기본 정보
- 표준 SMILES
O=S(=O)([O-])O.[Na+]- InChIKey
WBHQBSYUUJJSRZ-UHFFFAOYSA-M- 분자식
- HNaSO4
- 평균 분자량
- 120.06 g/mol
- 단동위원소 질량
- 119.94932379
개요
Bisulfate, aqueous solution is a white crystalline solid dissolved in water. It is corrosive to metals and tissue.
이름 및 식별자
- 우선 이름
- Sodium Bisulfate
- IUPAC
- sodium hydrogen sulfate
- 현지명
- 이황산 나트륨
- 영어명
- Sodium bisulfate
- 분자식
- NaHSO4
- 분자량
- 121.07
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
7681-38-1- PubChem CID
- 516919
- DTXSID
DTXSID3033983- ChEMBL
CHEMBL1200488- UNII
- BU8V88OWIQ
- EC Number
- 231-665-7
- Nikkaji
- J44.044B
물성
구조 계산 물성
- 극성 표면적
- 85.8 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 4
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 6
- 형식 전하
- 0
- 복잡도
- 93.2
실험 및 물리화학적 성질
Physical Description
Bisulfate, aqueous solution is a white crystalline solid dissolved in water. It is corrosive to metals and tissue.
Other Solid; Dry Powder; Liquid; Other Solid; Liquid
White, odourless crystals or granules
White crystals dissolved in water; [CAMEO] Hygroscopic crystals; [CHEMINFO]
물리화학적 성질
- 녹는점
- 315 °C · 315 °C
- 밀도
- 2.1 · 2.1
- 물리적 상태
- 과립
- 산도 계수 (pKa)
- 1.99 · 1.99
- 색상
- 흰색에서 밝은 노란색
- 수용성
- 2 O · H2O 2부, 끓는 H2O 1부에 용해됨; 알코올에서 황산나트륨과 H2SO4로 분해[MER06]
- Merck
- 13 · 13,8658
- 안정성
- 안정적인. 강염기, 강산화제, 탄산나트륨, 차아염소산나트륨과 호환되지 않습니다. 습한 공기나 물에 노출되면 분해될 수 있습니다.
- 화장품 원료 기능
- 버퍼링
- InChI
- InChI=1S/Na.H2O4S.H/c;1-5(2,3)4;/h;(H2,1,2,3,4);
- InChIKey
- TTXJTWGBBUPRBF-UHFFFAOYSA-N
- SMILES
- S(O)(O)(=O)=O.[NaH]
- EPA
- Sodium bisulfate (7681-38-1)
화학적 성질
Also known as sodium acid sulfate, niter cake, sodium hydrogen sulfate, NaHS04, is colorless crystals or white fused lumps,whose aqueous solution is strongly acid.It is soluble in water and noncombustible. Derived as a byproduct in the manufacture of hydrochloric acid and nitric acid, it is purified by recrystallization. Used as a flux for decomposing minerals,substitute for sulfuric acid in dyeing,disinfectant, in the manufacture of sodium hydrosulfide,sodium sulfate,and soda slum,for liberating CO2 in carbonic acid baths,in thermophores, for carbonizing wool, in the manufacture of magnesia cements,paper,soap,perfumes, foods, industrial cleaners, metal pickling compounds, and as a lab reagent.
안전 및 규제
GHS 분류
GHS Classification
Danger
H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)
This chemical does not meet GHS hazard criteria for 0.3% (2 of 794) of reports.
Danger
H318 (99.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
유해성 정보
Regulatory Information
Chemical: Sulfuric acid, monosodium salt
Regulation (EC) No 1333/2008 (amended)
Sulfuric acid, sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 24-02-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/14458
Sodium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard
Fire Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.
Hazards Summary
Corrosive to metals and tissues; Toxic by ingestion, inhalation, or skin contact; [CAMEO] Aqueous solutions are strong acids; [Merck Index] Harmful if swallowed; Do not inhale dust or aerosol; may cause acute lung edema if inhaled; [MSDSonline] Based on animal studies, not a skin irritant; [CHEMINFO]
Reactivity Profile
Acidic salts, such as SODIUM BISULFATE, SOLUTION, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pHs of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. The combination of calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, when compressed, caused the materials to incandescence, followed by explosion, [Ind. Eng. Chem., 1937, 15, 282].
Hazard Classes and Categories
Eye Dam. 1 (99.6%)
Eye damage - category 1
Serious eye damage/eye irritation - Category 2
Eye Dam. 1
안전 및 보호
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
General First Aid:
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Immediate precautionary measure
Protective Action Criteria (PAC)
8.4 [mg/m3]
92 [mg/m3]
550 [mg/m3]
독성 정보
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- rtecs
- VZ1860000
- ridadr
- 3260
- HS 번호
- 28331900
- risk_code
- 41
- hazard_code
- Xi
- safety_code
- 24-26
- 포장분류
- II
- 위험 등급
- 8
- 기존화학 물질
- KE-31481
- F 고인화성물질
- 3
- Hazard Classifications
- Eye Dam. 1
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
약리 정보
용도 및 제조
Uses
Used as a bactericide and disinfectant; [ChemIDplus] Used to pickle metals, carbonize wool, bleach leather, and manufacture magnesia cements; [Merck Index]
Acid and Alkali Cleaning of Metals [Category: Clean]
Use Classification
EPA Safer Chemical Functional Use Classes -> Antimicrobial Actives;Processing Aids and Additives
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
Food additives
Food Additives -> ACID -> JECFA Functional Classes
Cosmetics -> Buffering
General Manufacturing Information
Miscellaneous Manufacturing
Sulfuric acid, sodium salt (1:1): ACTIVE
응용 분야
용도sodium bisulfate is an inorganic salt used as an anti-septic and a pH adjuster in cosmetic creams. Concentrated solutions can produce strong irritation.
일반 설명Bisulfate, aqueous solution is a white crystalline solid dissolved in water. Sodium bisulfate is corrosive to metals and tissue.
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