Chlorodiphenylphosphine (HCID 66180)

이름 및 식별자

우선 이름: Chlorodiphenylphosphine
IUPAC: chloro(diphenyl)phosphane
현지명: 디페닐포스피너스클로라이드
영어명: Chlorodiphenylphosphine
분자식: C12H10ClP
분자량: 220.63

이름 및 동의어

Chlorodiphenylphosphine1079-66-9DiphenylchlorophosphineDiphenylphosphinous chloridePhosphinous chloride, diphenyl-chloro(diphenyl)phosphaneP-ChlorodiphenylphosphinechlorodiphenylphosphaneDiphenylphosphine chloridePhosphine, chlorodiphenyl-C12H10ClPMFCD00000529

이름 더 보기

디페닐포스피너스클로라이드포스피노스염화물클로로디페닐포스파인클로로다이페닐포스핀DPPCPH2PCLDiphenylphosphorus chlorideAURORA KA-132295% (C6H5)2PClChlordiphenylphosphin

ClPPh2PPh2ClDiphenyl(chloro)phosphinePhosphinous chloride, P,P-diphenyl-WO975PJK1YNSC-60407diphenyl chlorophosphinediphenyl phosphine chloride

데이터베이스 식별자

CAS: 1079-66-9
PubChem CID: 66180
DTXSID: DTXSID7038789
UNII: WO975PJK1Y
EC Number: 214-093-2
Nikkaji: J24.880K

물성

구조 계산 물성

XLogP: 3.8
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 2
무거운 원자 수: 14
형식 전하: 0
복잡도: 142

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Phosphorus Compounds

SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy

Physical DescriptionYellow liquid; [Merck Index] Yellow liquid with an acrid odor; [Alfa Aesar MSDS]

물리화학적 성질

녹는점: 14 · 14-16°C
끓는 점: 320 °C · 320 °C(lit.)
밀도: 1.229 g/mL · 1.229 g/mL at 25 °C(lit.)
증기 밀도: 7.8 · 7.8 (vs air)
증기압: 1.3 hPa · 1.3 hPa (20 °C)
굴절률: 20 · n20/D 1.636(lit.)
인화점: 230 °F · >230 °F
저장 조건: 30 °C · Store below +30°C.
용해도: 알코올과 섞임. 암모니아와 약간 섞임.
물리적 상태: 액체
색상: 무색~황색
Specific Gravity: 1.229 · 1.229
수용성: 물 에 용해
BRN: 512032 · 512032
InChI: 1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKey: XGRJZXREYAXTGV-UHFFFAOYSA-N
SMILES: ClP(c1ccccc1)c2ccccc2
LogP: 5.33 · 5.330 (est)
NIST: Chlorodiphenylphosphine(1079-66-9)
EPA: Phosphinous chloride, diphenyl- (1079-66-9)

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.5% (1 of 212) of reports.

Danger

H290 (67%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 212 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 3건

Chemical: Phosphinous chloride, diphenyl-

Status: Active Update: 07-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/24379

Chlorodiphenylphosphine: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1건

Reacts violently with water; Causes burns and lachrymation; [Merck Index] Reacts violently with water; Causes burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Triphenylphosphine oxide.

Hazard Classes and CategoriesMet. Corr. 1 (67%)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 2
tsca: TSCA listed
ridadr: UN 3265 8/PG 2
독성: LD50 orally in Rabbit: 316 mg/kg
HS 번호: 29310095
risk_code: 14-34-29-36
hazard_code: C
safety_code: 26-36/37/39-45-8-30-25-27
포장분류: II
위험 등급: 8
기존화학 물질: 2002-3-2048
F 고인화성물질: 1-9-19
자연 발화 온도: 320 °C
Hazard Classifications: Acute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Met. Corr. 1Skin Corr. 1B
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

용도 및 제조

UsesUsed as a reagent in organic chemistry; [Merck Index] Used as an intermediate; [ExPub: ECHA REACH Registrations]

General Manufacturing InformationPhosphinous chloride, P,P-diphenyl-: ACTIVE

응용 분야 · 1건

용도Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.

제조 방법 · 1건

생산 방법The specific synthesis steps of Chlorodiphenylphosphine are as follows: In a sealed NMR tube filled with argon,Dissolve Ph2P (O) H (0.05 mmol) in 0.5 mL of tetrahydrofuran,Add acetyl chloride (the amount of acetyl chloride added is 1.2 times the equivalent of Ph2P (O) H),The mixture was reacted at 100 ° C for 12 hours with a yield of 99%.

상·하류 제품 정보

하류 제품

9,9- 디메틸 -4,5- 비스 (디 페닐 포스 피노) 크 산텐 디 페닐 포스 핀 디 페닐 [4- (N, N- 디메틸 아미노) 페닐] 포스 핀 1,1'- 비스 (디 페닐 포스 피노) 페로센 비스 (2- 디 페닐 포스 피노 페닐) 에테르 (R)-1-[(1S)-2-(디페닐포스피노)페로세닐]에틸디-tert-부틸포스핀 바나듐 트리염화물 1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&Phosphine, 4-dibenzofuranyldiphenyl-2- (디 페닐 포스 피노) - 비 페닐 2-(디페닐포스피노)벤즈알데히드 디펜일(P-VINYLPHENYL)포스핀

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

艾特（浙江）供应链管理有限公司15553101207 18615619105

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