트리페닐메탄올

Triphenylcarbinol

HCID 6457CAS 76-84-6

기본 정보

표준 SMILES
OC(c1ccccc1)(c1ccccc1)c1ccccc1
InChIKey
LZTRCELOJRDYMQ-UHFFFAOYSA-N
분자식
C19H16O
평균 분자량
260.3 g/mol
단동위원소 질량
260.12011513

개요

Tritylalcohol is a benzenoid aromatic compound.

이름 및 식별자

우선 이름
Triphenylcarbinol
IUPAC
triphenylmethanol
현지명
트리페닐메탄올
영어명
Triphenylmethanol
분자식
C19H16O
분자량
260.33

이름 및 동의어

TRIPHENYLMETHANOL76-84-6TriphenylcarbinolTrityl alcoholTritanolTriphenylmethyl alcoholMethanol, triphenyl-hydroxytriphenylmethaneTriphenyl-methanolBenzenemethanol, .alpha.,.alpha.-diphenyl-U97Q0OU9KBZidovudine impurity D
이름 더 보기
트라이페닐메틴올트리페닐메탄올TRT-OHTriphenylmethanol, (Triphenyl carbinolTriphenylmethanol,98%Ih-TetrazoletirphenylmethanolTriphenylmethanol ,99%
NSC 4050NSC-4050EINECS 200-988-5Benzenemethanol, alpha,alpha-diphenyl-TRIPHENYLCARBINOL [MI]AI3-08929DTXSID0058803TRIPHENYLMETHANOL [USP-RS]

데이터베이스 식별자

CAS
76-84-6
PubChem CID
6457
DTXSID
DTXSID0058803
ChEMBL
CHEMBL118166
ChEBI
CHEBI:228440
UNII
U97Q0OU9KB
EC Number
200-988-5
Nikkaji
J4.186F

물성

구조 계산 물성

XLogP
3.7
극성 표면적
20.2 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
1
회전 가능 결합 수
3
무거운 원자 수
20

실험 및 물리화학적 성질

PolymersOther Classes -> Alcohols and Polyols, Other
SpringerMaterials Properties13C nuclear magnetic resonance spectrum
LogP3.68
Vapor Pressure0.00000003 [mmHg]
Physical Description · 2건

Other Solid

Solid; [Merck Index] White to cream crystalline powder; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
160 · 160-163 °C (lit.)
끓는 점
360 °C · 360 °C (lit.)
밀도
40 · d40 1.199
굴절률
1.622 · 1.6220 (estimate)
인화점
360 · 360-380°C
저장 조건
2 · 2-8°C
화학적 성질 · 1건

Triphenylmethanol is a white powder or colorless, isolated crystals that are soluble in alcohol, ether, and benzene. It turns dark yellow when dissolved in concentrated sulfuric acid, colorless when dissolved in glacial acetic acid, and is insoluble in water and petroleum ether. It distills at 360-380°C without decomposition.

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.9% (1 of 114) of reports.

Warning

H315 (98.2%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 114 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: Benzenemethanol, .alpha.,.alpha.-diphenyl-

Benzenemethanol, .alpha.,.alpha.-diphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenemethanol, .alpha.,.alpha.-diphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21505

Benzenemethanol, .alpha.,.alpha.-diphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS] See Chlorotriphenylmethane and Triphenylmethyl bromide.
Hazard Classes and CategoriesSkin Irrit. 2 (98.2%)

안전 데이터

wgk
3
tsca
TSCA listed
HS 번호
29062900
risk_code
38-36/37/38
hazard_code
Xi
safety_code
22-24/25-36-26

화학 및 산업

용도 및 제조

U.S. Production2023: <50,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2건

Petrochemical Manufacturing

Benzenemethanol, .alpha.,.alpha.-diphenyl-: ACTIVE

응용 분야 · 2건

용도Triphenylmethanol is used as a reagent in the research laboratory. It acts as an intermediate in the production of the commercially useful triarylmethane dyes. It is used in the preparation of triphenylmethane. It is also used as an antiproliferative agent. Further, it is used in the preparation of two-electron reduction product of pyrylogen. In addition to this, it reacts with triphenylphosphine oxide to form a 1:1 molecular complex. It serves as a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes. Triphenylmethanol was used in the synthesis of of the two-electron reduction product of pyrylogen. It undergoes reduction to triphenylmethane by 9, 10-dihydro-10-methylacridine in the presence of perchloric acid.

일반 설명Triphenylmethanol forms 1:1 molecular complex with triphenylphosphine oxide. It is a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes. It undergoes reduction to triphenylmethane by 9, l0-dihydro-10-methylacridine in the presence of perchloric acid.

제조 방법 · 1건

Triphenylmethanol synthesis: Triphenylmethanol was prepared by the action of benzene with carbon tetrachloride in the presence of Aluminum chloride, followed by acidification and hydrolysis.Triphenylmethanol can also be prepared by the reaction of phenylmagnesium bromide with methyl benzoate (instead of benzophenone).Synthesis of Triphenylmethanol

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

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