Binap, (A+-)-

HCID 634876CAS 76189-55-4
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1
InChIKey
MUALRAIOVNYAIW-UHFFFAOYSA-N
분자식
C44H32P2
평균 분자량
622.7 g/mol
단동위원소 질량
622.19792428

개요

See other relationships...

이름 및 식별자

우선 이름
Binap, (A+-)-
IUPAC
[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
영어명
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
분자식
C44H32P2
분자량
622.69

이름 및 동의어

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLrac-BINAP(1,1'-Binaphthalene)-2,2'-diylbis(diphenylphosphine)RAC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL970O8508MBPhosphine, 1,1'-(1,1'-binaphthalene)-2,2'-diylbis(1,1-diphenyl-DTXSID40913327RefChem:1079872Binap, (A+-)-DTXCID70102004898327-87-876189-55-4
이름 더 보기
(+)-BINAPRACEMIC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene(+/-)-BINAP98% (R)-BINAPRACEMIC-BINAP
76189-56-5(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthylBINAP(S)-BINAP2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl(R)-BINAP(R)-(+)-BINAP

데이터베이스 식별자

CAS
76189-55-4、76189-56-5、98327-87-8
PubChem CID
634876
DTXSID
DTXSID40913327
ChEMBL
CHEMBL1275990
UNII
4F1X2F8NA3、970O8508MB、OX12238KWH
EC Number
616-304-7、619-338-0、918-620-3
Nikkaji
J1.058.033A、J1.058.045E、J181.354D、J181.355B、J461.407K

물성

구조 계산 물성

XLogP
11.4
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
7
무거운 원자 수
46

물리화학적 성질

녹는점
283 · 283-286 °C(lit.)
끓는 점
724.3 · 724.3±55.0 °C(Predicted)
굴절률
235 ° · 235 ° (C=0.3, Toluene)
저장 조건
Inert atmosphere,Room Temperature
용해도
벤젠(약간 용해됨), 클로로포름(약간 용해됨)
물리적 상태
가루
화학적 성질 · 1건

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl is a white to light yellow crystal powde, it exhibits high stereoselectivity due to its chirality. It forms stable complexes with various metal catalysts, such as palladium, rhodium, and nickel.

안전 및 규제

GHS 분류

GHS Classification · 6건

Warning

H315 (96%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 25 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

This chemical does not meet GHS hazard criteria for 11.1% (1 of 9) of reports.

Warning

유해성 정보

Hazard Classes and Categories · 2건

Skin Irrit. 2 (77.8%)

Skin Irrit. 2 (96%)

안전 데이터

wgk
3
tsca
No
HS 번호
29319090
risk_code
36/37/38-20/21/22
hazard_code
Xi,Xn
safety_code
22-24/25-37/39-26-36

화학 및 산업

응용 분야

용도Chiral ligand for metal mediated asymmetric catalysis.

일반 설명(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene is an axially dissymmetric bis(triaryl)phosphine ligand for asymmetric reactions.

상·하류 제품 정보

공급사50 곳

北京华美互利生物化工010-56205725 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]

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