Tris(furan-2-yl)phosphane

HCID 521585CAS 5518-52-5

기본 정보

표준 SMILES: c1coc(P(c2ccco2)c2ccco2)c1
InChIKey: DLQYXUGCCKQSRJ-UHFFFAOYSA-N
분자식: C12H9O3P
평균 분자량: 232.17 g/mol
단동위원소 질량: 232.02893078

이름 및 식별자

우선 이름: Tris(furan-2-yl)phosphane
IUPAC: tris(furan-2-yl)phosphane
영어명: Tri(2-furyl)phosphine
분자식: C12H9O3P
분자량: 232.17

이름 및 동의어

tris(furan-2-yl)phosphaneRefChem:900318628-036-8Tri(2-furyl)phosphine5518-52-5Tri(furan-2-yl)phosphineTri-(2-furyl)phosphineTRI-2-FURYLPHOSPHINETRIS(2-FURYL)PHOSPHINEtris(2-furanyl)phosphinetrifuranyl phosphineMFCD00151857

이름 더 보기

tris(2-furyl)phosphaneTri(2-furyLTri(fur-2-yl)phosphineTris(o-furyl)phosphineTris(fur-2-yl)phosphinePhosphine, tri-2-furanyl-Tris(furan-2-yl)phosphine

TRI(FURAN-2-YL)PHOSPHANETRI-2-FURANYLPHOSPHINEtrifuran-2-ylphosphineTRIFURYLPHOSPHINEP(2-furyl)3CS-D1394EN300-207605C12H9O3P

데이터베이스 식별자

CAS: 5518-52-5
PubChem CID: 521585
DTXSID: DTXSID00334690
EC Number: 628-036-8
Nikkaji: J150.469J

물성

구조 계산 물성

XLogP: 2.8
극성 표면적: 39.4 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 3
무거운 원자 수: 16
형식 전하: 0
복잡도: 198

실험 및 물리화학적 성질

SpringerMaterials PropertiesChemical shift

물리화학적 성질

녹는점: 59 · 59-64 °C (lit.)
끓는 점: 136 °C/4 · 136 °C/4 mmHg (lit.)
인화점: 136 °C/4mm · 136°C/4mm
저장 조건: Keep in dark place,Sealed in dry,Room Temperature
물리적 상태: 고체
색상: 희미한 갈색
BRN: 1577564 · 1577564
InChI: InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChIKey: DLQYXUGCCKQSRJ-UHFFFAOYSA-N
SMILES: P(C1=CC=CO1)(C1=CC=CO1)C1=CC=CO1

화학적 성질

TRI(2-FURYL)PHOSPHINE is white to light yellow crystal powde

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 80 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 데이터

wgk: 3
tsca: No
HS 번호: 29319090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-24/25
F 고인화성물질: 10-23
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야

용도TRI(2-FURYL)PHOSPHINE is a phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.