트리메틸시릴 트리플루오로메탄설폰산염

Trimethylsilyl triflate

HCID 65367CAS 27607-77-8
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
C[Si](C)(C)OS(=O)(=O)C(F)(F)F
InChIKey
FTVLMFQEYACZNP-UHFFFAOYSA-N
분자식
C4H9F3O3SSi
평균 분자량
222.26 g/mol
단동위원소 질량
221.99937634

개요

deprotecting cpd for peptides

이름 및 식별자

우선 이름
Trimethylsilyl triflate
IUPAC
trimethylsilyl trifluoromethanesulfonate
현지명
트리메틸시릴 트리플루오로메탄설폰산염
영어명
Trimethylsilyl trifluoromethanesulfonate
분자식
C4H9F3O3SSi
분자량
222.26

이름 및 동의어

Trimethylsilyl trifluoromethanesulfonate27607-77-8Trimethylsilyl triflateTrimethylsilyl trifluoromethanesulphonateTrimethylsilyl trifluoromethylsulfonateMethanesulfonic acid, trifluoro-, trimethylsilyl estertrimethylsilyltriflateUNII-Z84V0CBH9JZ84V0CBH9Jtrimethylsilanol trifluoromethanesulfonateEINECS 248-565-4trimethylsilyltrifluoromethane sulfonate
이름 더 보기
트리메틸시릴트리플루오로메탄설폰산염트리메틸시릴트리플루오로메탄설폰산염(TRIMETHYLSILYLTRIFLUOROMETHANESULFONATE...TMS TRIFLATETrimethylsltrifluoromethanesulphonateTRIFLUOROMETHANESULFONIC ACID TRIMETHYLSILYL ESTERTrimethylsilyl trifluromethanesulfonateTRIMETHYLSILYTrimethylsllytrifluoromethanesulphonate
DTXSID2067325TRIMETHYLSILYL TRIFLATE [MI]1,1,1-Trifluoromethanesulfonic acid trimethylsilyl esterTMS-TFMSRefChem:191816DTXCID8037704248-565-4TMSOTf

데이터베이스 식별자

CAS
27607-77-8
PubChem CID
65367
DTXSID
DTXSID2067325
UNII
Z84V0CBH9J
EC Number
248-565-4
Nikkaji
J208.993I

물성

구조 계산 물성

극성 표면적
51.8 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
6
회전 가능 결합 수
2
무거운 원자 수
12

실험 및 물리화학적 성질

PFASPFAS -> PFAS identified in REACH Regulation EC No. 1272/2008
SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

물리화학적 성질

녹는점
25 °C · 25°C
끓는 점
77 °C/80 · 77 °C/80 mmHg (lit.)
밀도
1.228 g/mL · 1.228 g/mL at 25 °C (lit.)
증기압
4.7 hPa · 4.7 hPa (20 °C)
굴절률
20 · n20/D 1.36(lit.)
인화점
78 °F · 78 °F

화학적 성질

clear colourless to light brown fuming liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 6.3% (4 of 63) of reports.

Danger

H226 (92.1%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 63 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 3건

Chemical: Methanesulfonic acid, trifluoro-, trimethylsilyl ester

Status: Active Update: 24-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/24115

Trimethylsilyl trifluoromethanesulphonate: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (92.1%)
CSL Reaction Information · 6건

CSL00179

Trimethyl phosphite + Trimethylsilyl triflate

Reaction resulted in an explosion

Explosive

Not Available

User Reported

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 2920 8/PG 2
HS 번호
29310095
risk_code
10-14-34
hazard_code
C,F

화학 및 산업

용도 및 제조

General Manufacturing InformationMethanesulfonic acid, 1,1,1-trifluoro-, trimethylsilyl ester: ACTIVE
응용 분야 · 1건

용도Trimethylsilyl Trifluoromethanesulfonate is a trialkylsilyl triflate used as a catalyst in organic synthesis. Trimethylsilyl Trifluoromethanesulfonate is used in combination with boron trifluoride eth yl ether to prepare a Lewis acid that is more powerful than its components and especially effective in acetonitrile solvent. Trimethylsilyl is a common reagent used in a Dieckmann-like cyclization of ester-imides and diesters.

상·하류 제품 정보

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
中船（邯郸）派瑞特种气体股份有限公司021-53930372 13917175395
INTATRADE GmbH+49 3493/605464 · [email protected]

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