001 hPa (20 °C)
인화점
500 °C · 500°C
저장 조건
5 °C · Store at +5°C to +30°C.
화학적 성질 · 1건

Potassium thiocyanate, KSCN,also known as potassium sulfocyanate and potassium rhodanide, is a colorless deliquescent crystalline solid that melts at 173°C (343 OF) and decomposes at 500°C(932 OF). Soluble in water and alcohol,it has no odor and a saline taste.Potassium thiocyanate is used in printing and dyeing textiles, freezing mixtures, manufacturing chemicals, photography and medicine.

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H302+H312+H332 (45.4%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation];H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral];H312 (99.6%): Harmful in contact with skin [Warning Acute toxicity, dermal];H318 (29.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (28.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H332 (99.6%): Harmful if inhaled [Warning Acute toxicity, inhalation];H400 (13.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H412 (81%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P321, P330, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 284 reports by companies from 24 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 6건

Chemical: Thiocyanic acid, potassium salt

Commission Regulation (EU) No 188/2011

Thiocyanic acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Thiocyanic acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

05/751/EC, Reg. (EU) No 108/2014

Status: Active Update: 24-06-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/5157

Potassium thiocyanate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Thiocyanate salts: Human health tier II assessment
Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Hazards Summary · 1건

Toxic effects include skin eruptions, psychosis, and collapse; [Merck Index] May cause CNS effects (excitement and convulsions); Prolonged or repeated exposure may cause thyroid and CNS effects leading to impaired function and hypothyroidism; [ICSC] Human ingestion of 80 mg/kg causes hallucinations, convulsions, and muscle weakness; Human ingestion of 428 mg/kg causes toxic psychosis, hallucinations, and gastritis; [RTECS] Sheep exposed orally during gestation produced goiter in newborn lambs; Effects to female fertility observed in rats at high doses; Another study demonstrated maternal and fetal toxicity with no increase in congenital defects; [REPROTOX] Harmful by ingestion, inhalation, and skin absorption; Targets the CNS, cardiovascular system, and thyroid; [Sigma-Aldrich MSDS] See Sodium thiocyanate.

EC ClassificationSymbol: Xn; R: 20/21/22-32-52/53; S: (2)-13-61; Note: A
Chemical DangersDecomposes on heating. This produces very toxic fumes of sulfur compounds, nitrogen oxides and cyanides. Reacts violently with strong oxidants. Contact with water causes a strong cooling effect.

안전 및 보호

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4건

Fresh air, rest.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention .

Safe StorageSeparated from strong oxidants. Dry. Well closed.
Spillage DisposalPersonal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder.
Eye PreventionWear safety goggles or eye protection in combination with breathing protection.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.

독성 정보

Adverse EffectsNeurotoxin - Other CNS neurotoxin
Exposure RoutesThe substance can be absorbed into the body by inhalation and by ingestion.
Signs and Symptoms · 2건

Cough. Further see Ingestion.

Confusion. Convulsions. Nausea. Vomiting. Weakness.

규제 정보

Regulatory Information · 6건

Chemical: Thiocyanic acid, potassium salt

Commission Regulation (EU) No 188/2011

Thiocyanic acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Thiocyanic acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

05/751/EC, Reg. (EU) No 108/2014

Status: Active Update: 24-06-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/5157

Potassium thiocyanate: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
XL1925000
독성
LD50 orally in mice, rats: 594, 854 mg/kg, Andersen, Chen, J. Am. Pharm. Assoc. 29, 152 (1940)
HS 번호
28380000
risk_code
32-52/53-20/21/22

화학 및 산업

약리 정보

MeSH Pharmacological ClassificationChemicals and substances that impart color including soluble dyes and insoluble pigments. They are used in INKS; PAINTS; and as INDICATORS AND REAGENTS.

용도 및 제조

Uses · 2건

Used to make mustard oil, for printing and dyeing textiles, in photography (intensifier), and as a therapeutic hypotensive; [Merck Index] Used as a contact fungicide for green house vegetables and ornamentals and green house and open field strawberries; [ExPub: EFSA: DAR - Vol. 1]

Farming (Pesticides) [Category: Industry];Photographic Processing [Category: Other];Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: <50,000 lb;2022: <50,000 lb;2021: <50,000 lb;2020: <50,000 lb
Household ProductsInformation on 1 consumer products that contain Potassium Thiocyanate in the following categories is provided:;• Personal Care
Use ClassificationCosmetics -> Stabilizing
General Manufacturing InformationThiocyanic acid, potassium salt (1:1): ACTIVE
응용 분야 · 2건

용도Potassium Thiocyanate has been used as a catalyst in a one-pot reaction of dialkyl acetylenedicarboxylates with indane-1,3-dione. Potassium Thiocyanate has been used as a selective bacterial inhibitor to create ESS-3 broth to allow co-enrichment of the target pathogens and suppress growth of some non-target pathogens

일반 설명Potassium thiocyanate is an inorganic potassium salt. Phase transitions in potassium thiocyanate (KSCN) have been investigated by X-ray diffraction studies. The order-disorder type transition with respect to the orientation of the thiocyanate ions was identified. Its polarized infrared spectrum has been reported. It participates in the ring-opening of aziridines. The reaction was carried out in the presence of sulfated zirconia to afford the corresponding β-aminothiocyanates.

제조 방법 · 1건

Potassium thiocyanate may be made by adding caustic potash to a solution of ammonium thiocyanate, followed by evaporation of the solution. NH4SCN + KOH →KSCN + NH4OHAlso, the compound can be prepared by heating potassium cyanide with sulfur:KCN + S →KSCN.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]

추가 설명

정의ChEBI: A potassium salt which is the monopotassium salt of thiocyanic acid.

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739건

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