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1,2-디아미노프로판

Propylenediamine

HCID 6567
새 노트새 반응견적 요청하기
인쇄 미리보기

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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
78-90-0
표준 SMILES
CC(N)CN
InChIKey
AOHJOMMDDJHIJH-UHFFFAOYSA-N
분자식
C3H10N2
평균 분자량
74.13 g/mol
단동위원소 질량
74.08439832

개요

1,2-propylenediamine appears as a colorless liquid with an ammonia-like odor. Strongly irritates skin and tissue.

이름 및 식별자

우선 이름
Propylenediamine
IUPAC
propane-1,2-diamine
현지명
1,2-디아미노프로판
영어명
1,2-Diaminopropane
분자식
C3H10N2
분자량
74.12

이름 및 동의어

1,2-DIAMINOPROPANEPropylenediamine78-90-01,2-Propanediamine2,3-DiaminopropaneDTXSID40217612A4P522UGODL-1,2-PropanediamineNSC-1757311-Methyl-1,2-diaminoethaneDTXCID701761CHEBI:30630
이름 더 보기
1,2-디아미노프로판1,2-프로필렌디아민프로필렌다이아민1,2-프로필렌다이아민1,2-다이아미노프로판1,2-프로판다이아민프로판-1,2-다이아민DIAMINOPROPANEPROPANEDIAMINE12APrac 1,2-Diaminopropane-d6NSC 175731
RefChem:411509201-155-9propane-1,2-diamine1,2-PropylenediaminePropylene diamine1-methylethylenediamine10424-38-11,2 Diaminopropane

데이터베이스 식별자

CAS
78-90-0
PubChem CID
6567
DTXSID
DTXSID4021761
ChEMBL
CHEMBL1319459
ChEBI
CHEBI:30630
UNII
2A4P522UGO
EC Number
201-155-9
Nikkaji
J4.225K

물성

구조 계산 물성보충 중

XLogP
-1.2
극성 표면적
52 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
2
회전 가능 결합 수
1
무거운 원자 수
5
형식 전하
0
복잡도
20.9

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Amines, Aliphatic

Corrosives

LogP-1.8
Density · 3건

0.8584 (NTP, 1992) - Less dense than water; will float

Relative density (water = 1): 0.9

0.9 @25 °C

Solubility · 2건

Very soluble (NTP, 1992)

Solubility in water: miscible

Flash Point · 2건

92 °F (NFPA, 2010)

33 °C c.c.

Boiling Point · 3건

248.9 °F at 760 mmHg (NTP, 1992)

119 °C

118.9 °C @760 [mm Hg]

Melting Point · 2건

-35 °F (NTP, 1992)

-12 °C

Vapor Density · 2건

2.6 (NTP, 1992) - Heavier than air; will sink (Relative to Air)

Relative vapor density (air = 1): 2.6

Vapor Pressure · 2건

9.0 [mmHg]

Vapor pressure, kPa at 20 °C: 1.2

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H226: Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P270, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Danger

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P333+P317, P342+P316, P361+P364, P362+P364, P363, P370+P378, P403, P403+P235, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 4건

Chemical: 1,2-Propanediamine

Status: Active Update: 01-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/2163

1,2-Diaminopropane: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive Flammable Liquid
Fire Hazards · 3건

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

· Flammable/combustible material.

Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 33 °C explosive vapour/air mixtures may be formed.

Health Hazards · 2건

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

· May cause toxic effects if inhaled or ingested.

Hazards Summary

화학 및 산업

용도 및 제조

Uses · 2건

Used with cupric sulfate as reagent for mercury; [Merck Index] Used to make medicines, dyes, and rubber accelerators; Also used in electroplating and as analytical reagent; [NTP]

Electroplating [Category: Plate]

General Manufacturing Information1,2-Propanediamine: ACTIVE
응용 분야 · 3건

개요1,2-Diaminopropane is a colorless liquid that is very hygroscopic and miscible with water and most organic solvents. It forms azeotropes with butanol, 2-methylpropanol, and toluene and has a strong ammoniacal odor.

용도1,2-Diaminopropane was used as model precursor in the electron induced deposition of amorphous carbon nitride films.

일반 설명A colorless liquid with an ammonia-like odor. Flash point 160°F. Density 0.87 g / cm3. Boiling point 243°F. Strongly irritates skin and tissue.

상·하류 제품 정보

상류 원료

1,2-디클로로프로판암모니아(가스)

하류 제품

Amifostine2-에틸l-4-메틸이미다졸PEPLOMYCIN2,6-Dimethylpyrazine시베이직블루221,2-디메틸-1,4,5,6-테트라히드로피리미딘

관련 반응

93건
반응 기록 만들기
HRID 46163 반응식
HRID 46163반응물로uspto-grants-2013_09
HRID 65698 반응식
HRID 65698반응물로uspto-grants-1978_12
HRID 65831 반응식
HRID 65831반응물로uspto-grants-1978_12
HRID 66329 반응식
HRID 66329반응물로uspto-grants-1978_12
HRID 109239 반응식
HRID 109239반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 122995 반응식
HRID 122995반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 134601 반응식
HRID 134601반응물로Training data from https://doi.org/10.1039/C8SC04228D (9/10)
HRID 254466 반응식
HRID 254466반응물로uspto-grants-2011_01
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화합물 노트

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Physical Description · 4건

1,2-propylenediamine appears as a colorless liquid with an ammonia-like odor. Strongly irritates skin and tissue.

Extremely hygroscopic liquid; [Merck Index] Colorless liquid with an ammoniacal odor; [CAMEO]

Solid

HYGROSCOPIC COLOURLESS LIQUID WITH PUNGENT ODOUR.

Autoignition Temperature416 °C

물리화학적 성질

녹는점
-37 °C · -37 °C
끓는 점
120 · 120-122 °C(lit.)
밀도
0.87 g/mL · 0.87 g/mL at 25 °C(lit.)
증기 밀도
2.6 · 2.6 (vs air)
증기압
14 mm · 14 mm Hg ( 20 °C)
굴절률
20 · n20/D 1.446
인화점
92 °F · 92 °F
저장 조건
Flammables area
용해도
2 O: · H2O: 매우 용해됨
산도 계수 (pKa)
9.82 · 9.82(at 25℃)
물리적 상태
투명한 액체
색상
무색 내지 거의 무색
수소이온지수(pH)
12 · 12 (100g/l, H2O, 20℃)
폭발한계
2.2 · 2.2-11.1%(V)
수용성
녹는
Merck
14 · 14,7852
BRN
605274 · 605274
Henry's Law Constant
1.4 · 1.4×103 mol/(m3Pa) at 25℃, Nguyen (2013)
Dielectric constant
10.2 · 10.2(Ambient)
안정성
안정적인. 가연성. 강한 산화제, 산, 산 염화물, 산 무수물과 호환되지 않습니다.
InChI
1S/C3H10N2/c1-3(5)2-4/h3H,2,4-5H2,1H3
InChIKey
AOHJOMMDDJHIJH-UHFFFAOYSA-N
SMILES
CC(N)CN
LogP
-1.2 at · -1.2 at 20℃
표면장력
33.8 mN/m · 33.8mN/m at 293.15K
NIST
1 · 1,2-Propanediamine(78-90-0)
EPA
1 · 1,2-Diaminopropane (78-90-0)

화학적 성질

clear liquid

· 1건

Corrosive to skin; [Quick CPC] High inhalation exposure can cause pulmonary edema; [ICSC] Rapidly forms the hemihydrate on absorption of moisture; [Merck Index] Classifications in the EU: Causes severe burns; Harmful by ingestion and skin contact; [IUCLID]

DOT ID and Guide2258 132
Reactive GroupAmines, Phosphines, and Pyridines
EC ClassificationSymbol: C; R: 10-21/22-35; S: (1/2)-26-37/39-45
UN ClassificationUN Hazard Class: 8; UN Subsidiary Risks: 3; UN Pack Group: II
Reactivity AlertsHighly Flammable
Reactivity Profile · 1건

1,2-PROPYLENEDIAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.

Chemical DangersDecomposes on burning. This produces toxic fumes including nitrogen oxides. The substance is a strong base. It reacts violently with acid and is corrosive. Reacts with acid anhydrides, acid chlorides and strong oxidants.

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

First Aid Measures · 4건

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer immediately for medical attention.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention.

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

General First Aid:

Safe StorageFireproof. Separated from food and feedstuffs, strong oxidants, acids, acid anhydrides and acid chlorides. Well closed. Store in an area without drain or sewer access.
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Spillage Disposal · 1건

Remove all ignition sources. Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

Isolation and Evacuation · 2건

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Immediate precautionary measure

Eye PreventionWear face shield or eye protection in combination with breathing protection.
Fire PreventionNO open flames, NO sparks and NO smoking. NO contact with oxidizing agents. Above 33 °C use a closed system, ventilation and explosion-proof electrical equipment.
Inhalation RiskA harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesSerious local effects by all routes of exposure.
Signs and Symptoms · 4건

Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing.

Pain. Redness. Skin burns.

Pain. Redness. Burns. Loss of vision.

Burning sensation. Sore throat. Abdominal pain. Nausea. Vomiting. Shock or collapse.

ICSC Environmental DataThe substance is harmful to aquatic organisms.

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
TX6650000
ridadr
UN 2258
HS 번호
29212900
risk_code
10-21/22-35-42/43
hazard_code
C
safety_code
26-37/39-45-36/37/39-23
포장분류
II
위험 등급
8
기존화학 물질
KE-09748
F 고인화성물질
3-10-23
자연 발화 온도
680 °F
Hazard Classifications
Acute Tox. 3 DermalAcute Tox. 4 OralFlam. Liq. 3Resp. Sens. 1Skin Corr. 1ASkin Sens. 1
스토리지 클래스
3 - Flammable liquids
fluorocarbon sulfactant FC-3
Fluorocarbon Surfactant FN-2
Fluorocaruor surfactant FC-4
2,3-Diethyl-5-methylpyrazine

추가 설명

정의ChEBI: A diamine that is propane substituted by amino groups at positions 1 and 2. Propylenediamine is commonly used as a bidentate ligand in the formation of coordination complexes.