Tetramethylammonium fluoride (HCID 67803)

이름 및 식별자

우선 이름: Tetramethylammonium fluoride
IUPAC: tetramethylazanium fluoride
현지명: 사메틸 암모늄 플로라이드
영어명: Tetramethylammonium fluoride
분자식: C4H12FN
분자량: 93.14

이름 및 동의어

Tetramethylammonium fluoride373-68-2Methanaminium, N,N,N-trimethyl-, fluoride (1:1)DTXSID40883374RefChem:156872DTXCID601022910206-769-099678-28-1tetramethylazanium;fluorideMethanaminium, N,N,N-trimethyl-, fluorideMFCD00011627Tetramethylammonium fluoride, anhydrous

이름 더 보기

사메틸암모늄플로라이드플루오르화테트라메틸암모늄테트라메틸암모늄 플루오라이드플루오르화 테트라메틸암모늄TetraMethylaMMoniuM fluoridTetramethylammonium FluoridedeTetramethylaminium·fluorideTetramethylammonium fluoride (7CI)n,n,n-trimethyl-methanaminiufluorideN,N,N-Trimethylmethanaminium fluoride

TMAFtetramethylazanium fluorideMethanaminium, N,N,N-trimethyl-, fluoride-18FOTHER CA INDEX NAMES:Fluoride (18F1-), N,N,N-trimethylmethanaminiumTetramethylammoniumfluorideMethanaminium, N,N,N-trimethyl-, fluoride (1:1) (ACI); Ammonium, tetramethyl-, fluoride (8CI); Methanaminium, N,N,N-trimethyl-, fluoride (9CI); Tetramethylammonium fluoride (7CI); TMAFEINECS 206-769-0Tetramethylammonium fluoride (anhydrous)tetramethyammonium fluoride

데이터베이스 식별자

CAS: 373-68-2
PubChem CID: 67803
DTXSID: DTXSID40883374
EC Number: 206-769-0

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 6
형식 전하: 0
복잡도: 19

실험 및 물리화학적 성질

Physical DescriptionLiquid

물리화학적 성질

녹는점: 170 °C · 170 °C (dec.) (lit.)
저장 조건: Store at room temperature
물리적 상태: solid
InChI: InChI=1S/C4H12N.FH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChIKey: HQFTZNVQVRRDLN-UHFFFAOYSA-M
SMILES: [N+](C)(C)(C)C.[F-]
EPA: Tetramethylammonium fluoride (373-68-2)

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H302+H312+H332 (62.9%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]；H302 (86.8%): Harmful if swallowed [Warning Acute toxicity, oral]；H312 (86.2%): Harmful in contact with skin [Warning Acute toxicity, dermal]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H332 (86.2%): Harmful if inhaled [Warning Acute toxicity, inhalation]；H335 (86.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 167 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 1건

Methanaminium, N,N,N-trimethyl-, fluoride (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanaminium, N,N,N-trimethyl-, fluoride (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Hazard Classes and CategoriesAcute Tox. 4 (86.8%)；Acute Tox. 4 (86.2%)；Skin Irrit. 2 (100%)；Eye Irrit. 2A (100%)；Acute Tox. 4 (86.2%)；STOT SE 3 (86.2%)

규제 정보

Regulatory Information · 1건

Methanaminium, N,N,N-trimethyl-, fluoride (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanaminium, N,N,N-trimethyl-, fluoride (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: 2811
HS 번호: 29239000
risk_code: 20/21/22-36/37/38
hazard_code: Xn
safety_code: 26-36
포장분류: III
위험 등급: 6.1(b)
기존화학 물질: 2014-1-711
Hazard Classifications: Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: 플루오르화 테트라메틸암모늄 및 이를 1% 이상 함유한 혼합물
유해화학물질 필터링: 2014-1-711

화학 및 산업

약리 정보

MeSH Pharmacological Classification · 1건

Agents that mimic neural transmission by stimulation of the nicotinic receptors on postganglionic autonomic neurons. Drugs that indirectly augment ganglionic transmission by increasing the release or slowing the breakdown of acetylcholine or by non-nicotinic effects on postganglionic neurons are not included here nor are the nonspecific cholinergic agonists.

용도 및 제조

U.S. Production2023: <50,000 lb；2022: <50,000 lb；2021: 50,000 - <250,000 lb；2020: <50,000 lb

Industry UsesPlating agent

General Manufacturing Information · 2건

Computer and Electronic Product Manufacturing

Methanaminium, N,N,N-trimethyl-, fluoride (1:1): ACTIVE

응용 분야

용도Tetramethylammonium fluoride may be used in combination with sulfuryl fluoride for the conversion of aryl phenols to aryl fluorides. It can react with aminosilanes to generate onium amide bases in situ, which can deprotonate heteroarenes.