Rhodium, di-mu-chlorobis((1,2,5,6-eta)-1,5-cyclooctadiene)di-

HCID 6436379

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 12092-47-6
표준 SMILES: C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Cl-].[Cl-].[Rh].[Rh]
InChIKey: PDJQCHVMABBNQW-MIXQCLKLSA-L
분자식: C16H24Cl2Rh2-2
평균 분자량: 493.1 g/mol

개요

See other relationships...

이름 및 식별자

우선 이름: Rhodium, di-mu-chlorobis((1,2,5,6-eta)-1,5-cyclooctadiene)di-
IUPAC: bis((1Z,5Z)-cycloocta-1,5-diene);bis(rhodium);dichloride
영어명: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
분자식: C16H24Cl2Rh2
분자량: 493.08

이름 및 동의어

Rhodium, di-mu-chlorobis((1,2,5,6-eta)-1,5-cyclooctadiene)di-Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di-Di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]dirhodiumDi-mu-chlorobis((1,2,5,6-eta)-1,5-cyclooctadiene)dirhodiumRhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-RefChem:88303712092-47-6Chloro(1,5-cyclooctadiene)rhodium(I) dimer(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichlorideChloro(1,5-cyclooctadiene)rhodium(I)dimerMFCD00012415Chloro(1,5-cyclooctadiene)rhodium (I) dimer

이름 더 보기

[Rh(cod)Cl]2[RhCl(COD)]2Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodiumChloro(1,5-cyclooctadiene)rhodiuM(I)Chloro(1,5-cyclooctadiene)rhodium dimerRhodium chloro(cycloocta-1,5-diene) dimerBIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I) DICHLORIDE1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimerrhodium(1+)

Rhodium-1,5-cyclooctadiene chloride7BR4HR5Q6MC16H24Cl2Rh2--Bis(cyclooctadiene)dichlorodirhodium1,5-Cyclooctadiene, rhodium complexAKOS015964108FC36866dichlorobis(1,5-cyclooctadiene)dirhodium

데이터베이스 식별자

CAS: 12092-47-6
PubChem CID: 6436379
UNII: 7BR4HR5Q6M

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 0
무거운 원자 수: 20
형식 전하: -2
복잡도: 72.6

실험 및 물리화학적 성질

Food Contact SubstancesFCS -> FDA Inventory of Effective Food Contact Substance (FCS) Notifications

물리화학적 성질

녹는점: 243 °C · 243 °C (dec.) (lit.)
밀도: 1.94 · 1.94[at 20℃]
증기압: 0 Pa · 0Pa at 25℃
저장 조건: Inert atmosphere,Room Temperature
용해도: 클로로포름, 디클로로메탄 및 메탄올에 용해됩니다. 가장 일반적인 용매에 거의 용해되지 않습니다.
물리적 상태: 결정 또는 결정성 분말
색상: 주황색에서 주황색 갈색까지
수용성: 1.56 g/L · 1.56g/L at 20℃
안정성: 흡습성
InChI: InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChIKey: QSUDXYGZLAJAQU-MIXQCLKLSA-L
SMILES: Cl[Rh].C1CCC=CCCC=1.C1CCC=CCCC=1.[Rh]Cl |c:4,8,12,16|
LogP: 3.16 at · 3.16 at 20℃
NIST: Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA: 1 · Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

화학적 성질

orange crystals

안전 및 규제

안전 데이터

wgk: 3
tsca: TSCA listed
HS 번호: 28439000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39
F 고인화성물질: 3
Hazard Classifications: Eye Irrit. 2
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

용도 및 제조

General Manufacturing InformationRhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di-: ACTIVE

응용 분야 · 2건

용도It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

일반 설명This product has been enhanced for catalytic efficiency.