Acetic Acid → Adipic Acid

HRID 1744005

반응식

HRID 1744005 반응식
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4]CC1.[N+]([O-])(O)=O.[O:12]=O.[C:14]([OH:17])(=[O:16])[CH3:15]>[N+]([O-])([O-])=O.[Mn+2].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[Co+2].[N+]([O-])([O-])=O>[C:1]([OH:7])(=[O:12])[CH2:6][CH2:5][CH2:4][CH2:15][C:14]([OH:17])=[O:16]

참가 물질

7

반응물 4

HCID 176Acetic AcidHCID 944Nitric AcidHCID 977OxygenHCID 7967Cyclohexanone

생성물 1

HCID 196Adipic Acid

시약·촉매·용매 2

HCID 25000Cobalt dinitrate촉매HCID 61511Manganese nitrate촉매

실험 절차

A solution containing 25 mmol of cyclohexanone, 0.5 mmol of manganese(II) nitrate, 0.5 mmol of cobalt(II) nitrate and 1.5 mmol of nitric acid in 25 ml of acetic acid was stirred for 5 h at 40° C. in an oxygen atmosphere under ambient pressure. Subsequently, the acetic acid was distilled off. The residue was found to consist mainly of adipic acid with some glutaric acid and a small amount of unreacted starting material. The conversion of cyclo-hexanone was found to be 97.5%, the selectivity of the oxidation to adipic acid being 93.4%.

후처리

  1. distillationSubsequently, the acetic acid was distilled off

출처 및 근거

ORD 기록
ord-ea8b88fa6ef14293914a9ca4eb3c2d0d
출처 데이터셋
uspto-grants-2006_03
특허 번호
US07012155B2

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