디페닐포스피너스클로라이드
Chlorodiphenylphosphine
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기본 정보
- CAS
1079-66-9- 표준 SMILES
ClP(c1ccccc1)c1ccccc1- InChIKey
XGRJZXREYAXTGV-UHFFFAOYSA-N- 분자식
- C12H10ClP
- 평균 분자량
- 220.63 g/mol
- 단동위원소 질량
- 220.02086463
이름 및 식별자
- 우선 이름
- Chlorodiphenylphosphine
- IUPAC
- chloro(diphenyl)phosphane
- 현지명
- 디페닐포스피너스클로라이드
- 영어명
- Chlorodiphenylphosphine
- 분자식
- C12H10ClP
- 분자량
- 220.63
이름 및 동의어
Chlorodiphenylphosphine1079-66-9DiphenylchlorophosphineDiphenylphosphinous chloridePhosphinous chloride, diphenyl-chloro(diphenyl)phosphaneP-ChlorodiphenylphosphinechlorodiphenylphosphaneDiphenylphosphine chloridePhosphine, chlorodiphenyl-C12H10ClPMFCD00000529
이름 더 보기
디페닐포스피너스클로라이드포스피노스염화물클로로디페닐포스파인클로로다이페닐포스핀DPPCPH2PCLDiphenylphosphorus chlorideAURORA KA-132295% (C6H5)2PClChlordiphenylphosphin
ClPPh2PPh2ClDiphenyl(chloro)phosphinePhosphinous chloride, P,P-diphenyl-WO975PJK1YNSC-60407diphenyl chlorophosphinediphenyl phosphine chloride
데이터베이스 식별자
- CAS
1079-66-9- PubChem CID
- 66180
- DTXSID
DTXSID7038789- UNII
- WO975PJK1Y
- EC Number
- 214-093-2
- Nikkaji
- J24.880K
물성
구조 계산 물성보충 중
- XLogP
- 3.8
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 2
- 무거운 원자 수
- 14
- 형식 전하
- 0
- 복잡도
- 142
실험 및 물리화학적 성질
Chemical ClassesOther Classes -> Phosphorus Compounds
SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy
Physical DescriptionYellow liquid; [Merck Index] Yellow liquid with an acrid odor; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 14 · 14-16°C
- 끓는 점
- 320 °C · 320 °C(lit.)
- 밀도
- 1.229 g/mL · 1.229 g/mL at 25 °C(lit.)
- 증기 밀도
- 7.8 · 7.8 (vs air)
- 증기압
- 1.3 hPa · 1.3 hPa (20 °C)
- 굴절률
- 20 · n20/D 1.636(lit.)
- 인화점
- 230 °F · >230 °F
- 저장 조건
- 30 °C · Store below +30°C.
- 용해도
- 알코올과 섞임. 암모니아와 약간 섞임.
- 물리적 상태
- 액체
- 색상
- 무색~황색
- Specific Gravity
- 1.229 · 1.229
- 수용성
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 0.5% (1 of 212) of reports.
Danger
H290 (67%): May be corrosive to metals [Warning Corrosive to Metals]
P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P405, P406, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 212 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: Phosphinous chloride, diphenyl-
Status: Active Update: 07-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/24379
Chlorodiphenylphosphine: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Reacts violently with water; Causes burns and lachrymation; [Merck Index] Reacts violently with water; Causes burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Triphenylphosphine oxide.
Hazard Classes and CategoriesMet. Corr. 1 (67%)
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 2
- tsca
- TSCA listed
- ridadr
- UN 3265 8/PG 2
화학 및 산업
용도 및 제조
UsesUsed as a reagent in organic chemistry; [Merck Index] Used as an intermediate; [ExPub: ECHA REACH Registrations]
General Manufacturing InformationPhosphinous chloride, P,P-diphenyl-: ACTIVE
응용 분야
용도Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.
제조 방법
생산 방법The specific synthesis steps of Chlorodiphenylphosphine are as follows: In a sealed NMR tube filled with argon,Dissolve Ph2P (O) H (0.05 mmol) in 0.5 mL of tetrahydrofuran,Add acetyl chloride (the amount of acetyl chloride added is 1.2 times the equivalent of Ph2P (O) H),The mixture was reacted at 100 ° C for 12 hours with a yield of 99%.
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