Tris(furan-2-yl)phosphane → 2-Fluoro-4-[4-methyl-5-(2-{3-methyl-4-[(4-methyl-2,6,7-trioxabicyclo[2.2.2]oct-1-yl)methoxy]phenyl}ethyl)thien-2-yl]benzonitrile

반응식

C([Sn](CCCC)(CCCC)[C:6]1[S:7][C:8]([CH2:12][CH2:13][C:14]2[CH:19]=[CH:18][C:17]([O:20][CH2:21][C:22]34[O:29][CH2:28][C:25]([CH3:30])([CH2:26][O:27]3)[CH2:24][O:23]4)=[C:16]([CH3:31])[CH:15]=2)=[C:9]([CH3:11])[CH:10]=1)CCC.[F:40][C:41]1[CH:48]=[C:47](Br)[CH:46]=[CH:45][C:42]=1[C:43]#[N:44].O1C=CC=C1P(C1OC=CC=1)C1OC=CC=1>O1CCCC1.C(=CC(C=CC1C=CC=CC=1)=O)C1C=CC=CC=1.C(=CC(C=CC1C=CC=CC=1)=O)C1C=CC=CC=1.[Pd]>[F:40][C:41]1[CH:48]=[C:47]([C:6]2[S:7][C:8]([CH2:12][CH2:13][C:14]3[CH:19]=[CH:18][C:17]([O:20][CH2:21][C:22]45[O:23][CH2:24][C:25]([CH3:30])([CH2:26][O:27]4)[CH2:28][O:29]5)=[C:16]([CH3:31])[CH:15]=3)=[C:9]([CH3:11])[CH:10]=2)[CH:46]=[CH:45][C:42]=1[C:43]#[N:44]