기본 정보
- 표준 SMILES
O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mn+2]- InChIKey
MIVBAHRSNUNMPP-UHFFFAOYSA-N- 분자식
- MnN2O6
- 평균 분자량
- 178.95 g/mol
- 단동위원소 질량
- 178.91368082
개요
Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
이름 및 식별자
- 우선 이름
- Manganese nitrate
- IUPAC
- manganese(2+) dinitrate
- 현지명
- 망간 니트레이트 용액
- 영어명
- Manganese nitrate
- 분자식
- MnN2O6
- 분자량
- 178.95
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
10377-66-9- PubChem CID
- 61511
- DTXSID
DTXSID90890659- UNII
- I389H78514
- EC Number
- 233-828-8
물성
구조 계산 물성
- 극성 표면적
- 126 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 6
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 9
- 형식 전하
- 0
- 복잡도
- 18.8
실험 및 물리화학적 성질
Physical Description
Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
Large Crystals; Liquid
Colorless hygroscopic solid; [Merck Index] White crystals; [CAMEO] 50% Aqueous solution: Pink liquid with an acidic odor; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 37 °C · 37°C
- 끓는 점
- 100 °C · 100°C
- 밀도
- 1.536 g/mL · 1.536 g/mL at 25 °C
- 증기압
- 0 Pa · 0Pa at 20℃
- 용해도
- very soluble in ethanol
- 물리적 상태
- 액체
- Specific Gravity
- 1.5 · 1.5
- 색상
- 분홍색
- 수용성
- 녹는
- Merck
- 13 · 13,5756
- InChI
- 1S/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1
- InChIKey
- MIVBAHRSNUNMPP-UHFFFAOYSA-N
- SMILES
- [Mn++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
- EPA
- Nitric acid, manganese(2+) salt (10377-66-9)
화학적 성질
Light red liquid
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 0.6% (2 of 310) of reports.
Danger
H272 (89%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]
P210, P220, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P370+P378, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 310 reports by companies from 26 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
유해성 정보
Regulatory Information
Chemical: Nitric acid, manganese(2+) salt
Nitric acid, manganese(2+) salt (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, manganese(2+) salt (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 11-08-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13480
Nitric acid, manganese(2+) salt: HSNO Approval: HSR001332 Approved with controls
Fire Hazards
Excerpt from ERG Guide 140 [Oxidizers]:
CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).
Health Hazards
Excerpt from ERG Guide 140 [Oxidizers]:
· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.
Hazards Summary
A skin and eye irritant; Toxic by ingestion; May ignite in contact with organic matter or explode in contact with fuels; [CAMEO] 50% Aqueous solution: An oxidizer that may cause fire on contact with combustible materials; A skin and strong eye irritant; [Alfa Aesar MSDS] See Manganese and linked occupational diseases. See NITRATES and NITRITES.
Reactivity Profile
Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures of nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. The anhydrous nitrate salt with urea explodes upon heating, [Chem Abs., 1975, 82, 48151].
DOT Hazard Classification
Manganese nitrate
UN2724
Div 5.1 Oxidizer (49 eCFR § 173.127)
PG III: the degree of danger presented by the material is minor
안전 및 보호
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Keep combustibles (wood, paper, oil, etc.) away from spilled material.
First Aid
Excerpt from ERG Guide 140 [Oxidizers]:
General First Aid:
Exposure Control and Personal Protection
· Wear positive pressure self-contained breathing apparatus (SCBA).
0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)[German Research Foundation (DFG)]
Isolation and Evacuation
Excerpt from ERG Guide 140 [Oxidizers]:
Immediate precautionary measure
Protective Action Criteria (PAC)
9.8 [mg/m3]
16 [mg/m3]
98 [mg/m3]
독성 정보
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 2724
- HS 번호
- 28342990
- risk_code
- 8-34-40-36/37/38-36/38-20
- hazard_code
- O,C,Xn,Xi
- safety_code
- 17-26-27-36/37/39-45-36
- 포장분류
- III
- 위험 등급
- 5.1
- 기존화학 물질
- KE-23016
- Hazard Classifications
- Acute Tox. 4 OralEye Dam. 1Met. Corr. 1Ox. Liq. 2Skin Corr. 1CSTOT RE 2 Inhalation
- 스토리지 클래스
- 5.1B - Oxidizing hazardous materials
화학 및 산업
용도 및 제조
Uses
Used to produce manganese dioxide, to color ceramics, and as a catalyst; [NJHSFS] Used to make reagent grade manganese dioxide and porcelain colorants; [Merck Index]
Ceramics making [Category: Hobbies]
General Manufacturing Information
Fabricated Metal Product Manufacturing
Nitric acid, manganese(2+) salt (2:1): ACTIVE
응용 분야
용도Ceramics, intermediates, catalyst, manganese dioxide.
일반 설명A white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
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