디 페닐 포스 핀

Diphenylphosphine

HCID 70017CAS 829-85-6

기본 정보

표준 SMILES
c1ccc(Pc2ccccc2)cc1
InChIKey
GPAYUJZHTULNBE-UHFFFAOYSA-N
분자식
C12H11P
평균 분자량
186.19 g/mol
단동위원소 질량
186.05983698

이름 및 식별자

우선 이름
Diphenylphosphine
IUPAC
diphenylphosphane
현지명
디 페닐 포스 핀
영어명
Diphenylphosphine
분자식
C12H11P
분자량
186.19

이름 및 동의어

Diphenylphosphine829-85-6Phosphine, diphenyl-F9B5T7O7ZYEINECS 212-591-4NSC-152123DIPHENYLPHOSPHINE [MI]DTXSID50232076NSC 152123RefChem:588939DTXCID50154567212-591-4
이름 더 보기
디페닐포스핀Diphenylphosphin98% Ph2PHAURORA KA-1107Diphenyl phospinePHOSPHINE, DIPHENYLDPP/DIPHENYLPHOSPHIN
diphenylphosphaneHPPH2PH2PHMFCD00003040C12H11PUNII-F9B5T7O7ZYdiphenylphospinediphenyl-phosphane

데이터베이스 식별자

CAS
829-85-6
PubChem CID
70017
DTXSID
DTXSID50232076
UNII
F9B5T7O7ZY
EC Number
212-591-4
Nikkaji
J99.507J

물성

구조 계산 물성

XLogP
3
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
2
무거운 원자 수
13

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Phosphorus Compounds
SpringerMaterials Properties31P nuclear magnetic resonance spectrum
Physical DescriptionClear liquid with strong unpleasant odor; [Merck Index] Clear light yellow liquid; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점
-14.5 °C · -14.5 °C
끓는 점
280 °C · 280 °C(lit.)
밀도
1.07 g/mL · 1.07 g/mL at 25 °C(lit.)
증기압
2 mm · 2 mm Hg ( 110 °C)
굴절률
20 · n20/D 1.625(lit.)
인화점
-18 °C · -18°C (Hexane)
화학적 성질 · 1건

Diphenylphosphine is an organophosphorus compound commonly used in laboratories. It is a clear colorless to slightly yellow liquid with unpleasant odor, irritating, easily oxidized in air and spontaneously combusts, sensitive to air and light, and needs to be protected by nitrogen. It can be used as a precursor for the synthesis of a variety of organophosphine ligands. These ligands, in turn, are used in homogeneous catalysis for many applications including: asymmetric hydrogenation, coupling chemistry, ethylene oligomerization, hydroformylation, hydration of nitriles, and polymerization of alkenes.

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P261, P264, P264+P265, P271, P280, P302+P335+P334, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationStatus: Active Update: 15-03-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/28173
Hazards SummaryPyrophoric and irritating; [Merck Index] Pyrophoric; Reacts violently with water; A skin and strong eye irritant; [Sigma-Aldrich MSDS] See Triphenylphosphine and Phenylphosphine.
Hazard Classes and CategoriesPyr. Liq. 1 (100%)

안전 데이터

wgk
3
ridadr
UN 2845 4.2/PG 1
HS 번호
29319090
risk_code
17-36/37/38
hazard_code
F,Xi
safety_code
26-36

화학 및 산업

용도 및 제조

UsesUsed as a reagent in synthetic organic chemistry; [Merck Index]

응용 분야

용도Diphenylphosphine is used in the synthesis of aminophosphines for application as catalysts. It is also used in the preparation of chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]

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257건

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