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구리 염화물

Cuprous chloride

HCID 62652
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
1344-67-8
표준 SMILES
[Cl][Cu]
InChIKey
OXBLHERUFWYNTN-UHFFFAOYSA-M
분자식
ClCu
평균 분자량
99 g/mol

개요

Copper(I) chloride is an inorganic chloride of copper in which the metal is in the +1 oxidation state. It has a role as an agrochemical and a molluscicide. It is a copper molecular entity and an inorganic chloride. It contains a copper(1+).

이름 및 식별자

우선 이름
Cuprous chloride
IUPAC
chlorocopper
현지명
구리 염화물
영어명
Cupric chloride
분자식
Cl.Cu
분자량
0

이름 및 동의어

Cuprous chlorideCOPPER(I) CHLORIDE7758-89-6Copper monochlorideDicopper dichlorideCopper(1+) chlorideCopper chloride (CuCl)Chlorid mednyCuClCuproidCu-lytC955P95064
이름 더 보기
구리염화물구리염화물(COPPERCHLORIDE)COPPER CHLORIDECOPPER ATOMIC SPECTROSCOPY STANDARDUn2802HAMP-OLKirticopperCUPRIC CHLORIDEEinecs 215-704-5Copper, diaquadichloro-COPPER AA STANDARD CONCENTRATECopper chloride [un2802] [corrosive]
CHEBI:53472RefChem:128845DTXCID3015242231-842-9DTXSID5035242Copper (I) chlorideChlorid medny [Czech]EINECS 231-842-9

데이터베이스 식별자

CAS
1344-67-8、7758-89-6
PubChem CID
62652
ChEBI
CHEBI:53472

물성

구조 계산 물성보충 중

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesthermal expansion coefficient
Density4.14 @25 °C
Boiling Point1490 °C @760 [mm Hg]
Melting Point423 °C
Vapor Pressure1 [mm Hg] @546 °C
Physical Description · 2건

Dry Powder; Liquid

White solid; Turns green on exposure to moist air, and blue to brown on exposure to light; [Merck Index] Insoluble in water (0.1 g/L); [Ullmann] Grey-tan to light green odorless powder; [Reference #2]

물리화학적 성질

녹는점
620 °C · 620 °C(lit.)
끓는 점
993 °C · 993 °C
밀도
3.386 g/mL · 3.386 g/mL at 25 °C(lit.)
저장 조건
2 · 2-8°C
용해도
2 O: · H2O: 용해성
물리적 상태

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P273, P301+P317, P330, P391, and P501 (click each P-code to see the statement)

Warning

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P260, P261, P272, P273, P280, P302+P352, P319, P321, P333+P317, P362+P364, P391, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 3건

Chemical: Copper chloride (CuCl)

Copper chloride (CuCl) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Copper chloride (CuCl) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Copper (I) chloride: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Copper chloride (CuCl): Human health tier I assessment
Hazards Summary · 1건

Harmful if swallowed; [MSDSonline] Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] Classified as category I for skin and eye irritation (corrosive); Category II for acute oral and dermal exposure (moderate toxicity); Category III for acute inhalation exposure (low toxicity); Positive results in dermal sensitization studies; [Reference #2] May cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Copper.

DOT Hazard Classification · 2건

Cuprous chloride

Severe marine pollutant

Hazard Classes and Categories · 3건

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Copper is mainly absorbed through the gastrointestinal tract, but it can also be inhalated and absorbed dermally. It passes through the basolateral membrane, possibly via regulatory copper transporters, and is transported to the liver and kidney bound to serum albumin. The liver is the critical organ for copper homoeostasis. In the liver and other tissues, copper is stored bound to metallothionein, amino acids, and in association with copper-dependent enzymes, then partitioned for excretion through the bile or incorporation into intra- and extracellular proteins. The transport of copper to the peripheral tissues is accomplished through the plasma attached to serum albumin, ceruloplasmin or low-molecular-weight complexes. Copper may induce the production of metallothionein and ceruloplasmin. The membrane-bound copper transporting adenosine triphosphatase (Cu-ATPase) transports copper ions into and out of cells. Physiologically normal levels of copper in the body are held constant by alterations in the rate and amount of copper absorption, compartmental distribution, and excretion. (L277, L279)

용도 및 제조

Uses · 3건

Used to produce other copper compounds and in the production of silicone polymers, ethylene-propene rubbers, dialkyl carbonates, and acrylonitrile; Also used to purify carbon monoxide and to produce phthalocyanine pigments; Occurs in nature as nantokite; [Ullmann] Used as a catalyst for organic reactions, decolorizer, catalyst, and desulfuring agent in the petroleum industry, in denitration of cellulose, as condensing agent for soaps, fats, and oils, and in gas analysis to absorb carbon monoxide; [Merck Index] Used in Korea as a raw material for coloring agents and as a catalyst for CO and H2 production; [Reference #1] Used to control plant root growth in nursery pots (incorporated into the plastic); [Reference #2]

Petroleum Production and Refining [Category: Industry]

Copper(I) chloride is as a precursor to the fungicide copper oxychloride. It is also used in organic and polymer chemistry. (L292)

U.S. Production2023: 2,500,000 - <4,000,000 lb
Consumer Uses

관련 반응

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HRID 1382 반응식
HRID 1382촉매로uspto-grants-1998_03
HRID 4174 반응식
HRID 4174촉매로uspto-grants-1988_02
HRID 4175 반응식
HRID 4175촉매로uspto-grants-1988_02
HRID 6792 반응식
HRID 6792촉매로uspto-grants-2006_08
HRID 7088 반응식
HRID 7088촉매로uspto-grants-2006_08
HRID 7090 반응식
HRID 7090촉매로uspto-grants-2006_08
HRID 7092 반응식
HRID 7092촉매로uspto-grants-2006_08
HRID 10097 반응식
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가루
InChI
InChI=1S/ClH.Cu/h1H;
InChIKey
NNIYFVYSVUWTOA-UHFFFAOYSA-N
SMILES
Cl.[Cu]
EPA
Copper chloride (1344-67-8)

화학적 성질

(1) Brownish-yellow powder, hygroscopic, (2) green, deliquescent crystals, soluble in water and alcohol.

Acute toxicity (Oral) - Category 3

Skin sensitization - Category 1

Acute Tox. 4 *

안전 및 보호

Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Minimum Risk LevelAcute Oral: 0.01 mg/kg/day (L134) Intermediate Oral: 0.01 mg/kg/day (L134)
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Protective Action Criteria (PAC) · 3건

0.093 [mg/m3]

4.6 [mg/m3]

28 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

People must absorb small amounts of copper every day because copper is essential for good health, however, high levels of copper can be harmful. Very-high doses of copper can cause damage to your liver and kidneys, and can even cause death. Copper may induce allergic responses in sensitive individuals. (L278, L279)

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Exposure RoutesOral (L277) ; inhalation (L277) ; dermal (L277)
Toxicity Summary · 1건

Excess copper is sequestered within hepatocyte lysosomes, where it is complexed with metallothionein. Copper hepatotoxicity is believed to occur when the lysosomes become saturated and copper accumulates in the nucleus, causing nuclear damage. This damage is possibly a result of oxidative damage, including lipid peroxidation. Copper inhibits the sulfhydryl group enzymes such as glucose-6-phosphate 1-dehydrogenase, glutathione reductase, and paraoxonases, which protect the cell from free oxygen radicals. It also influences gene expression and is a co-factor for oxidative enzymes such as cytochrome C oxidase and lysyl oxidase. In addition, the oxidative stress induced by copper is thought to activate acid sphingomyelinase, which lead to the production of ceramide, an apoptotic signal, as well as cause hemolytic anemia. Copper-induced emesis results from stimulation of the vagus nerve. (L277, T49, A174, L280)

Signs and SymptomsBreathing high levels of copper can cause irritation of the nose and throat. Ingesting high levels of copper can cause nausea, vomiting, diarrhea, headache, dizziness, and respiratory difficulty. (L278, L279)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Toxicity Data · 2건

LC50 (mice) = 1,008 mg/m3

LD50: 140 mg/kg (Oral, Rat) (L335) LD50: 100 mg/kg (Subcutaneous, Guinea pig) (L335) LC50: 1008 mg/kg (Inhalation, Mouse) (L335)

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
GL7000000
ridadr
UN 3264 8/PG 3
risk_code
52/53
hazard_code
N
safety_code
61
기존화학 물질
KE-08908
F 고인화성물질
3
Catalyst
Industry UsesIntermediate
General Manufacturing Information · 2건

Computer and Electronic Product Manufacturing

Copper chloride (CuCl): ACTIVE

응용 분야 · 1건

용도Isomerization and cracking catalyst, mordant in dyeing and printing fabrics, sympathetic ink, disinfectant, pyrotechnics, wood preservation, fungicides, metallurgy, preservation of pulpwood, deodorizing and desulfurizing petroleum distillates, photography, water purification, feed additive, electroplating baths, pigment for glass and ceramics, acrylonitrile manufacturing.